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Surface-active agents (surfactants) release potential energy as they migrate from one of two adjacent fluids onto their fluid-fluid interface, a process that profoundly impacts the system's energy and entropy householding. The continuum…

Fluid Dynamics · Physics 2024-05-29 T. B. van Sluijs , S. K. F. Stoter , E. H. van Brummelen

The interface temperature of two rods with equal cross section joined at one end and with different initial temperatures, initially always acquires the value characteristic for two semi-infinite rods. This value, which is shown to be a…

Classical Physics · Physics 2010-06-14 T Kranjc , J Peternelj

A map from the initial conditions to the values of the function and its first spatial derivative evaluated at the interface is constructed for the heat equation on finite and infinite domains with $n$ interfaces. The existence of this map…

Analysis of PDEs · Mathematics 2016-04-11 Natalie E. Sheils , Bernard Deconinck

Four results associated with the diffuse-interface model (DIM) for contact lines are reported in this paper. First, a boundary condition is derived, which states that the fluid near a solid wall must have a certain density $\rho_{0}$…

Fluid Dynamics · Physics 2021-09-27 E. S. Benilov

So far the problem of interface behavior upon phase transition has not yet acquired a satisfactory mathematical formulation due to a variety of the physical phenomena involved. Analytical solutions exist only for elementary problems…

Statistical Mechanics · Physics 2011-08-12 Alex Guskov

All current formulations of nonequilibrium thermodynamics of open chemical reaction networks rely on the assumption of non-interacting species. We develop a general theory which accounts for interactions between chemical species within a…

Statistical Mechanics · Physics 2021-03-09 Francesco Avanzini , Emanuele Penocchio , Gianmaria Falasco , Massimiliano Esposito

We briefly review some equilibrium and nonequilibrium properties of systems with long-range interactions. Such systems, which are characterized by a potential that weakly decays at large distances, have striking properties at equilibrium,…

Statistical Mechanics · Physics 2009-11-13 Stefano Ruffo

It is common belief that the equilibrium contact angle, corresponding to the minimum system energy state, lies between advancing and receding contact angles. Here, we derive advancing and receding contact angles considering the micro…

We establish that boundary degrees of freedom associated with a generic co-dimension one null surface in $D$ dimensional pure Einstein gravity naturally admit a thermodynamical description. We expect the $\textit{null surface…

High Energy Physics - Theory · Physics 2022-03-23 H. Adami , M. M. Sheikh-Jabbari , V. Taghiloo , H. Yavartanoo

The contact angle of a liquid drop on a rigid surface is determined by the classical theory of Young-Laplace. For chemically homogeneous surfaces, this angle is a constant. We study the minimal-energy configurations of liquid drops on rough…

Mathematical Physics · Physics 2017-08-03 Gershon Wolansky

In terms of fundamental principles of quantum theory of interacting particles and relativistic kinetic theory there was carried out an analysis of the main principle of standard cosmological scenario - the initial existence of local…

General Relativity and Quantum Cosmology · Physics 2011-06-21 Yurii G. Ignatyev

Motivated by solid-solid phase transitions in elastic thin films, we perform a Gamma-convergence analysis for a singularly perturbed energy describing second order phase transitions in a domain of vanishing thickness. Under a two-wells…

Analysis of PDEs · Mathematics 2012-02-29 Bernardo Galvão-Sousa , Vincent Millot

In this paper, we use a unified framework introduced in [3] to study two classes of nonconforming immersed finite element (IFE) spaces with integral value degrees of freedom. The shape functions on interface elements are piecewise…

Numerical Analysis · Mathematics 2018-10-19 Ruchi Guo , Tao Lin , Xu Zhang

We develop a theory of the effective disorder temperature in glass-forming materials driven away from thermodynamic equilibrium by external forces. Our basic premise is that the slow configurational degrees of freedom of such materials are…

Materials Science · Physics 2015-05-13 Eran Bouchbinder , J. S. Langer

Thermodynamics is a well developed tool to study systems in equilibrium but no such general framework is available for non-equilibrium processes. Only hope for a quantitative description is to fall back upon the equilibrium language as…

Statistical Mechanics · Physics 2015-05-14 Poulomi Sadhukhan , Somendra M. Bhattacharjee

Geometrical approach to the phenomenological theory of phase transitions of the second kind at constant pressure $P$ and variable temperature $T$ is proposed. Equilibrium states of a system at zero external field and fixed $P$ and $T$ are…

Condensed Matter · Physics 2019-08-17 A. K. Kanyuka , V. S. Glukhov

In the scalar theory of gravitation with a preferred reference frame, a consistent formulation of electrodynamics in the presence of gravitation needs to introduce an additional energy tensor: the interaction energy tensor. This energy is…

General Physics · Physics 2023-02-21 Mayeul Arminjon

Thermodynamics provides a unified perspective of thermodynamic properties of various substances. To formulate thermodynamics in the language of sophisticated mathematics, thermodynamics is described by a variety of differential geometries,…

Mathematical Physics · Physics 2023-03-13 Shin-itiro Goto

We present to the community a surface-definition problem, whose solution we consider to be critical for the proper description of contacts between nominally flat surfaces [1,2]. In 2015, M\"user and Dapp issued the Contact Mechanics…

Materials Science · Physics 2022-06-28 Tevis D. B. Jacobs , Nathaniel Miller , Martin H. Müser , Lars Pastewka

The application of the Young-Laplace equation to a solid-liquid interface is considered. Computer simulations show that the pressure inside a solid cluster of hard spheres is smaller than the external pressure of the liquid (both for small…

Soft Condensed Matter · Physics 2024-01-24 P. Montero de Hijes , K. Shi , E. G. Noya , E. E. Santiso , K. E. Gubbins , E. Sanz , C. Vega