Related papers: Chemical Rates on Small Grains and PAHs: C^+ Recom…
We study the evolution of molecular hydrogen on the grain surfaces and in the gas phase using both the rate equation (which tracks the average number of molecules) and the master equation (which tracks the expectation values of molecules).…
The physical and chemical conditions in photodissociation regions (PDRs) are largely determined by the influence of far ultraviolet radiation. Far-UV photons can efficiently dissociate molecular hydrogen, a process that must be balanced at…
Methods: The microscopic equations of H2-formation and protonation are integrated numerically over time in such a manner that the overall structures evolve self-consistently under benign conditions. Results: The equilibrium H2 formation…
Recent experimental results on the formation of molecular hydrogen on astrophysically relevant surfaces under conditions similar to those encountered in the interstellar medium provided useful quantitative information about these processes.…
We calibrate the integrated luminosity from the polycyclic aromatic hydrocarbon (PAH) features at 6.2\micron, 7.7\micron\ and 11.3\micron\ in galaxies as a measure of the star-formation rate (SFR). These features are strong (containing as…
A knowledge of the recombination time on the grain surfaces has been a major obstacle in deciding the production rate of molecular hydrogen and other molecules in the interstellar medium. We present a numerical study to compute this time…
The molecular evolution that occurs in collapsing prestellar cores is investigated. To model the dynamics, we adopt the Larson-Penston (L-P) solution and analogues with slower rates of collapse. For the chemistry, we utilize the new…
Aims. Interstellar dust grains, because of their catalytic properties, are crucial to the formation of H2, the most abundant molecule in the Universe. The formation of molecular hydrogen strongly depends on the ability of H atoms to stick…
The CO-to-H$_2$ conversion factor ($\alpha_\mathrm{CO}$) is expected to vary with dust abundance and grain size distribution through the efficiency of shielding gas from CO-dissociation radiation. We present a comprehensive analysis of…
An analysis of the kinetics of H2 formation on interstellar dust grains is presented using rate equations. It is shown that semi-empirical expressions that appeared in the literature represent two different physical regimes. In particular,…
Continuous-time, random-walk Monte Carlo simulations of H2 formation on grains have been performed for surfaces that are stochastically heated by photons. We have assumed diffuse cloud conditions and used a variety of grains of varying…
Hydrogen sulfide (H$_2$S) is thought to be efficiently formed on grain surfaces through the successive hydrogenation of S atoms. Its non-detection so far in astronomical observations of icy dust mantles thus indicates that effective…
We use JWST/NIRCam and MIRI imaging acquired by the Feedback in Emerging extrAgalactic Star clusTers (FEAST) program along with archival HST imaging to map ionized gas (Pa$\alpha$, Br$\alpha$, and H$\alpha$) and Polycyclic Aromatic…
A prominent chemical reaction in interstellar clouds is the formation of molecular hydrogen by recombination, which essentially takes place on dust grain surfaces. Analytical approaches to model such a system have hitherto neglected the…
Combining Atacama Large Millimeter/sub-millimeter Array CO(2-1) mapping and JWST near- and mid-infrared imaging, we characterize the relationship between CO(2-1) and polycyclic aromatic hydrocarbon (PAH) emission at ~100 pc resolution in 70…
Glycoaldehyde, ethylene glycol, and methyl formate are complex organic molecules that have been observed in dark molecular clouds. Because there is no efficient gas-phase route to produce these species, it is expected that a low-temperature…
Unlike gas-phase reactions, chemical reactions taking place on interstellar dust grain surfaces cannot always be modeled by rate equations. Due to the small grain sizes and low flux,these reactions may exhibit large fluctuations and thus…
We used archival data acquired with the Copernicus satellite to reexamine CO column densities because self-consistent oscillator strengths are now available. Our focus is on lines of sight containing modest amounts of molecular species. Our…
We examine the UV reprocessing efficiencies of warm dust and polycyclic aromatic hydrocarbons (PAHs) through an analysis of the mid- and far-infrared surface luminosity densities of 85 nearby H$\alpha$-selected star-forming galaxies…
Context. The formation of water on the dust grains in the interstellar medium may proceed with hydrogen peroxide (H2O2) as an intermediate. Recently gas-phase H2O2 has been detected in {\rho} Oph A with an abundance of ~1E-10 relative to…