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We present a systematic and comparative study of the structural and electronic properties of Cu-based ternary and quaternary semiconductors using first-principles electronic structure approaches. The important role that Cu d electrons play…

Materials Science · Physics 2015-05-28 Yubo Zhang , Xun Yuan , Xiudong Sun , Bi-Ching Shih , Peihong Zhang , Wenqing Zhang

Orthorhombic GdFeO$_3$ has attracted considerable attention in recent years because its magnetic structure is similar to that in the well-known BiFeO$_3$ material. We investigate electronic structure, magnetism, and optical properties of…

Materials Science · Physics 2017-07-26 Xu-Hui Zhu , Xiang-Bo Xiao , Xiang-Rong Chen , Bang-Gui Liu

We have investigated the electronic structure of fluorite Cu$_{2}$Se using density functional theory calculations within the LDA, PBE and AM05 approximations as well as with the non-local hybrid PBE0 and HSE approximations. Our results show…

Materials Science · Physics 2013-03-04 Mikael Råsander , Lars Bergqvist , Anna Delin

We present a comprehensive ab initio investigation on Mg$_3$Bi$_2$, a promising Mg-ion battery anode material with high rate capacity. Through combined DFT (PBE, HSE06) and $G_0W_0$ electronic structure calculations, we find that…

Materials Science · Physics 2018-07-31 Jeongjae Lee , Bartomeu Monserrat , Ieuan Seymour , Zigeng Liu , Sian Dutton , Clare Grey

PbTiO$_3$ is a ferroelectric perovskite semiconductor with favourable electronic and optical properties, making it suitable for a wide range of applications, including photo-catalysis and (opto)electronic devices. Despite its relevance, an…

Materials Science · Physics 2025-12-03 Pietro Pacchioni , Lorenzo Varrassi , Cesare Franchini

Triphosphides, with a chemical formula of XP$_3$ (X is a group IIIA, IVA, or VA element), have recently attracted much attention due to their great potential in several applications. Here, using density functional theory calculations, we…

The electronic band structure of SrTiO$_3$ is investigated in the all-electron QS$GW$ approximation. Unlike previous pseudopotential based QS$GW$ or single-shot $G_0W_0$ calculations, the gap is found to be significantly overestimated…

Materials Science · Physics 2018-01-31 Churna Bhandari , Mark van Schilfgaarde , Takao Kotani , Walter R. L. Lambrecht

We present an extension of the quasiparticle self-consistent $GW$ approximation (QS$GW$) [Phys. Rev. B, 76 165106 (2007)] to include vertex corrections in the screened Coulomb interaction $W$. This is achieved by solving the Bethe-Salpeter…

Materials Science · Physics 2023-10-11 Brian Cunningham , Myrta Grüning , Dimitar Pashov , Mark van Schilfgaarde

Topological semimetals with several types of three-dimensional (3D) fermion of electrons, such as Dirac fermions, Weyl fermions, Dirac nodal lines and triply degenerate nodal points have been theoretically predicted and then experimentally…

Materials Science · Physics 2018-02-28 Sami Ullah , Jiangxu Li , Ronghan Li , Qing Xie , Hui Ma , Dianzhong Li , Yiyi Li , Xing-Qiu Chen

Two-dimensional (2D) van der Waals ferroelectrics are recognized for enabling many applications, from memory and logic to neuromorphic computing, as well as transforming other materials to control electronic phase transitions and…

The structural properties and the band structures of the charge-transfer insulating oxides SrO, MgO and SrTiO3 are computed both within density functional theory in the local density approximation (LDA) and in the Hedin's GW scheme for…

Condensed Matter · Physics 2009-10-31 G. Cappellini , S. Bouette-Russo , B. Amadon , C. Noguera , F. Finocchi

Applying numerical techniques to a model recently proposed for the one dimensional spin-Peierls compound CuGeO_3, we calculate dynamical properties that can be directly compared with inelastic neutron scattering data and angle-resolved…

Condensed Matter · Physics 2009-10-28 Stephan Haas , Elbio Dagotto

Ab initio investigation of the two porous coordination polymers Cu[Cu(pdt)$ _{2} $] and Cu[Ni(pdt)$ _{2} $] has been performed. The dispersion laws and partial density of states was obtained with the PBE0 hybrid functional. The results…

Materials Science · Physics 2021-01-20 S. V. Syrotyuk , Yu. V. Klysko

We use first-principles calculations to show that van der Waals (vdW) heterostructures consisting of few-layer Bi$_2$Se$_3$ and PtSe$_2$ exhibit electronic and spintronics properties that can be tuned by varying the constituent layers.…

Mesoscale and Nanoscale Physics · Physics 2020-12-15 Shahid Sattar , J. Andreas Larsson

BaBiO3 is a well-known example of a 3D charge density wavecompound, in which the CDW behavior is induced by charge disproportionation at the Bi site. At ambient pressure, this compound is a charge-ordered insulator, but little is known…

Strongly Correlated Electrons · Physics 2017-07-12 Andriy Smolyanyuk , Lilia Boeri , Cesare Franchini

The electronic properties of epitaxial heterojunctions consisting of the prototypical perovskite oxide semiconductor,n-SrTiO3 and the high-mobility Group IV semiconductor p-Ge have been investigated. Hard x-ray photoelectron spectroscopy…

Rutile GeO$_2$ is a visible and near-ultraviolet-transparent oxide that has not been explored for semiconducting applications in electronic and optoelectronic devices. We investigate the electronic and optical properties of rutile GeO$_2$…

Materials Science · Physics 2019-08-27 Kelsey A. Mengle , Sieun Chae , Emmanouil Kioupakis

First-principles calculations were performed to investigate the ferroelectric properties of barium titanate and bismuth ferrite, as well as phonon dispersion of BaTiO3, using density functional theory and density functional perturbation…

Materials Science · Physics 2014-12-08 Hong-Jian Feng

We investigate the band structure of BaBiO$_{3}$, an insulating parent compound of doped high-$T_{c}$ superconductors, using \emph{in situ} angle-resolved photoemission spectroscopy on thin films. The data compare favorably overall with…

Density functional theory and molecular dynamics simulations have been used to optimize the structure of nanowires of SiO2. The starting structures were based on b-cristobalite, orthotridymite, b-tridymite, and rutile crystals. The analysis…

Materials Science · Physics 2012-08-02 José I. Martínez , Federico Calle-Vallejo , Clifford M. Krowne , Julio A. Alonso