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Atomically flat interfaces between ternary oxides have chemically different variants, depending on the terminating lattice planes of both oxides. Electronic properties change with the interface termination which affects, for instance,…

We studied LaAlO3/SrTiO3 interfaces for varying LaAlO3 thickness by core-level photoemission spectroscopy. In Ti 2p spectra for conducting "n-type" interfaces, Ti3+ signals appeared, which were absent for insulating "p-type" interfaces. The…

Materials Science · Physics 2015-05-28 M. Takizawa , S. Tsuda , T. Susaki , H. Y. Hwang , A. Fujimori

The emergent superconductivity at the LaAlO3/KTaO3 interfaces exhibits a mysterious dependence on the KTaO3 crystallographic orientations. Here we show, by soft X-ray angle-resolved photoemission spectroscopy, that the interfacial…

Current memcapacitor implementations typically demand complex fabrication processes or depend on organic materials exhibiting poor environmental stability and reproducibility. Here, we demonstrate memcapacitor structures utilizing a quasi…

Heterostructuring provides different ways to manipulate the orbital degrees of freedom and to tailor orbital occupations in transition metal oxides. However, the reliable prediction of these modifications remains a challenge. Here, we…

Strongly Correlated Electrons · Physics 2022-04-27 P. Radhakrishnan , B. Geisler , K. Fürsich , D. Putzky , Y. Wang , G. Christiani , G. Logvenov , P. Wochner , P. A. van Aken , R. Pentcheva , E. Benckiser

The concept of duality has proved extremely powerful in extending our understanding in many areas of physics (1, 2). Charge-vortex duality has been proposed (3, 4) as a model to understand the superconductor to insulator transition (SIT) in…

Superconductivity · Physics 2012-07-31 Manan Mehta , D. A. Dikin , C. W. Bark , S. Ryu , C. M. Folkman , C. B. Eom , V. Chandrasekhar

The electronic reconstruction at the interface between two insulating oxides can give rise to a highly-conductive interface. In analogy to this remarkable interface-induced conductivity we show how, additionally, magnetism can be induced at…

Strongly Correlated Electrons · Physics 2007-06-13 A. Brinkman , M. Huijben , M. van Zalk , J. Huijben , U. Zeitler , J. C. Maan , W. G. van der Wiel , G. Rijnders , D. H. A. Blank , H. Hilgenkamp

Understanding the nature of electrical conductivity, superconductivity and magnetism between layers of oxides is of immense importance for the design of electronic devices employing oxide heterostructures. We demonstrate that resonant…

We investigated how different materials affect the orbital-charge conversion in heterostructures with the naturally oxidized cooper capping layer. When we added a thin layer of $CuOx(3nm)$ onto yttrium iron garnet $(YIG)/W$ stacks, we…

Mesoscale and Nanoscale Physics · Physics 2024-01-29 E. Santos , J. E. Abrão , A. S. Vieira , J. B. S. Mendes , R. L. Rodríguez-Suárez , A. Azevedo

In this paper, density functional theory calculations are used to explore the electronic and atomic reconstruction at interfaces between III-III/I-V oxides. In particular, at these interfaces, two dimensional electron gases (2DEGs) with…

Materials Science · Physics 2012-06-06 Valentino R. Cooper

By performing first-principles calculations on four capacitor structures based on BaTiO3 and PbTiO3, we determine the intrinsic interfacial effects that are responsible for the destabilization of the polar state in thin-film ferroelectric…

Materials Science · Physics 2011-03-03 Massimiliano Stengel , David Vanderbilt , Nicola A. Spaldin

We investigate the effect of oxygen vacancies and hydrogen dopants at the surface and inside slabs of LaAlO3, SrTiO3, and LaAlO3/SrTiO3 heterostructures on the electronic properties by means of electronic structure calculations as based on…

Strongly Correlated Electrons · Physics 2019-05-03 I. I. Piyanzina , V. Eyert , Yu. V. Lysogorskiy , D. A. Tayurskii , T. Kopp

A combination of spectroscopic probes was used to develop a detailed experimental description of the transport and magnetic properties of superlattices composed of the paramagnetic metal CaRuO$_3$ and the antiferromagnetic insulator…

Strongly Correlated Electrons · Physics 2015-05-13 J. W. Freeland , J. Chakhalian , A. V. Boris , J. -M. Tonnerre , J. J. Kavich , P. Yordanov , S. Grenier , P. Popovich , H. N. Lee , B. Keimer

The discovery of two-dimensional electron gas (2DEG) at well-defined interfaces between insulating complex oxides provides the opportunity for a new generation of all-oxide electronics. Particularly, the 2DEG at the interface between two…

Materials Science · Physics 2013-12-16 Y. Z. Chen , N. Pryds , J. R. Sun , B. G. Shen , S. Linderoth

We perform first-principles density functional calculations to elucidate structural, electronic and magnetic properties at the interface of \ce{(0001)Cr2O3-(111)Pt} bilayers. This investigation is motivated by the fact that, despite the…

Materials Science · Physics 2024-05-09 Marlies Reher , Nicola A. Spaldin , Sophie F. Weber

The analysis of the structure, chemical stability, electronic and ferroelectric properties of the interfaces between Pt(001) and PbZrTiO$_3$(001) (PZT) have been performed with $ab$ $initio$ methods. We show that the chemical environment…

Materials Science · Physics 2020-01-08 Anna V. Kimmel

The realization of ambient-pressure superconductivity in La$_3$Ni$_2$O$_7$ thin films raises a fundamental question: is the metallic ground state driven by lattice strain or interfacial charge reconstruction? Using fully self-consistent…

Superconductivity · Physics 2025-12-22 Guanlin Li , Cui-Qun Chen , Haoliang Shi , Zhengtao Liu , Hao Ma , Fubo Tian , Dao-Xin Yao , Defang Duan

Perovskite solar cells (PSCs) based on methylammonium lead iodide (MAPbI3) exhibit remarkable photovoltaic performance, where interface engineering with hole transport layers (HTLs) is crucial for optimizing charge transfer and device…

Materials Science · Physics 2025-12-30 Somayyeh Alidoust , V. Ongun Özçelik

Epitaxial strain, layer confinement and inversion symmetry breaking have emerged as powerful new approaches to control the electronic and atomic-scale structural properties in complex metal oxides. Nickelate heterostructures, based on…

LaNiO$_{3}$-BaTiO$_{3}$ superlattices with different types of interfaces are studied from first-principles density-functional theory. It is revealed that the ferroelectricity in the superlattice with (NiO$_2$)$^-$/(BaO)$^0$ interfaces is…

Materials Science · Physics 2014-09-30 Yin-Zhong Wu , Hai-Shuang Lu , Tian-Yi Cai , Sheng Ju