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Results of a systematic investigation of the vapour-liquid equilibria (VLE) of 30 individual two-centre Lennard-Jones plus pointquadrupole model fluids (2CLJQ) are reported over a range of reduced quadrupolar momentum $0 \le Q^{*2} \le 4$…

Chemical Physics · Physics 2009-04-24 J. Stoll , J. Vrabec , H. Hasse

An ion and a polar molecule interact by an anisotropic ion-dipole potential scaling as $- \alpha \cos (\theta)/r^2$ at large distances. Due to its long-range character, it modifies the properties of angular wave functions, which are no…

Atomic Physics · Physics 2021-03-03 Tomasz Wasak , Zbigniew Idziaszek

The phase behavior of colloidal particles embedded in a binary fluid is influenced by wetting layers surrounding each particle. The free energy of the fluid film depends on its morphology, i.e., on size, shape and connectivity. Under rather…

Soft Condensed Matter · Physics 2007-05-23 Uwe Brodatzki , Klaus Mecke

We show that the kinetic-theoretical self-diffusion coefficient of an atomic fluid plays the same role as the short-time self-diffusion coefficient D_S in a colloidal liquid, in the sense that the dynamic properties of the former, at times…

We study an air-fluidized granular monolayer, composed of plastic spheres which roll on a metallic grid. The air current is adjusted so that the spheres never loose contact with the grid, so that the dynamics may be regarded as pseudo…

Soft Condensed Matter · Physics 2022-11-21 F. Vega Reyes , A. Rodríguez-Rivas , J. F. González-Saavedra , M. A. López-Castaño

The asymptotic analysis of kinetic models describing the behavior of particles interacting through alignment is performed. We will analyze the asymptotic regime corresponding to large alignment frequency where the alignment effects are…

Analysis of PDEs · Mathematics 2017-01-16 M. Bostan , J. A. Carrillo

Molecular dynamics simulations of a Lennard-Jones binary mixture confined in a disordered array of soft spheres are presented. The single particle dynamical behavior of the glass former is examined upon supercooling. Predictions of mode…

Statistical Mechanics · Physics 2009-11-07 P. Gallo , R. Pellarin , M. Rovere

We simulate the compression of a two-component Lennard-Jones liquid at a variety of constant temperatures using a molecular dynamics algorithm in an isobaric-isothermal ensemble. The viscosity of the liquid increases with pressure,…

chem-ph · Physics 2009-10-22 Shelly L. Shumway , Andrew S. Clarke , Hannes Jónsson

Using a density functional based interface displacement model we determine the effective interaction potential between two spherical particles which are immersed in a homogeneous fluid such as the vapor phase of a one-component substance or…

Soft Condensed Matter · Physics 2009-10-31 C. Bauer , T. Bieker , S. Dietrich

We have investigated thermodynamic and dynamic properties as well as the dielectric constant of water-metha\-nol model mixtures in the entire range of composition by using constant pressure molecular dynamics simulations at ambient…

Soft Condensed Matter · Physics 2015-12-25 E. Galicia-Andrés , H. Dominguez , L. Pusztai , O. Pizio

Spherical truncations of Coulomb interactions in standard models for water permit efficient molecular simulations and can give remarkably accurate results for the structure of the uniform liquid. However truncations are known to produce…

Statistical Mechanics · Physics 2009-11-13 Jocelyn M. Rodgers , John D. Weeks

Evidence for capillary waves at a liquid/vapor interface are presented from extensive molecular dynamics simulations of a system containing up to 1.24 million Lennard-Jones particles. Careful measurements show that the total interfacial…

Statistical Mechanics · Physics 2009-10-31 Scott W. Sides , Gary S. Grest , Martin-D. Lacasse

We use Monte Carlo and molecular dynamics simulations to study phase behavior and transport properties in a symmetric binary fluid where particles interact via Lennard-Jones potential. Our results for the critical behavior of collective…

Statistical Mechanics · Physics 2018-03-09 Sutapa Roy , Subir K. Das

We investigate through numerical simulations the hydrodynamic interactions between two rigid spherical particles suspended on the axis of a cylindrical tube filled with an elastoviscoplastic fluid subjected to pressure-driven flow. The…

Simple models for spherical particles with a soft shell have been shown to self-assemble into numerous crystal phases and even quasicrystals. However, most of these models rely on a simple pairwise interaction, which is usually a valid…

Soft Condensed Matter · Physics 2020-09-03 Emanuele Boattini , Nina Bezem , Sudeep N. Punnathanam , Frank Smallenburg , Laura Filion

We use molecular dynamics simulations in 2d to study multi-component fluid in the limiting case where {\it all the particles are different} (APD). The particles are assumed to interact via Lennard-Jones (LJ) potentials, with identical size…

Soft Condensed Matter · Physics 2015-06-23 Lenin S. Shagolsem , Dino Osmanović , Orit Peleg , Yitzhak Rabin

By means of extensive equilibrium molecular dynamics simulations we have investigated, the behavior of the interfacial tension $\gamma$ of two immiscible symmetrical Lennard-Jones fluids. This quantity is studied as function of reduced…

Statistical Mechanics · Physics 2016-08-15 Enrique Diaz-Herrera , José Alejandre , Guillermo Ramírez-Santiago , F. Forstmann

We present a systematic study of the self-diffusion coefficient for a fluid of particles interacting via the square-well pair potential by means of molecular dynamics simulations in the canonical (N,V,T) ensemble. The discrete nature of the…

Soft Condensed Matter · Physics 2018-11-14 Alexis Torres-Carbajal , Victor M. Trejos , Luz Adriana Nicasio-Collazo

We study indented spherical colloids, interacting via depletion forces. These systems exhibit liquid-vapor phase transitions whose properties are determined by a combination of strong "lock-and-key" bonds and weaker non-specific…

Soft Condensed Matter · Physics 2015-06-17 Douglas J. Ashton , Robert L. Jack , Nigel B. Wilding

The phase behaviour of room-temperature ionic liquids (ILs) confined in disordered porous media is studied using a theoretical approach that combines an extension of scaled particle theory, Wertheim's thermodynamic perturbation theory, and…

Soft Condensed Matter · Physics 2025-03-12 T. Hvozd , T. Patsahan , O. Patsahan , Yu. Kalyuzhnyi , M. Holovko