Related papers: On a new definition of quantum entropy

In a previous work (M. Campisi. Stud. Hist. Phil. M. P. 36 (2005) 275-290) we have addressed the mechanical foundations of equilibrium thermodynamics on the basis of the Generalized Helmholtz Theorem. It was found that the volume entropy…

We treat a quantum mechanical system with certain general properties which are expected to be common in macroscopic quantum systems. Starting from a PURE initial state (which may not describe an equilibrium) in which energy is mildly…

The second law of thermodynamics states that the entropy of an isolated system can only increase over time. This appears to conflict with the reversible evolution of isolated quantum systems under the Schr\"odinger equation, which preserves…

For a quantum state undergoing unitary Schr\"odinger time evolution, the von Neumann entropy is constant. Yet the second law of thermodynamics, and our experience, show that entropy increases with time. Ingarden introduced the quantum…

We initially prepare a quantum linear oscillator weakly coupled to a bath in equilibrium at an arbitrary temperature. We disturb this system by varying a Hamiltonian parameter of the coupled oscillator, namely, either its spring constant or…

In the article, on a new definition of quantum entropy, Campisi has explained an operator for entropy based on quantum number operator. It has been claimed that the expectation values for this operator increases for every non-quasi-static…

A new axiomatic characterization with a minimum of conditions for entropy as a function on the set of states in quantum mechanics is presented. Traditionally unspoken assumptions are unveiled and replaced by proven consequences of the…

We review our approach to the second law of thermodynamics, viewed as a theorem asserting the growth of the mean (Gibbs-von Neumann) entropy of quantum spin systems undergoing automorphic (unitary) adiabatic transformations. Non-automorphic…

In a macroscopic (quantum or classical) Hamiltonian system, we prove the second law of thermodynamics in the forms of the minimum work principle and the law of entropy increase, under the assumption that the initial state is described by a…

Quantum physics, despite its observables being intrinsically of a probabilistic nature, does not have a quantum entropy assigned to them. We propose a quantum entropy that quantify the randomness of a pure quantum state via a conjugate pair…

A quantum statistical expression for the entropy of a nonequilibrium system is defined so as to be consistent with Gibbs' relation, and is shown to corresponds to dynamical variable by introducing analogous to the Heisenberg picture in…

A quantum coordinate-entropy formulated in quantum phase space has been recently proposed together with an entropy law that asserts that such entropy can not decrease over time. The coordinate-entropy is dimensionless, a relativistic…

Based on quantum statistical mechanics and microscopic quantum dynamics, we prove Planck's and Kelvin's principles for macroscopic systems in a general and realistic setting. We consider a hybrid quantum system that consists of the…

All the laws of physics are time-reversible. Time arrow emerges only when ensembles of classical particles are treated probabilistically, outside of physics laws, and the entropy and the second law of thermodynamics are introduced. In…

This article is a short version of a longer article to appear in Physics Reports (cond-mat/9708200). The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of…

The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of entropy in irreversible adiabatic processes that take one equilibrium state to another. The entropy…

We derive the law of entropy non-decrease directly from the Kelvin-Planck principle for simple and compound systems without using the Clausius inequality. A key of the derivation is a new formulation of entropy in terms of work by a Carnot…

The essence of the second law of classical thermodynamics is the `entropy principle' which asserts the existence of an additive and extensive entropy function, S, that is defined for all equilibrium states of thermodynamic systems and whose…

Quantum mechanics is derived as an application of the method of maximum entropy. No appeal is made to any underlying classical action principle whether deterministic or stochastic. Instead, the basic assumption is that in addition to the…

The classical Second Law of Thermodynamics demands that an isolated system evolves with a non-diminishing entropy. This holds as well in quantum mechanics if the evolution of the energy-isolated system can be described by a unital quantum…