Related papers: Nonanalyticities of the entropy induced by saddle …
Traditionally, phase transitions are defined in the thermodynamic limit only. We propose a new formulation of equilibrium thermo-dynamics that is based entirely on mechanics and reflects just the {\em geometry and topology} of the N-body…
Within its range of applicability, the Boltzmann equation seems unique in its capacity to accurately describe the transition from almost any initial state to a self-equilibrated thermal state. Using information-theoretic methods to rephrase…
Equilibrium phase transitions usually emerge from the microscopic behavior of many-body systems and are associated to interesting phenomena such as the generation of long-range order and spontaneous symmetry breaking. They can be defined…
We argue that the phase transition in the mean-field XY model is related to a particular change in the topology of its configuration space. The nature of this topological transition can be discussed on the basis of elementary Morse theory…
Recent numerical developments in the study of glassy systems have shown that it is possible to give a purely geometric interpretation of the dynamic glass transition by considering the properties of unstable saddle points of the energy.…
The presence of nonanalyticity in observables is a manifestation of phase transitions. Through the study of two paradigmatic topological models in one and two dimensions, in this work we show that the circuit complexity based on our…
Traditionally, phase transitions are defined in the thermodynamic limit only. We discuss how phase transitions of first order (with phase separation and surface tension), continuous transitions and (multi)-critical points can be seen and…
Boltzmann's principle S(E,N,V)=k*ln W(E,N,V) relates the entropy to the geometric area e^{S(E,N,V)} of the manifold of constant energy in the N-body phase space. From the principle all thermodynamics and especially all phenomena of phase…
Entropy production during the process of thermal phase-separation of multiphase flows is investigated by means of a discrete Boltzmann kinetic model. The entropy production rate is found to increase during the spinodal decomposition stage…
Boltzmann's principle S(E,N,V)=k\ln W relates the entropy to the geometric area e^{S(E,N,V)} of the manifold of constant energy in the N-body phase space. From the principle all thermodynamics and especially all phenomena of phase…
A way to construct Boltzmann entropy, i.e., the entropy as a function of a microscopic pure state, for quantum field systems is proposed. Operators that shift the field in wavevector space are used in the construction. By employing an…
Many complex systems are characterized by non-Boltzmann distribution functions of their statistical variables. If one wants to -- justified or not -- hold on to the maximum entropy principle for complex statistical systems (non-Boltzmann)…
Nonequilibrium phase transitions can be typified in a similar way to equilibrium systems, for instance, by the use of the order parameter. However, this characterization hides the irreversible character of the dynamics as well as its…
Maximum-entropy ensembles are key primitives in statistical mechanics from which thermodynamic properties can be derived. Over the decades, several approaches have been put forward in order to justify from minimal assumptions the use of…
A central tenet in the theory of quantum phase transitions (QPTs) is that a nonanalyticity in the ground-state energy in the thermodynamic limit implies a QPT. Here we report on a finding that challenges this assertion. As a case study we…
If the von Neumann equation is modified by time dependent statistical weights, the time rate of entropy, the entropy exchange and production of a Schottky system are derived whose Hamiltonian does not contain the interaction with the…
Boltzmann's entropy is slightly modified to make it suitable for discussing phase transitions in finite systems. As an example it is shown that the pendulum undergoes a second order phase transition when passing from a vibrational to a…
The issue of the thermodynamics of a system of distinguishable particles is discussed in this paper. In constructing the statistical mechanics of distinguishable particles from the definition of Boltzmann entropy, it is found that the…
Most natural systems operate far from equilibrium, displaying time-asymmetric, irreversible dynamics characterized by a positive entropy production while exchanging energy and matter with the environment. Although stochastic thermodynamics…
Phase transitions in nuclei, small atomic clusters and self-gravitating systems demand the extension of thermo-statistics to ``Small'' systems. The main obstacle is the thermodynamic limit. It is shown how the original definition of the…