Related papers: On the Raman shift in nanosized crystals
The use of phononic crystals for vibration attenuation and isolation has been widely studied, showing that the attenuation frequency range depends on their mass and stiffness. The concepts of chirality and tacticity have been introduced…
We treat resonant Raman scattering via the multiphonon exciton transitions in cylindrical quantum dots with a parabolic confinement in the lateral direction and with a finite rectangular interface-barrier confinement in the axial direction.…
A mass and spring model is used to calculate the phonon mode dispersion for single wall carbon nanotubes (SWNTs) of arbitrary chirality. The calculated dispersions are used to determine the chirality dependence of the radial breathing…
The nanocrystallite have the finite number of the oscillation modes. Their number increases proportionally to a cube of the characteristic size. Thus the oscillation spectrum of nanocrystal becomes discrete, and the separate modes of…
Intermediate frequency range (511 - 514 cm-1) Si phonons in Si-SiO2 nanocomposites are shown to have contribution from both core1 and surface/interface1 Si phonons, where, ratio of contribution of the two depends on the size of a Si…
A simple way to investigate theoretically the Raman spectra (RS) of nonpolar nanoparticles is proposed. For this aim we substitute the original lattice optical phonon eigenproblem by the continuous Klein-Fock-Gordon-like equation with…
Micro-Raman spectroscopy has been used to study lattice dynamics associated with the ferroelectric domains of a BiFeO$_3$ single crystal at low temperature. The phonon assignment shows a large frequency splitting between the transverse and…
For nanostructured materials, strain is of fundamental importance in stabilizing a specific crystallographic phase, modifying electronic properties, and in consequence their magnetism when it applies. Here we describe a magnetic shape…
In order to clarify the relationship between the phonon spectra of nanoparticles and their melting temperature, we studied in detail the size-dependent low energy vibration modes. A minimum model with atoms on a lattice and harmonic…
We theoretically calculate the average fraction of frozen particles in rectangular systems of arbitrary dimensions for the Kob-Andersen and Fredrickson-Andersen kinetically-constrained models. We find the aspect ratio of the rectangle's…
The interest of micro and tip-enhanced Raman spectroscopy to analyze nanosized and nanostructured materials, chiefly semiconductors, oxides and pristine or functionalized carbon nanotubes, is reviewed at the light of the contributions to…
Large variations of up to two orders of magnitude are observed in the Raman intensity of pristine, suspended quasi-metallic single-walled carbon nanotubes in response to applied gate potentials. No change in the resonance condition is…
Temperature dependence of Fano resonance, recently discovered in infra-red (IR spectra of nanodiamonds synthesized from chloroadamantane at high static pressures, is investigated. For the first time, marked variations of the resonance…
By performing density functional theory-based ab-initio calculations, Raman active phonon modes of novel single-layer two-dimensional (2D) materials and the effect of in-plane biaxial strain on the peak frequencies and corresponding…
In terms of lattice dynamics theory, we study the vibrational properties of the oxygen-functionalized single wall carbon nanotubes (O-SWCNs). Due to the C-O and O-O interactions, many degenerate phonon modes are split and even some new…
Phonon-phonon anharmonic effects have a strong influence on the phonon spectrum; most prominent manifestation of these effects are the softening (shift in frequency) and broadening (change in FWHM) of the phonon modes at finite temperature.…
A theoretical model supported by experimental results explains the dependence of the Raman scattering signal on the evolution of structural parameters along the amorphization trajectory of polycrystalline graphene systems. Four parameters…
Pressure-dependent Raman scattering studies in the range 0.0 -- 32 kbar were carried out in L-alanine in order to investigate its external mode phonon spectra in relation to the phase transitions in the crystal. A careful analysis of the…
Phonons are quanta of lattice vibrations, and their modes (linear, circular, or stationary) are symmetry-determined. Circularly polarized phonons, possessing nonzero angular momentum (AM), have drawn widespread attention recently. Despite…
The effect of pressure on the zone-center optical phonon modes and the elastic properties of hafnium has been studied by both experimental (Raman scattering) and theoretical (DFT) approaches. It was found an anomaly dependence of the phonon…