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Related papers: Diffusion and desorption of SiH3 on hydrogenated H…

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One of the most promising acceptor precursors for atomic-precision $\delta$-doping of silicon is BCl$_3$. The chemical pathway, and the resulting kinetics, through which BCl$_3$ adsorbs and dissociates on silicon, however, has only been…

Materials Science · Physics 2025-05-14 Quinn T. Campbell , Shashank Misra , Jeffrey A. Ivie

In this paper we use density-functional theory calculations to analyze both the stability and diffusion of Cu adatoms near and on the H-passivated Si(001) surface. Two different Cu sources are considered: depositing Cu from vacuum, and…

Materials Science · Physics 2024-02-08 A. Rodriguez-Prieto , D. R. Bowler

Analysis of lithiation and delithiation kinetics in pulse-laser-deposited crystalline thin-film silicon (Si) electrodes is presented. Data from open-circuit relaxation experiments are used in conjunction with a model based on Tafel kinetics…

Materials Science · Physics 2013-01-04 Vijay A. Sethuraman , Venkat Srinivasan , John Newman

The results of RHEED, FTIR and Raman spectroscopy study of silicon and germanium films with the thickness up to 200 nm grown from molecular beams on dielectric Si$_3$N$_4$/SiO$_2$/Si(001) substrates are presented. Noticeable changes of the…

BCl$_3$ is a promising candidate for atomic-precision acceptor doping in Si, but optimizing the electrical properties of structures created with this technique requires a detailed understanding of adsorption and dissociation pathways for…

We report on molecular dynamics simulations of the atomic structure and diffusion processes at Al(110)/Si(001) interphase boundary created by simulated vapor deposition of Al(Si) alloy onto Si(001) substrate. An array of parallel misfit…

Materials Science · Physics 2024-12-31 Yang Li , Yuri Mishin

The adsorption of PBr3 on the Si(100)-2$\times$1 surface was studied by scanning tunneling microscopy (STM) and density functional theory (DFT). The PBr3 molecule completely dissociates on the Si(100) surface at room temperature into P and…

Materials Science · Physics 2025-10-24 Vladimir M. Shevlyuga , Yulia A. Vorontsova , Tatiana V. Pavlova

Using density-functional theory we investigate several properties of Al(111), Al(100), Al(110), and stepped Al(111) surfaces. We report results of formation energies of surfaces, steps, adatoms, and vacancies. For the adsorption and…

mtrl-th · Physics 2008-02-03 Roland Stumpf , Matthias Scheffler

The diffusion path and diffusivity of oxygen in crystalline silicon are computed using an empirical interatomic potential which was recently developed for modelling the interactions between oxygen and silicon atoms. The diffusion path is…

mtrl-th · Physics 2008-02-03 Z. Jiang , R. A. Brown

The adsorption of C60 on Si(111) has been studied by means of first-principles density functional calculations. A 2x2 adatom surface reconstruction was used to simulate the terraces of the 7x7 reconstruction. The structure of several…

We report total-energy calculations based on the density-functional theory that clarify microscopic mechanisms of initial stage of graphene formation on the SiC(0001) surface. We explore favorable reactions for desorption of either Si or C…

Materials Science · Physics 2016-11-21 Fumihiro Imoto , Jun-Ichi Iwata , Mauro Boero , Atsushi Oshiyama

The coefficient of diffusion of hydrogen in crystalline silicon is calculated using tight-binding molecular dynamics. Our results are in good quantitative agreement with an earlier study by Panzarini and Colombo [Phys. Rev. Lett. 73, 1636…

Materials Science · Physics 2009-10-31 Sabrina Bedard , Laurent J. Lewis

The experimental results presented in this paper show the influence of the elastic deformation of porous solids on the adsorption process. With p+-type porous silicon formed on highly boron doped (100) Si single crystal, we can make…

Soft Condensed Matter · Physics 2015-05-13 Annie Grosman , Camille Ortega

We present a numerical study of the structural correlations associated to gas adsorption/desorption in silica aerogels in order to provide a theoretical interpretation of scattering experiments. Following our earlier work, we use a…

Disordered Systems and Neural Networks · Physics 2016-08-31 F. Detcheverry , E. Kierlik , M. L. Rosinberg , G. Tarjus

The structure of the transient layer at the interface between air and the aqueous solution of silica nanoparticles with the size distribution of particles that has been determined from small-angle scattering has been studied by the X-ray…

The energetics of H$_2$ interacting with the Si(100) surface is studied by means of {\em ab initio} total energy calculations within the framework of density functional theory. We find a direct desorption pathway from the mono-hydride phase…

mtrl-th · Physics 2009-10-28 P. Kratzer , B. Hammer , J. K. Norskov

Hydrogen point defects in silicon still hold unsolved problems, whose disclosure is fundamental for future advances in Si technologies. Among the open issues is the mechanism for the condensation of atomic hydrogen into molecules in Si…

Materials Science · Physics 2022-04-29 Diana Gomes , Vladimir P. Markevich , Anthony R. Peaker , José Coutinho

The light absorption of [001] grown single-crystalline silicon wafers can be enhanced by chemical etching with potassium hydroxide resulting in a pyramid-like surface texture. Alongside this advantageous property in the context of solar…

We present an ab initio study of the structural and electronic properties of styrene molecules adsorbed on the dimerized Si(100) surface at different coverages, ranging from the single-molecule to the full monolayer. The adsorption…

Soft Condensed Matter · Physics 2009-11-11 A. Calzolari , A. Ruini , M. J. Caldas , E. Molinari

Adsorption of acetylene on Si(100) is studied from first principles. We find that, among a number of possible adsorption configurations, the lowest-energy structure is a ``bridge'' configuration, where the C$_2$H$_2$ molecule is bonded to…

Condensed Matter · Physics 2009-10-31 Pier Luigi Silvestrelli , Flavio Toigo , Francesco Ancilotto