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The second law of thermodynamics states that entropy increases (or does not change) by time in an isolated system. As microscopic physical laws are reversible, the origin of irreversibility is not straightforward. Although the outcome of a…

Statistical Mechanics · Physics 2013-02-19 Balint Szabo

The observed general time-asymmetric behavior of macroscopic systems -- embodied in the second law of thermodynamics -- arises naturally from time-symmetric microscopic laws due to the great disparity between macro and micro-scales. More…

Condensed Matter · Physics 2007-05-23 Joel L. Lebowitz

The second law of thermodynamics states that entropy production in macroscopic systems is non-negative, reaching zero only at thermodynamic equilibrium. As a corollary, this implies that the state trajectory of macroscopic systems is…

Statistical Mechanics · Physics 2025-01-30 O. Politano , Alejandro L. Garcia , F. Baras , M. Malek Mansour

A heuristic generalization of the Boltzmann-Gibbs microcanonical entropy is proposed, able to describe meta-equilibrium features and evolution of macroscopic systems. Despite its simple-minded derivation, such a function of "collective…

Statistical Mechanics · Physics 2007-05-23 Piero Cipriani

Irreversibility is one of the most intriguing concepts in physics. While microscopic physical laws are perfectly reversible, macroscopic average behavior has a preferred direction of time. According to the second law of thermodynamics, this…

Quantum Physics · Physics 2017-04-12 T. B. Batalhao , A. M. Souza , R. S. Sarthour , I. S. Oliveira , M. Paternostro , E. Lutz , R. M. Serra

Unlike most other laws of nature, the second law of thermodynamics is of a statistical nature, according to Boltzmann, meaning that its reliability arises from the vast number of particles present in macroscopic systems. This means that…

General Physics · Physics 2019-07-22 Ian von Hegner

I show that whenever a system undergoes a reproducible macroscopic process the mutual distinguishability of macrostates, as measured by their relative entropy, diminishes. This extends the second law which regards only ordinary entropies,…

Quantum Physics · Physics 2010-08-10 Jochen Rau

Through extended consideration of two wide classes of case studies -- dilute gases and linear systems -- I explore the ways in which assumptions of probability and irreversibility occur in contemporary statistical mechanics, where the…

Statistical Mechanics · Physics 2021-04-23 David Wallace

Statistical mechanics descriptions of the second law of thermodynamics generally imply point-like particles driven by a dissipative overall mechanism for their simultaneous time-evolution. As the number of involved particles grows larger,…

General Physics · Physics 2016-02-16 Hans R. Moser

In stochastic thermodynamics, the entropy production of a thermodynamic system is defined by the irreversibility measured by the logarithm of the ratio of the path probabilities in the forward and reverse processes. We derive the relation…

Statistical Mechanics · Physics 2018-03-14 Hyun-Myung Chun , Jae Dong Noh

We give a simple proof of the uncertainty principle with quantum side information, as in [Berta et al. Nature Physics 6, 659 (2010)], invoking the monotonicity of the relative entropy. Our proof shows that the entropic uncertainty principle…

Quantum Physics · Physics 2011-12-08 Patrick J. Coles , Li Yu , Michael Zwolak

I argue that if a special science satisfies certain key assumptions that are familiar from physicalist accounts of the special sciences and from physics, then its causal regularities have an associated notion of entropy, and that this…

History and Philosophy of Physics · Physics 2026-05-01 Balazs Gyenis

Fluctuations of observables as functions of time, or "fluctuation patterns", are studied in a chaotic microscopically reversible system that has irreversibly reached a nonequilibrium stationary state. Supposing that during a certain, long…

chao-dyn · Physics 2008-10-08 G. Gallavotti

Time-asymmetric behavior as embodied in the second law of thermodynamics is observed in {\it individual macroscopic} systems. It can be understood as arising naturally from time-symmetric microscopic laws when account is taken of a) the…

Statistical Mechanics · Physics 2007-09-06 Joel L. Lebowitz

The second law of thermodynamics is asymmetric with respect to time as it says that the entropy of the universe must have been lower in the past and will be higher in the future. How this time-asymmetric law arises from the time-symmetric…

Statistical Mechanics · Physics 2021-06-07 Sivapalan Chelvaniththilan

The question of how irreversibility can emerge as a generic phenomena when the underlying mechanical theory is reversible has been a long-standing fundamental problem for both classical and quantum mechanics. We describe a mechanism for the…

Quantum Physics · Physics 2013-09-20 Cozmin Ududec , Nathan Wiebe , Joseph Emerson

This article aims at revisiting, with the aid of simple and neat numerical examples, some of the basic features of macroscopic irreversibility, and, thus, of the mechanical foundation of the second principle of thermodynamics as drawn by…

Statistical Mechanics · Physics 2015-11-12 Luca Cerino , Fabio Cecconi , Massimo Cencini , Angelo Vulpiani

It is often claimed that the fundamental laws of physics are deterministic and time-symmetric and that therefore our experience of the passage of time is an illusion. This paper will critically discuss these claims and show that they are…

Quantum Physics · Physics 2023-04-20 Barbara Drossel

We consider a free fermion chain with uniform nearest-neighbor hopping and let it evolve from an arbitrary initial state with a fixed macroscopic number of particles. We then prove that, at a sufficiently large and typical time, the…

Statistical Mechanics · Physics 2026-04-13 Hal Tasaki

Here we deconstruct, and then in a reasoned way reconstruct, the concept of "entropy of a system," paying particular attention to where the randomness may be coming from. We start with the core concept of entropy as a COUNT associated with…

General Physics · Physics 2017-05-10 Tommaso Toffoli
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