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We provide a theoretical description of dynamical heterogeneities in glass-forming liquids, based on the premise that relaxation occurs via local rearrangements coupled by elasticity. In our framework, the growth of the dynamical…

Soft Condensed Matter · Physics 2023-11-02 Ali Tahaei , Giulio Biroli , Misaki Ozawa , Marko Popović , Matthieu Wyart

Fragility, quantifying the rapidity of variation of relaxation times, is analysed for a series of model glass formers, which differ in the softness of their interparticle interactions. In an attempt to rationalize experimental observations…

Soft Condensed Matter · Physics 2017-05-30 Anshul D. S. Parmar , Pallabi Kundu , Srikanth Sastry

We consider the dynamics of a diluted mean-field spin glass model in the aging regime. The model presents a particularly rich heterogeneous behavior. In order to catch this behavior, we perform a **spin-by-spin analysis** for a **given…

Disordered Systems and Neural Networks · Physics 2009-11-07 Andrea Montanari , Federico Ricci-Tersenghi

We study aging dynamics in two non-disordered spin models with multi-spin interactions, following a sudden quench to low temperature. The models are relevant to the physics of supercooled liquids. Their low temperature dynamics resemble…

Statistical Mechanics · Physics 2009-11-11 Robert L. Jack , Ludovic Berthier , Juan P. Garrahan

We show, using molecular dynamics simulations, that a two-dimensional Lennard-Jones solid is subject to droplet fluctuations characterized by {\em non-affine} deviations from local crystallinity. The fraction of particles in these droplets…

Materials Science · Physics 2013-05-29 Tamoghna Das , Surajit Sengupta , Madan Rao

The systematic identification of temperature scales in supercooled liquids that are key to understanding those liquids' underlying glass properties, and the latter's formation-history dependence, is a challenging task. Here we study the…

Soft Condensed Matter · Physics 2021-01-05 Karina González-López , Edan Lerner

Aging to the equilibrium liquid state of organic glasses is studied. The glasses were prepared by cooling the liquid to temperatures just below the glass transition. Aging following a temperature jump was studied by measuring the dielectric…

Soft Condensed Matter · Physics 2013-01-29 Tina Hecksher , Niels Boye Olsen , Kristine Niss , Jeppe C. Dyre

Glass formers are in general classified as strong or fragile depending on whether their relaxation rates follow Arrhenius or super-Arrhenius temperature dependence. There are however notable exceptions such as water, which exhibit a…

Soft Condensed Matter · Physics 2023-01-06 Chin-Yuan Ong , Chun-Shing Lee , Xin-Yuan Gao , Qiang Zhai , Rui Shi , Hai-Yao Deng , Chi-Hang Lam

The interplay of slow dynamics and thermodynamic features of dense liquids is studied by examinining how the glass transition changes depending on the presence or absence of Lennard-Jones-like attractions. Quite different thermodynamic…

Materials Science · Physics 2009-11-13 Th. Voigtmann

With molecular dynamics simulations of a fluid mixture of classical particles interacting with pair-wise additive Weeks-Chandler-Andersen potentials, we consider the time series of particle displacements and thereby determine distributions…

Statistical Mechanics · Physics 2011-11-10 Lester O. Hedges , Lutz Maibaum , David Chandler , Juan P. Garrahan

Molecular anisotropy plays an important role in the glass transition of a liquid. Recently, a novel bulk glass state has been discovered by optical microscopy experiments on suspensions of ellipsoidal colloids. 'Liquid glass' is a…

Soft Condensed Matter · Physics 2024-05-16 Mohammed Alhissi , Andreas Zumbusch , Matthias Fuchs

The theory developed in our previous papers is applied in this paper to investigate the dependence of slowing down of dynamics of glass-forming liquids on the attractive and repulsive parts of intermolecular interactions. Through an…

Soft Condensed Matter · Physics 2021-05-12 Ankit Singh , Yashwant Singh

We assess the relative importance of spatial congestion and lowered temperature in the slowing dynamics of supercooled glycerol near the glass transition. We independently vary both volume, V, and temperature, T, by applying high pressure…

Soft Condensed Matter · Physics 2007-05-23 Kyaw Zin Win , Narayanan Menon

Glassy behavior is a generic feature of electrons close to disorder-driven metal-insulator transitions. Deep in the insulating phase, electrons are tightly bound to impurities, and thus classical models for electron glasses have long been…

Strongly Correlated Electrons · Physics 2009-11-10 V. Dobrosavljevic

A glass is a non-equilibrium thermodynamic state whose physical properties depend on time. Glass formation from the melt, as well as the inverse process of liquid structural recovery from the glass are non-equilibrium processes. A positive…

Soft Condensed Matter · Physics 2020-02-19 H. Jabraoui , S. Ouaskit , J. Richard , J. -L Garden

Apart from not having crystallized, supercooled liquids can be considered as being properly equilibrated and thus can be described by a few thermodynamic control variables. In contrast, glasses and other amorphous solids can be arbitrarily…

Disordered Systems and Neural Networks · Physics 2017-10-10 Vassiliy Lubchenko , Peter G. Wolynes

The aim of this paper is to discuss some basic notions regarding generic glass forming systems composed of particles interacting via soft potentials. Excluding explicitly hard-core interaction we discuss the so called `glass transition' in…

Disordered Systems and Neural Networks · Physics 2009-11-13 Jean-Pierre Eckmann , Itamar Procaccia

We study concentrated binary colloidal suspensions, a model system which has a glass transition as the volume fraction $\phi$ of particles is increased. We use confocal microscopy to directly observe particle motion within dense samples…

Soft Condensed Matter · Physics 2011-05-20 Takayuki Narumi , Scott V. Franklin , Kenneth W. Desmond , Michio Tokuyama , Eric R. Weeks

We introduce a new quantity to probe the glass transition. This quantity is a linear generalized compressibility which depends solely on the positions of the particles. We have performed a molecular dynamics simulation on a glass forming…

Disordered Systems and Neural Networks · Physics 2007-05-23 Herve M. Carruzzo , Clare C. Yu

A mesoscopic model is proposed to explain the anomalous dynamics in a supercooled liquid as its glass transition temperature is approached from above. The model is based on the assumption of $\beta$ organized $\alpha$ process, with the…

Soft Condensed Matter · Physics 2007-05-23 Dwaipayan Chakrabarti , Biman Bagchi