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We carry out a layer-by-layer investigation to understand electron transport across metal-insulator-metal junctions. Interfacial structures of junctions were studied and characterized using first-principles density functional theory within…

Mesoscale and Nanoscale Physics · Physics 2017-03-02 Yun-Peng Wang , X. -G. Zhang , J. N. Fry , Hai-Ping Cheng

Ever since the high thermal conductivity in cubic boron arsenide (c-BAs) was predicted theoretically by Lindsay et. al in 2013, countless studies have zeroed in on this particular material. Most recently, c-BAs has been confirmed…

Materials Science · Physics 2018-11-15 Charles Shi , Xuan Luo

Built-in electric fields across heterojunctions between semiconducting materials underpin the functionality of modern device technologies. Heterojunctions between semiconductors and epitaxially grown crystalline oxides provide a rich…

Recent predictions and experimental observations of high Tc superconductivity in hydrogen-rich materials at very high pressures are driving the search for superconductivity in the vicinity of room temperature. We have developed a novel…

The electronic transport properties and switching mechanism of single photochromic diarylethene derivatives sandwiched between two gold surfaces with closed and open configurations are investigated by a fully self-consistent nonequilibrium…

Other Condensed Matter · Physics 2009-11-13 Jing Huang , Qunxiang Li , Hao Ren , Haibin Su , Q. W. Shi , Jinlong Yang

We explore the thermodynamic geometry of a simple system that models the bistable dynamics of nucleic acid hairpins in single molecule force-extension experiments. Near equilibrium, optimal (minimum-dissipation) driving protocols are…

Statistical Mechanics · Physics 2016-11-04 David A. Sivak , Gavin E. Crooks

Methanol is an important tracer to probe physical and chemical conditions in the interstellar medium of galaxies. Methanol is also the most sensitive target molecule for probing potential space-time variations of the proton-electron mass…

Astrophysics of Galaxies · Physics 2021-08-04 S. Muller , W. Ubachs , K. M. Menten , C. Henkel , N. Kanekar

Quantum emitters in hexagonal Boron Nitride (hBN) were recently reported to hol a homogeneous linewidth according to the Fourier-Transform limit up to room temperature. This unusual observation was traced back to decoupling from in-plane…

Mesoscale and Nanoscale Physics · Physics 2020-10-02 Michael Hoese , Prithvi Reddy , Andreas Dietrich , Michael K. Koch , Konstantin G. Fehler , Marcus W. Doherty , Alexander Kubanek

The conductance of a single-atom contact is sensitive to the coupling of this contact atom to the atoms in the leads. Notably for the transition metals this gives rise to a considerable spread in the observed conductance values. The mean…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 S. K. Nielsen , Y. Noat , M. Brandbyge , R. H. M. Smit , K. Hansen , L. Y. Chen , A. I. Yanson , F. Besenbacher , J. M. van Ruitenbeek

Proper design and manufacturing thermal bridges based on molecular junctions at the contact between graphene platelets or other thermally conductive nanoparticles would provide a fascinating way to produce efficient heat transport networks…

Materials Science · Physics 2017-11-07 Alessandro Di Pierro , Guido Saracco , Alberto Fina

The electric conductance of Rh atomic contacts was investigated under the electrochemical potential control. The conductance histogram of Rh atomic contacts varied with the electrochemical potential. When the electrochemical potential of…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 Tatsuya Konishi , Manabu Kiguchi , Kei Murakoshi

Hexagonal boron nitride (h-BN) is a promising two-dimensional insulator with a large band gap and low density of charged impurities that is isostructural and isoelectronic with graphene. Here we report the chemical and atomic-scale…

We present a state-of-the-art first-principles analysis of electronic transport in a Pt nanocontact in the presence of H2 which has been recently reported by Smit et al. in Nature 419, 906 (2002). Our results indicate that at the last…

Materials Science · Physics 2009-11-10 Yamila Garcia , J. J. Palacios , E. San Fabian , J. A. Verges , A. J. Perez-Jimenez , E. Louis

In this contribution we demonstrate structural control over a transport resonance in HS(CH$_{2}$)$_{n}$[1,4 - C$_{6}$H$_{4}$](CH$_{2}$)$_{n}$SH (n = 1, 3, 4, 6) metal - molecule - metal junctions, fabricated and tested using the scanning…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 Carly Brooke , Andrea Vezzoli , Simon J. Higgins , Linda A. Zotti , J. J. Palacios , Richard J. Nichols

We have investigated the intermediate valence narrow-gap semiconductor SmB6 at low temperatures using both conventional spear-anvil type point contacts as well as mechanically controllable break junctions. The zero-bias conductance varied…

Strongly Correlated Electrons · Physics 2009-11-07 K. Flachbart , K. Gloos , E. Konovalova , Y. Paderno , M. Reiffers , P. Samuely , P. Svec

We developed a combined atomistic-continuum hierarchical multiscale approach to explore the effective thermal conductivity of graphene laminates. To this aim, we first performed molecular dynamics simulations in order to study the heat…

Materials Science · Physics 2017-04-07 B Mortazavi , T Rabczuk

Temperature ($T$) dependent conductance $G = G(T)$ data measured in molecular junctions are routinely taken as evidence for a two-step hopping mechanism. The present paper emphasizes that this is not necessarily the case. A curve of $\ln G$…

Mesoscale and Nanoscale Physics · Physics 2022-12-01 Ioan Baldea

Vibrational nonequilibrium effects in charge transport through single-molecule junctions are investigated. Focusing on molecular bridges with multiple electronic states, it is shown that electronic-vibrational coupling triggers a variety of…

Mesoscale and Nanoscale Physics · Physics 2011-03-15 R. Härtle , C. Benesch , M. Thoss

We present the first in a series of microscopic studies of electrical transport through individual molecules with metallic contacts. We view the molecules as ``heterostructures'' composed of chemically well-defined atomic groups, and…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Yongqiang Xue , Mark A. Ratner

Atomic-sized lead (Pb) contacts are deposited and dissolved in an electrochemical environment, and their transport properties are measured. Due to the electrochemical fabrication process, we obtain mechanically unstrained contacts and…

Mesoscale and Nanoscale Physics · Physics 2010-09-21 F. -Q. Xie , F. Hüser , F. Pauly , Ch. Obermair , G. Schön , Th. Schimmel