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An overview is given of recent advances in experimental and theoretical understanding of optical properties of ultra-thin crystal structures (graphene, phosphorene, silicene, MoS2, MoSe2 , WS2 , WSe2 , h-AlN, h-BN, fluorographene,…

Mesoscale and Nanoscale Physics · Physics 2016-03-02 H. Sahin , E. Torun , C. Bacaksiz , S. Horzum , J. Kang , R. T. Senger , F. M. Peeters

Graphene oxide can be used as a precursor to graphene but the quality of graphene flakes is highly heterogeneous. Scanning-Raman-Microscopy (SRM) is used to characterize films of graphene derived from flakes of graphene oxide with an almost…

Graphene-based materials (GBMs) constitute a large family of materials which has attracted great interest for potential applications. In this work, we apply first-principles calculations based on density functional theory (DFT) and fully…

Materials Science · Physics 2021-05-05 Enesio Marinho , Pedro A. S. Autreto

The unusual transport properties of graphene are the direct consequence of a peculiar bandstructure near the Dirac point. We determine the shape of the pi bands and their characteristic splitting, and the transition from a pure 2D to…

Materials Science · Physics 2007-05-23 Taisuke Ohta , Aaron Bostwick , J. L. McChesney , Thomas Seyller , Karsten Horn , Eli Rotenberg

Through a systematic structural search we found an allotrope of carbon with Cmmm symmetry which we predict to be more stable than graphite for pressures above 10 GPa. This material, which we refer to as Z-carbon, is formed by pure sp3 bonds…

In the case of graphene, hydrogenation removes the conductivity due to the bands forming the Dirac cone by opening up a band gap. This type of chemical functionalization is of utmost importance for electronic applications. As predicted by…

Materials Science · Physics 2017-12-07 W. Wang , W. Olovsson , R. I. G. Uhrberg

Graphene is a two-dimensional carbon material with a honeycomb lattice and Dirac-like low-energy excitations. When Zeeman and spin-orbit interactions are neglected its Landau levels are four-fold degenerate, explaining the $4 e^2/h$…

Mesoscale and Nanoscale Physics · Physics 2008-06-30 Kentaro Nomura , A. H. MacDonald

Graphene nanoribbons with sub-nanometer widths are extremely interesting for nanoscale electronics and devices as they combine the unusual transport properties of graphene with the opening of a band gap due to quantum confinement in the…

Carbon allotropes have a large family of materials with varieties of crystal structures and properties and can realize different topological phases. Using first principles calculations, we predict a new two-dimensional (2D) carbon…

Materials Science · Physics 2019-12-06 Heng Gao , Wei Ren

Silicene, a monolayer of silicon atoms tightly packed into a two-dimensional honeycomb lattice, is the challenging hypothetical reflection in the silicon realm of graphene, a one-atom thick graphite sheet, presently the hottest material in…

Materials Science · Physics 2008-11-18 A. Kara , C. Leandri , M. E. Davila , P. de Padova , B. Ealet , H. Oughaddou , B. Aufray , G. Le Lay

Due to the lack of two-dimensional silicon-based semiconductors and the fact that most of the components and devices are generated on single-crystal silicon or silicon-based substrates in modern industry, designing two-dimensional…

Mesoscale and Nanoscale Physics · Physics 2017-06-05 Yan Qian , Haiping Wu , Erjun Kan , Kaiming Deng

Graphene, a monolayer of carbon atoms packed into a two-dimensional crystal structure, attracted intense attention owing to its unique structure and optical, electronic properties. Recent advances in chemical vapor deposition (CVD) have led…

Materials Science · Physics 2020-10-23 Yu-Hao Deng

We report nanocrystalline carbon impurities coexisting with graphene synthesized via chemical vapor deposition (CVD) on platinum. We observe micron-size island-like impurity layers, which can easily be mistaken for second graphene layers in…

Mesoscale and Nanoscale Physics · Physics 2014-08-04 Jinglei Ping , Michael S. Fuhrer

Graphyne (GY) and graphdiyne (GDY)-based materials represent an intriguing class of two-dimensional (2D) carbon-rich networks with tunable structures and properties surpassing those of graphene. However, the challenge of fabricating…

A simple analysis is performed for the absorption properties of graphene; sandwiched between two media. For a proper choice of media and graphene doping/gating one can approach 50-100% absorption in the GHz-THz range for the one atom thick…

Optics · Physics 2012-01-17 S. P. Apell , G. W. Hanson , C. Hägglund

A series of carbon allotropes with novel optoelectronic and rich topological properties is predicted by systematic first-principles calculations. These fascinating carbon allotropes can be derived by inserting acetylenic linkages…

Materials Science · Physics 2021-08-12 Yan Gao , Chengyong Zhong , Shengyuan A. Yang , Kai Liu , Zhong-Yi Lu

Geometrically a crystal containing dislocations and disclinations can be envisaged as a `fixed frame' Cartan--Einstein space-time carrying torsion and curvature, respectively. We demonstrate that electrons in defected graphene are…

Mesoscale and Nanoscale Physics · Physics 2011-08-04 Andrej Mesaros , Darius Sadri , Jan Zaanen

Two-dimensional (2D) carbon materials play an important role in nanomaterials. We propose a new carbon monolayer, named hexagonal-4,4,4-graphyne (H4,4,4-graphyne), which is a nanoporous structure composed of rectangular carbon rings and…

Materials Science · Physics 2018-03-20 Linyang Li , Xiangru Kong , François M. Peeters

Graphene is a two dimensional crystal of carbon atoms with fascinating electronic and morphological properties. The low energy excitations of the neutral, clean system are described by a massless Dirac Hamiltonian in (2+1) dimensions which…

Strongly Correlated Electrons · Physics 2011-07-28 Maria A. H. Vozmediano

Adsorption is one important way applied to water decontamination, where carbon is commonly used as highly effective absorbent. Carbon of different morphologies and structures normally demonstrate distinct capabilities to adsorption-typed…

Materials Science · Physics 2017-05-02 Sun Ling