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The effect of strong confinement on the positional and orientational ordering is examined in a system of hard rectangular rods with length L and diameter D (L>D) using the Parsons-Lee modification of the second virial density functional…

Soft Condensed Matter · Physics 2018-01-24 Roohollah Aliabadi , Peter Gurin , Enrique Velasco , Szabolcs Varga

Resonant x-ray diffraction performed at the $\rm L_{II}$ and $\rm L_{III}$ absorption edges of Ru has been used to investigate the magnetic and orbital ordering in Ca$_2$RuO$_4$ single crystals. A large resonant enhancement due to electric…

We present results of electrical resistivity, magnetoresistance and ac and dc magnetic susceptibility on polycrystalline samples of the type La(0.5)Ca(0.5-x)Ba(x)MnO(3) synthesized under identical heat treatment conditions. The substitution…

Strongly Correlated Electrons · Physics 2009-10-31 R. Mallik , E. S. Reddy , P. L. Paulose , Subham Mazumdar , E. V. Sampathkumaran

Within a phase field approach which takes the strain-induced elasticity into account, the kinetics of the coherent order-disorder transition is investigated for the specific case of $Al_3 Zr$ alloy. It is shown that a microstructure with…

Materials Science · Physics 2009-11-07 Laurent Proville , Alphonse Finel

The structural phase diagram of the La1-xSrxMnO3 system in the compositional range 0.08 <= x <= 0.125 has been investigated by high-resolution synchrotron x-ray powder diffraction techniques between 20-600 K. Recent studies have reported…

Strongly Correlated Electrons · Physics 2009-10-31 D. E. Cox , T. Iglesias , E. Moshopoulou , K. Hirota , K. Takahashi , Y. Endoh

The electrochemical performance of the spinel LiNi0.5Mn1.5O4, a high-voltage positive electrode material for Li-ion batteries, is influenced by the transition metal arrangement in the octahedral network, leading to disordered (Fd m S.G.)…

Resonant soft X-ray scattering was used to determine the presence of more subtle orderings not detected in standard structural analyses. By tuning to specific Co absorption edges, arrangements particular to the electronic states of those…

Strongly Correlated Electrons · Physics 2017-07-17 F. J. Rueckert , F. He , B. Poudel , B. Dabrowski , W. A. Hines , J. I. Budnick , B. O. Wells

Numerical simulations of phase ordering under dissipative dynamics in a (2+1)-dimensional 3-vector model with O(3) symmetry are reported. The energy functional includes terms which stabilize the size of extended topological defects. They…

High Energy Physics - Phenomenology · Physics 2011-07-19 G. Holzwarth , J. Klomfass

We show that in mixed-valence 3d transition metal oxides undergoing a structural transition, the low temperature phase results from an effective ordering of the charge. This arrangement and the quantitative evaluation of the atomic charges…

Materials Science · Physics 2007-05-23 Y. Joly , S. Grenier , J. E. Lorenzo

We have utilized neutron powder diffraction to probe the crystal structure of layered Na$_{x}$CoO$_{2}$ near the half doping composition of $x=$0.46 over the temperature range of 2 to 600K. Our measurements show evidence of a dynamic…

Strongly Correlated Electrons · Physics 2008-06-16 D. N. Argyriou , O. Prokhnenko , K. Kiefer , C. J. Milne

The local structure of (Al_0.06V_0.94)_2O_3 in the paramagnetic insulating (PI) and antiferromagnetically ordered insulating (AFI) phase has been investigated using hard and soft x-ray absorption techniques. It is shown that: 1) on a local…

Strongly Correlated Electrons · Physics 2009-11-07 P. Pfalzer , J. Will , A. Nateprov , M. Klemm , V. Eyert , S. Horn , A. I. Frenkel , S. Calvin , M. L. denBoer

New metal-ordered manganites RBaMn_{2}O_{6} have been synthesized and investigated in the structures and electromagnetic properties. RBaMn_{2}O_{6} can be classified into three groups from the structural and electromagnetic properties. The…

Strongly Correlated Electrons · Physics 2009-11-07 T. Nakajima , H. Kageyama , H. Yoshizawa , Y. Ueda

The discovery of novel structural and physical properties in the $A$-site ordered manganite $R$BaMn$_{2}$O$_{6}$ ($R$ = Y and rare earth elements) has demanded new comprehension about perovskite manganese oxides. In the present study, the…

Strongly Correlated Electrons · Physics 2009-11-10 T. Nakajima , H. Yoshizawa , Y. Ueda

Switchable order parameters in ferroic materials are essential for functional electronic devices, yet disruptions of the ordering can take the form of planar boundaries or defects that exhibit distinct properties. Characterizing the…

We systematically study Raman spectroscopy of cleaved Na$_x$CoO$_2$ single crystals with 0.37 $\leq$ x $\leq$ 0.80. The Raman shift of A$_{1g}$ mode is found to be linearly dependent on Na content, while the Raman shift of E$_{1g}$ mode has…

Strongly Correlated Electrons · Physics 2009-11-13 T. Wu , K. Liu , H. Chen , G. Wu , Q. L. Luo , J. J. Ying , X. H. Chen

(abridged) We present results of the disorder-induced metal-insulator-transition (MIT) in three-dimensional amorphous indium-oxide films. The amorphous version studied here differs from the one reported earlier [PRB 46, 10917 (1992)] in…

Materials Science · Physics 2012-10-02 U. Givan , Z. Ovadyahu

The oxide heterostructure [(YFeO$_3$)$_5$(LaFeO$_3$)$_5$]$_{40}$, which is magnetically ordered and piezoelectric at room temperature, has been constructed from two weak ferromagnetic AFeO$_3$ perovskites with different A cations using…

Frustrated magnetic systems exhibit highly degenerate ground states and strong fluctuations, often leading to new physics. An intriguing example of current interest is the antiferromagnet on a diamond lattice, realized physically in A-site…

Materials Science · Physics 2011-09-21 G. J. MacDougall , D. Gout , J. L. Zarestky , G. Ehlers , A. Podlesnyak , M. A. McGuire , D. Mandrus , S. E. Nagler

We conduct a numerical investigation of structural order in the shifted-force Lennard-Jones system by calculating metrics of translational and bond-orientational order along various paths in the phase diagram covering equilibrium solid,…

Statistical Mechanics · Physics 2009-11-07 Jeffrey R. Errington , Pablo G. Debenedetti , Salvatore Torquato

We use electron momentum density in ice as a tool to quantify order-disorder transitions by comparing Compton profiles differences of ice VI, VII, VIII and XII with respect to ice Ih. Quantitative agreement is found between theory and…

Materials Science · Physics 2011-03-17 Ch. Bellin , B. Barbiellini , S. Klotz , T. Buslaps , G. Rousse , Th. Straessle , A. Shukla