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Beams of polar molecules can be focused using an array of electrostatic lenses in alternating gradient (AG) configuration. They can also be accelerated or decelerated by applying an appropriate high voltage switching sequence to the lenses.…

Cold supersonic beams of molecules can be slowed down using a switched sequence of electrostatic field gradients. The energy to be removed is proportional to the mass of the molecules. Here we report deceleration of YbF, which is 7 times…

Cold, continuous, high flux beams of benzonitrile, fluorobenzine, and anisole have been created. Buffer-gas cooling with a cryogenic gas provides the cooling and slow forward beam velocities. The beam of benzonitrile was measured to have a…

Chemical Physics · Physics 2014-07-21 David Patterson , John M. Doyle

A beam of polar molecules can be focused and transported through an ac electric quadrupole guide. At a given ac frequency, the transmission of the guide depends on the mass-to-dipole-moment (m/\textmu) ratio of the molecular quantum state.…

Atomic and Molecular Clusters · Physics 2017-09-13 Stephan Putzke , Frank Filsinger , Henrik Haak , Jochen Küpper , Gerard Meijer

We report on the focusing and guiding of the van der Waals complex formed between benzonitrile molecules (C$_6$H$_5$CN) and argon atoms in a cold molecular beam using an ac electric quadrupole guide. The distribution of quantum states in…

Atomic Physics · Physics 2013-01-15 Stephan Putzke , Frank Filsinger , Jochen Küpper , Gerard Meijer

The Stark deceleration of OH radicals in both low-field-seeking and high-field-seeking levels of the rovibronic ${}^2\Pi_{3/2},v=0,J=3/2$ ground state is demonstrated using a single experimental setup. Applying alternating-gradient…

Chemical Physics · Physics 2008-09-18 Kirstin Wohlfart , Frank Filsinger , Fabian Grätz , Jochen Küpper , Gerard Meijer

Supersonic beams of polar molecules are deflected using inhomogeneous electric fields. The quantum-state selectivity of the deflection is used to spatially separate molecules according to their quantum state. A detailed analysis of the…

Polar molecules, in strong-field seeking states, can be transported and focused by an alternating sequence of electric field gradients that focus in one transverse direction while defocusing in the other. We show, by calculation and…

Accelerator Physics · Physics 2014-11-18 Juris Kalnins , Glen Lambertson , Harvey Gould

We present an analysis of the deceleration and trapping of heavy diatomic molecules in low-field seeking states by a moving electric potential. This moving potential is created by a 'ring-decelerator', which consists of a series of…

We describe the production of cold, slow-moving LiH molecules. The molecules are produced in the ground state using laser ablation and supersonic expansion, and 68% of the population is transferred to the rotationally excited state using…

Atomic Physics · Physics 2015-05-13 S. K. Tokunaga , J. M. Dyne , E. A. Hinds , M. R. Tarbutt

Stark deceleration allows for precise control over the velocity of a pulsed molecular beam and, by the nature of its limited phase-space acceptance, reduces the energy width of the decelerated packet. We describe an alternate method of…

Atomic Physics · Physics 2015-05-13 L. P. Parazzoli , N. Fitch , D. S. Lobser , H. J. Lewandowski

We report on the production of a pulsed molecular beam of metastable NH ($a ^1\Delta$) radicals and present first results on the Stark deceleration of the NH ($a ^1\Delta, J=2, M\Omega=-4$) radicals from 550 m/s to 330 m/s. The decelerated…

We here report on the experimental realization of a microwave decelerator for neutral polar molecules, suitable for decelerating and focusing molecules in high-field-seeking states. The multi-stage decelerator consists of a cylindrical…

Chemical Physics · Physics 2015-06-04 Simon Merz , Nicolas Vanhaecke , Wolfgang Jäger , Melanie Schnell , Gerard Meijer

A Stark decelerator is an effective tool for controlling motional degrees of freedom of polar molecules. Due to technical limitations, many of the current Stark decelerators focus on molecules in low-field-seeking quantum states and are…

Atomic Physics · Physics 2017-05-25 Demitri Y. Balabanov , Liam M. Duffy

We present a theoretical study of the mixed-field-orientation of asymmetric top molecules in tilted static electric field and non-resonant linearly polarized laser pulse by solving the time-dependent Schr\"odinger equation. Within this…

Chemical Physics · Physics 2016-12-21 Juan J. Omiste , Rosario González-Férez

We present experiments on decelerating and trapping ammonia molecules using a combination of a Stark decelerator and a traveling wave decelerator. In the traveling wave decelerator a moving potential is created by a series of ring-shaped…

Detecting the internal state of polar molecules is a substantial challenge when standard techniques such as resonance-enhanced multi photon ionization (REMPI) or laser-induced fluorescense (LIF) do not work. As this is the case for most…

Atomic Physics · Physics 2014-12-01 Rosa Glöckner , Alexander Prehn , Gerhard Rempe , Martin Zeppenfeld

We demonstrate experimentally the guiding of cold and slow ND3 molecules along a thin charged wire over a distance of ~0.34 m through an entire molecular beam apparatus. Trajectory simulations confirm that both linear and quadratic…

Atomic and Molecular Clusters · Physics 2011-12-19 M. Strebel , S. Spieler , F. Stienkemeier , M. Mudrich

The manipulation of the motion of neutral molecules with electric or magnetic fields has seen tremendous progress over the last decade. Recently, these techniques have been extended to the manipulation of large and complex molecules. In…

Chemical Physics · Physics 2011-04-07 Frank Filsinger , Gerard Meijer , Henrik Stapelfeldt , Henry N. Chapman , Jochen Küpper

Recently, the extremely sensitive torsion-rotation transitions in methanol have been used to set a tight constraint on a possible variation of the proton-to-electron mass ratio over cosmological time scales. In order to improve this…

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