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We consider a statistical mechanics model for biopolymers. Sophisticated polymer chains, such as DNA, have stiffness when they stretch chains. The Laplacian interaction is used to describe the stiffness. Also, the surface between two media…

Probability · Mathematics 2014-08-05 Chien-Hao Huang

Consider directed polymers in a random environment on the complete graph of size $N$. This model can be formulated as a product of i.i.d. $N\times N$ random matrices and its large time asymptotics is captured by Lyapunov exponents and the…

Probability · Mathematics 2018-01-22 Francis Comets , Gregorio R. Moreno Flores , Alejandro F. Ramirez

A variational framework is developed to examine the equilibrium states of a semi-flexible polymer that is constrained to lie on a fixed surface. As an application the confinement of a closed polymer loop of fixed length $2\pi R$ within a…

Soft Condensed Matter · Physics 2012-02-17 Jemal Guven , Pablo Vázquez-Montejo

Dendronized polymers consist of an elastic backbone with a set of iterated branch structures (dendrimers)attached at every base point of the backbone. The conformations of such molecules depend on the elastic deformation of the backbone and…

Chaotic Dynamics · Physics 2015-03-17 François Gay-Balmaz , Darryl D. Holm , Vakhtang Putkaradze , Tudor S. Ratiu

We study the dynamics and conformation of polymers composed by active monomers. By means of Brownian dynamics simulations we show that when the direction of the self-propulsion of each monomer is aligned with the backbone, the polymer…

Soft Condensed Matter · Physics 2018-11-28 Valentino Bianco , Emanuele Locatelli , Paolo Malgaretti

Polymer chains dissolved in a solvent take random conformations due to large internal degrees of freedom and are characterized geometrically by their average shape and size. The diffusive dynamics of such large macromolecules play an…

Soft Condensed Matter · Physics 2023-07-11 Prabeen Kumar Pattnayak , Aloke Kumar , Gaurav Tomar

We consider the topologically constrained random walk model for topological polymers. In this model, the polymer forms an arbitrary graph whose edges are selected from an appropriate multivariate Gaussian which takes into account the…

Statistical Mechanics · Physics 2022-11-30 Jason Cantarella , Tetsuo Deguchi , Clayton Shonkwiler , Erica Uehara

We propose a two-body spherically symmetric (isotropic) potential such that particles interacting by the potential self assemble into linear semiflexible polymeric chains without branching. By suitable control of the potential parameters we…

Soft Condensed Matter · Physics 2018-05-09 Alex Abraham , Apratim Chatterji

The sequence of random probability measures $\nu_n$ that gives a path of length $n$, $\unsur{n}$ times the sum of the random weights collected along the paths, is shown to satisfy a large deviations principle with good rate function the…

Probability · Mathematics 2008-08-29 Philippe Carmona

The adsorption of polydisperse ideal polymer chains is shown to be sensitive to the large N tail of the distribution of chains. If and only if the number of chains decays more slowly than exponentially then there is an adsorption transition…

Soft Condensed Matter · Physics 2009-10-31 Richard P. Sear

Helices are not generic outcomes of polymer collapse. Collapsed conformations of semiflexible polymers with isotropic attractions typically form globules, toroids, or rod-like structures, as seen in simulations and described by…

Statistical Mechanics · Physics 2026-03-31 Biman Bagchi

The subject of this work is the adsorption transition of a long flexible self-avoiding polymer chain onto a rigid thin rod. The rod is represented by a cylinder of radius R with a short-ranged attractive surface potential for the chain…

Statistical Mechanics · Physics 2009-11-11 Andreas Hanke

Through extensive molecular simulations we determine a phase diagram of attractive, flexible polymer chains in two and three dimensions. A surprisingly rich collection of distinct crystal morphologies appear, which can be finely tuned…

Through extensive Monte Carlo simulations, we systematically study the effect of chain stiffness on the packing ability of linear polymers composed of hard spheres in extremely confined monolayers, corresponding effectively to 2D films.…

We investigate the kinetics of a polymer collapse due to the formation of irreversible crosslinks between its monomers. Using the contact probability $P(s)$ as a scale-dependent order parameter depending on the chemical distance $s$, our…

Soft Condensed Matter · Physics 2018-08-15 Vittore F. Scolari , Guillaume Mercy , Romain Koszul , Annick Lesne , Julien Mozziconacci

Conformation-dependent design of polymer sequences can be considered as a tool to control macromolecular self-assembly. We consider the monomer unit sequences created via the modification of polymers in a homogeneous melt in accordance with…

Soft Condensed Matter · Physics 2021-07-07 Elena N. Govorun , Ruslan M. Shupanov , Sophia A. Pavlenko , Alexei R. Khokhlov

The interplay of topological constraints, excluded volume interactions, persistence length and dynamical entanglement length in solutions and melts of linear chains and ring polymers is investigated by means of kinetic Monte Carlo…

Statistical Mechanics · Physics 2009-10-31 M. Mueller , J. P. Wittmer , J. -L. Barrat

We report the results of extensive Dynamic Monte Carlo simulations of systems of self-assembled Equilibrium Polymers without rings in good solvent. Confirming recent theoretical predictions, the mean-chain length is found to scale as $\Lav…

Soft Condensed Matter · Physics 2009-10-31 J. P. Wittmer , A. Milchev , M. E. Cates

We study random heteropolymer chain with gaussian distribution of kinds of monomers. The long-range correlations between kinds of monomers were introduce. The mean-field analysis of such heteropolymer indicates the existence of infinite…

Soft Condensed Matter · Physics 2009-09-25 E. Sh. Mamasakhlisov , V. F. Morozov , M. S. Shahinian

We use Newtonian and overdamped Langevin dynamics to study long flexible polymers dragged by an external force at a constant velocity $v$. The work $W$ by that force depends on the initial state of the polymer and the details of the…

Statistical Mechanics · Physics 2017-08-30 Raz Halifa Levi , Yacov Kantor
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