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We present a theoretical study of wetting phenomena and interactions between liquid-vapor interfaces based on the density functional theory. The focus is mostly on the impact of long-range van der Waals interactions both within the fluid…

Chemical Physics · Physics 2011-11-10 Arik Yochelis , Len M. Pismen

We discuss the effect of an external electric field on the wetting of a solid surface by liquid. To this end, we use a model of the two-level-atom fluid for which the changes in interatomic interactions due to the presence of the field can…

Soft Condensed Matter · Physics 2017-02-20 Vasyl Myhal , Oleg Derzhko

Surface tension and wetting are dominating physical effects in micro and nanoscale flows. We present an efficient and reliable model of surface tension and equilibrium contact angles in Smoothed Particle Hydrodynamics for free-surface…

Fluid Dynamics · Physics 2024-05-22 Michael Blank , Prapanch Nair , Thorsten Pöschel

Soft interfaces can mediate interactions between particles bound to them. The force transmitted through the surface geometry on a particle may be expressed as a closed line integral of the surface stress tensor around that particle. This…

Soft Condensed Matter · Physics 2007-05-23 Martin Michael Mueller , Markus Deserno , Jemal Guven

We study the dependence of the surface tension of a fluid interface on the density profile of a third suspended phase. By means of an approximated model for the binary mixture and of a perturbative approach we derive close formulas for the…

Statistical Mechanics · Physics 2021-02-03 Alessio Squarcini , Paolo Malgaretti

Interface free energy is the contribution to the free energy of a system due to the presence of an interface separating two coexisting phases at equilibrium. It is also called surface tension. The content of the paper is 1) the definition…

Statistical Mechanics · Physics 2009-11-30 C. -E. Pfister

Depletion of the liquid density near a solid surface with a weak long-range fluid-surface interaction was studied by computer simulations of the liquid-vapor coexistence of a LJ fluid confined in slitlike pores. In a wide temperature range…

Statistical Mechanics · Physics 2015-06-25 A. Oleinikova , I. Brovchenko , A. Geiger

Liquid wetting of a surface is omnipresent in nature and the advance of micro-fabrication and assembly techniques in recent years offers increasing ability to control this phenomenon. Here, we identify how surface roughness influences the…

The surface energy is one of the fundamental properties nuclei, appearing in the simplest form of the semi-empirical mass formula. The surface enery has an influence on e.g. the shape of a nucleus and its ability to deform. This in turn…

Nuclear Theory · Physics 2020-04-22 P. D. Stevenson

We propose a novel three-way coupling method to model the contact interaction between solid and fluid driven by strong surface tension. At the heart of our physical model is a thin liquid membrane that simultaneously couples to both the…

Fluid Dynamics · Physics 2021-05-19 Liangwang Ruan , Jinyuan Liu , Bo Zhu , Shinjiro Sueda , Bin Wang , Baoquan Chen

We use a simple generic model to study the desorption of atoms from a solid surface in contact with a liquid, by using a combination of Monte Carlo and molecular dynamics simulations. The behavior of the system depends on two parameters:…

Chemical Physics · Physics 2022-11-16 Krishna Jaiswal , Horia Metiu , Vishal Agarwal

We study wetting droplets formed of active Brownian particles in contact with a repulsive potential barrier, in a wedge geometry. Our numerical results demonstrate a transition between partially wet and completely wet states, as a function…

Statistical Mechanics · Physics 2023-10-12 Francesco Turci , Robert L. Jack , Nigel B. Wilding

Viscoelasticity and rate-dependent adhesion of soft matter lead to difficulties in modeling the 'relatively simple' problem of a rigid sphere in contact with a viscoelastic half-space. For this reason, approximations in describing surface…

Soft Condensed Matter · Physics 2021-12-08 Luciano Afferrante , Guido Violano

We present a model for computing the surface force density on a fluid ellipsoid in simple shear flow, which we derive by coupling existing models for the shape of a fluid droplet and the surface force density on a solid ellipsoid. The…

Fluid Dynamics · Physics 2016-10-13 E. P. Kightley , A. Pearson , J. A. Evans , D. M. Bortz

The surface free energy is the difference between the free energies for a system with open boundary conditions and the same system with periodic boundary conditions. We use the quantum transfer matrix formalism to express the surface free…

Statistical Mechanics · Physics 2015-06-25 Frank Göhmann , Michael Bortz , Holger Frahm

We investigate the equilibrium of a fluid in contact with a solid boundary through a density-functional theory. Depending on the conditions, the fluid can be in one phase, gas or liquid, or two phases, while the wall induces an external…

Fluid Dynamics · Physics 2012-02-06 Antonio Pereira , Serafim Kalliadasis

Four results associated with the diffuse-interface model (DIM) for contact lines are reported in this paper. First, a boundary condition is derived, which states that the fluid near a solid wall must have a certain density $\rho_{0}$…

Fluid Dynamics · Physics 2021-09-27 E. S. Benilov

We look at the wetting of a pure fluid in contact with a charged flat surface. In the bulk, the fluid is a classical van der Waals fluid containing dissociated ions. The presence of wall and ions leads to strong dielectrophoretic and…

Statistical Mechanics · Physics 2021-11-16 Yoav Tsori

We propose a simple Monte Carlo method to calculate the interfacial free energy between the substrate and the material. Using this method we investigate the interfacial free energys of the hard sphere fluid and solid phases near a smooth…

Soft Condensed Matter · Physics 2008-06-24 Mingcheng Yang , Hongru Ma

We present a diffuse-interface model for the solid-state dewetting problem with anisotropic surface energies in ${\mathbb R}^d$ for $d\in\{2,3\}$. The introduced model consists of the anisotropic Cahn--Hilliard equation, with either a…

Analysis of PDEs · Mathematics 2023-02-15 Harald Garcke , Patrik Knopf , Robert Nürnberg , Quan Zhao