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In this work, the rate law for inhomogeneous concentration distributions has been formulated, by applying spatial integration over the products of species concentrations. Reaction rates for typical reactions have been investigated by…

Chemical Physics · Physics 2025-12-24 Xiang-Yuan Li , Xin-Yu Zhang , ChuanFeng Yue

Smoluchowski's coagulation equation is a mean-field model describing the growth of clusters by successive mergers. Since its derivation in 1916 it has been studied by several authors, using deterministic and stochastic approaches, with a…

Analysis of PDEs · Mathematics 2018-06-22 Philippe Laurençot

We report surprising steady oscillations in aggregation-fragmentation processes. Oscillating solutions are observed for the class of aggregation kernels $K_{i,j} = i^{\nu}j^{\mu} + j^{\nu}i^{\mu}$ homogeneous in masses $i$ and $j$ of…

Statistical Mechanics · Physics 2023-07-18 N. V. Brilliantov , W. Otieno , S. A. Matveev , A. P. Smirnov , E. E. Tyrtyshnikov , P. L. Krapivsky

The mesoscopic reaction-diffusion master equation (RDME) is a popular modeling framework, frequently applied to stochastic reaction-diffusion kinetics in systems biology. The RDME is derived from assumptions about the underlying physical…

Numerical Analysis · Mathematics 2015-06-23 Stefan Hellander , Andreas Hellander , Linda Petzold

We investigate irreversible aggregation in which monomer-monomer, monomer-cluster, and cluster-cluster reactions occur with constant but distinct rates K_{MM}, K_{MC}, and K_{CC}, respectively. The dynamics crucially depends on the ratio…

Statistical Mechanics · Physics 2009-11-10 M. Mobilia , P. L. Krapivsky , S. Redner

The paper outlines an exact combinatorial approach to finite coagulating systems. In this approach, cluster sizes and time are discrete, and the binary aggregation alone governs the time evolution of the systems. By considering the growth…

Statistical Mechanics · Physics 2018-02-21 Agata Fronczak , Anna Chmiel , Piotr Fronczak

We study a coupled thermo-diffusion system that accounts for the dynamics of hot colloids in periodically heterogeneous media. Our model describes the joint evolution of temperature and colloidal concentrations in a saturated porous…

Analysis of PDEs · Mathematics 2017-04-07 Vo Anh Khoa , Adrian Muntean

We show that solutions to Smoluchowski's equation with a constant coagulation kernel and an initial datum with some regularity and exponentially decaying tail converge exponentially fast to a self-similar profile. This convergence holds in…

Analysis of PDEs · Mathematics 2010-02-02 José Alfredo Cañizo , Stéphane Mischler , Clément Mouhot

We present a combined analytical and numerical approach based on the Mori projection operator formalism and Monte Carlo simulations to study surface diffusion within the lattice-gas model. In the present theory, the average jump rate and…

Soft Condensed Matter · Physics 2009-10-30 T. Hjelt , I. Vattulainen , J. Merikoski , T. Ala-Nissila , S. C. Ying

We study conserved one-dimensional models of particle diffusion, attachment and detachment from clusters, where the detachment rates decrease with increasing cluster size as gamma(m) ~ m^{-k}, k>0. Heuristic scaling arguments based on…

Statistical Mechanics · Physics 2009-11-13 F. D. A. Aarao Reis , R. B. Stinchcombe

We consider the (smoothed) average correlation between the density of energy levels of a disordered system, in which the Hamiltonian is equal to the sum of a deterministic H0 and of a random potential $\varphi$. Remarkably, this correlation…

High Energy Physics - Theory · Physics 2009-10-28 E. Brezin , S. Hikami , A. Zee

We consider the scaling solutions of Smoluchowski's equation of irreversible aggregation, for a non gelling collision kernel. The scaling mass distribution f(s) diverges as s^{-tau} when s->0. tau is non trivial and could, until now, only…

Statistical Mechanics · Physics 2016-08-31 Stephane Cueille , Clement Sire

We characterize the long-time behaviour of solutions to Smoluchowski's coagulation equation with a diagonal kernel of homogeneity $\gamma < 1$. Due to the property of the diagonal kernel, the value of a solution depends only on a discrete…

Analysis of PDEs · Mathematics 2016-08-11 Philippe Laurençot , Barbara Niethammer , Juan J. L. Velázquez

The Smoluchowski coagulation-diffusion PDE is a system of partial differential equations modelling the evolution in time of mass-bearing Brownian particles which are subject to short-range pairwise coagulation. This survey presents a fairly…

Probability · Mathematics 2019-02-14 Alan Hammond

In many biological situations, a species arriving from a remote source diffuses in a domain confined between two parallel surfaces until it finds a binding partner. Since such a geometric shape falls in between two- and three-dimensional…

Chemical Physics · Physics 2019-11-05 Denis S. Grebenkov , Diego Krapf

We study stochastic particle systems on a complete graph and derive effective mean-field rate equations in the limit of diverging system size, which are also known from cluster aggregation models. We establish the propagation of chaos under…

Probability · Mathematics 2021-07-21 Watthanan Jatuviriyapornchai , Stefan Grosskinsky

We develop a new fast-diffusion approximation for the kinetics of deposition of extended objects on a linear substrate, accompanied by diffusional relaxation. This new approximation plays the role of the mean-field theory for such processes…

Condensed Matter · Physics 2010-10-12 Vladimir Privman , Mustansir Barma

Spatially-distributed, nonequilibrium chemical systems described by a Markov chain model are considered. The evolution of such systems arises from a combination of local birth-death reactive events and random walks executed by the particles…

chao-dyn · Physics 2009-10-31 Mikhail V. Velikanov , Raymond Kapral

The cluster mean-field approximations are performed, up to 13 cluster sizes, to study the critical behavior of the driven pair contact process with diffusion (DPCPD) and its precedent, the PCPD in one dimension. Critical points are…

Statistical Mechanics · Physics 2007-05-23 Su-Chan Park , Hyunggyu Park

The $A + B\to 0$ diffusion-limited reaction, with equal initial densities $a(0) = b(0) = n_0$, is studied by means of a field-theoretic renormalization group formulation of the problem. For dimension $d > 2$ an effective theory is derived,…

Condensed Matter · Physics 2009-10-22 Benjamin P. Lee , John Cardy