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An investigation of field-free molecular alignment produced by elliptically polarized laser pulses is reported. Experiments are conducted in CO$_2$ at room temperature. A non invasive all-optical technique, based on the cross defocusing of…

Quantum Physics · Physics 2008-12-18 E. Hertz , D. Daems , S. Guérin , H. R. Jauslin , B. Lavorel , O. Faucher

The field-free alignment and orientation of the linear molecule by the two-color trapezoidal laser pulses were theoretically investigated. The trapezoidal shape of a laser pulse allows to enhance the maximum alignment degree for the same…

Quantum Physics · Physics 2024-01-11 Eugene A. Koval

We have experimentally and theoretically investigated the mixed-field orientation of rotational-state-selected OCS molecules and we achieve strong degrees of alignment and orientation. The applied moderately intense nanosecond laser pulses…

We show that field-free molecular orientation induced by a half-cycle pulse may be considerably enhanced by an additional laser pulse inducing molecular anti-alignment. Two qualitatively different enhancement mechanisms are identified…

Quantum Physics · Physics 2009-11-11 E. Gershnabel , I. Sh. Averbukh , R. J. Gordon

We use an optical centrifuge to align asymmetric top $\mathrm{SO_2}$ molecules by adiabatically spinning their most polarizable O-O axis. The effective centrifugal potential in the rotating frame confines sulfur atoms to the plane of the…

Chemical Physics · Physics 2016-05-11 A. Korobenko , V. Milner

We explore the role of laser induced anti-alignment in enhancing molecular orientation. A field-free enhanced orientation via anti-alignment scheme is presented, which combines a linearly polarized femtosecond laser pulse with a half-cycle…

Optics · Physics 2009-11-11 E. Gershnabel , I. Sh. Averbukh , Robert J. Gordon

We present a strategy for post-pulse orientation aiming both at efficiency and maximal duration within a rotational period. We first identify the optimally oriented states which fulfill both requirements. We show that a sequence of…

Quantum Physics · Physics 2007-05-23 D. Sugny , A. Keller , O. Atabek , D. Daems , C. M. Dion , S. Guérin , H. R. Jauslin

Genetic algorithms, as implemented in optimal control strategies, are currently successfully exploited in a wide range of problems in molecular physics. In this context, laser control of molecular alignment and orientation remains a very…

Chemical Physics · Physics 2007-05-23 O. Atabek , C. M. Dion

We review on the theoretical status of intense laser orientation and alignment. The evolution of the rotational wave packet and its dynamics leading to orientation and alignment is the topic of the present discussion. The major part of the…

Atomic Physics · Physics 2021-04-14 Vijit V. Nautiyal , Sumana Devi , Ashish Tyagi , Bhawna Vidhani , Anjali Maan , Vinod Prasad

The impact of nonadiabatic laser-induced molecular alignment on filamentation is numerically studied. Weak and strong field model of impulsive molecular alignment are compared in the context of nonlinear pulse propagation. It is shown that…

Optics · Physics 2014-12-03 N. Berti , P. Béjot , J. -P. Wolf , O. Faucher

We show that a linear molecule subjected to a short specific elliptically polarized laser field yields postpulse revivals exhibiting alignment alternatively located along the orthogonal axis and the major axis of the ellipse. The effect is…

Quantum Physics · Physics 2007-05-23 D. Daems , S. Guérin , E. Hertz , H. R. Jauslin , B. Lavorel , O. Faucher

We present a theoretical study of recent laser-alignment and mixed-field-orientation experiments of asymmetric top molecules. In these experiments, pendular states were created using linearly polarized strong ac electric fields from pulsed…

Experimental results, supported by precise modelling, demonstrate optimisation of a plasma-based injector with intermediate laser pulse energy ($<1$ J), corresponding to a normalised vector potential $a_0 = 2.15$, using ionisation injection…

A gradient-based optimization approach combined with automatic differentiation is employed to ensure high accuracy and scalability when working with high-dimensional parameter spaces. Numerical simulations confirm the effectiveness of the…

Quantum Physics · Physics 2025-07-15 Roman Sahakyan , Romik Sargsyan , Edgar Pogosyan , Karen Arzumanyan , Emil A. Gazazyan

We show that a combination of a half-cycle pulse and a short nonresonant laser pulse produces a strongly enhanced postpulse orientation. Robust transients that display both efficient and long-lived orientation are obtained. The mechanism is…

Quantum Physics · Physics 2007-05-23 D. Daems , S. Guérin , D. Sugny , H. R. Jauslin

We present a theoretical study of the impact of an electrostatic field combined with non-resonant linearly polarized laser pulses on the rotational dynamics of linear molecules. Within the rigid rotor approximation, we solve the…

Atomic Physics · Physics 2015-06-05 Juan J. Omiste , Rosario González-Férez

The present work reports on the generation of short-pulse coherent extreme ultraviolet radiation of controlled polarization. The proposed strategy is based on high-order harmonics generated in pre-aligned molecules. Field-free molecular…

We develop a mathematically simple yet accurate model for the single-pulse non-resonant impulsive alignment of thermal ensembles of linear molecules. We find that our molecular alignment model not only provides a simplification for…

Optics · Physics 2023-06-08 A. Löhr , M. Ivanov , M. Khokhlova

Fixing molecules in space is a crucial step for the imaging of molecular structure and dynamics. Here, we demonstrate three-dimensional (3D) field-free alignment of the prototypical asymmetric top molecule indole using elliptically…

Alignment and orientation of molecules by intense, ultrashort laser fields are crucial for a variety of applications in physics and chemistry. These include control of high harmonics generation, molecular orbitals tomography, control of…

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