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X-ray resonant scattering at the K-edge of transition metal oxides is shown to measure the orbital order parameter, supposed to accompany magnetic ordering in some cases. Virtual transitions to the 3d-orbitals are quadrupolar in general. In…

Strongly Correlated Electrons · Physics 2009-10-30 Michele Fabrizio , Massimo Altarelli , Maurizio Benfatto

This work reports on magnetic, dielectric, thermodynamic and magnetoelectric properties of Gd$_{1-x}$Y$_{x}$MnO$_{3}$, with 0 \leq x \leq 0.4, with emphasis on the (x, T) phase diagram, towards unraveling the role of the driving mechanisms…

Strongly Correlated Electrons · Physics 2015-06-18 R. Vilarinho , A. Almeida , J. M. Machado da Silva , J. B. Oliveira , M. A. Sá , P. B. Tavares , J. Agostinho Moreira

The improper ferroelectricity in YMnO$_3$ and other related multiferroic hexagonal manganites are known to cause topologically protected ferroelectric domains that give rise to rich and diverse physical phenomena. The local structure and…

We attribute the structural phase transition (SPT) in the parent compounds of the iron pnictides to orbital ordering. Due to the anisotropy of the $d_{xz}$ and $d_{yz}$ orbitals in the $xy$ plane, a ferro-orbital ordering makes the…

Strongly Correlated Electrons · Physics 2013-05-29 Weicheng Lv , Jiansheng Wu , Philip Phillips

Combining infrared reflectivity, transport, susceptibility and several diffraction techniques, we find compelling evidence that CaCrO3 is a rare case of a metallic and antiferromagnetic transition-metal oxide with a three-dimensional…

The synthesis, structure, and elementary magnetic and electronic properties are reported for layered compounds of the type Na3-xMIr2O6 and Na3-xM2IrO6, where M is a transition metal from the 3d series (M=Zn, Cu, Ni, Co, Fe and Mn). The…

Evidence has been found for a change in the ordered occupation of the vanadium d-orbitals at the 77K phase transition in YVO3, manifested by a change in the type of Jahn-Teller distortion. The orbital ordering above 77K is not destroyed at…

Strongly Correlated Electrons · Physics 2009-11-07 G. R. Blake , T. T. M. Palstra , Y. Ren , A. A. Nugroho , A. A. Menovsky

We study a continuous quasi-two-dimensional order-disorder phase transition that occurs in a simple model of a material that is inhomogeneously strained due to the presence of dislocation lines. Performing Monte Carlo simulations of…

Statistical Mechanics · Physics 2010-09-15 Charo I. Del Genio , Kevin E. Bassler

The discovery of novel structural and physical properties in the $A$-site ordered manganite $R$BaMn$_2$O$_6$ ($R$ = Y and rare earth elements) has demanded new comprehension about perovskite manganese oxides. In the present study, the…

Strongly Correlated Electrons · Physics 2007-05-23 T. Nakajima , Y. Ueda

The crystal structure and the magnetic properties of the W1-xNbxO3-d, (x<0.03) system have been investigated. In contrast to the orthorhombic diamagnetic WO3, the material with x=0.01 is paramagnetic down to 5 K. Introducing of 2.5 at. % of…

Materials Science · Physics 2009-11-07 I. Felner , U. Asaf , M. Weger

We report a high-resolution neutron diffraction study of the crystal and magnetic structure of the orbitally-degenerate frustrated metallic magnet AgNiO2. At high temperatures the structure is hexagonal with a single crystallographic Ni…

Strongly Correlated Electrons · Physics 2009-11-13 E. Wawrzynska , R. Coldea , E. M. Wheeler , T. Sorgel , M. Jansen , R. M. Ibberson , P. G. Radaelli , M. M. Koza

We have performed the powder neutron diffraction measurements on the solid solutions of SrRu_{1-x}Mn_xO_3, and found that the itinerant ferromagnetic order observed in pure SrRuO_3 changes into the C-type antiferromagnetic (AF) order with…

Strongly Correlated Electrons · Physics 2007-05-23 M. Yokoyama , C. Satoh , A. Saitou , H. Kawanaka , H. Bando , K. Ohoyama , Y. Nishihara

The pressure-temperature phase diagram of an intermediate-valence compound YbPd was revealed via simultaneous ac-calorimetry and electrical resistivity measurements. Two successive structural phase transition temperatures, $T_1$ = 125 K and…

We use first-principles calculations based on density functional theory to investigate the interplay between oxygen vacancies, A-site cation size / tolerance factor, epitaxial strain, ferroelectricity and magnetism in the perovskite…

Materials Science · Physics 2021-03-09 Astrid Marthinsen , Carina Faber , Ulrich Aschauer , Nicola A. Spaldin , Sverre M. Selbach

In this paper the amorphous/solid to disorder liquid structural phase transitions of an anomalous confined fluid is analyzed using their local fractal dimension. The model is a system of particles interacting through a two length scales…

Soft Condensed Matter · Physics 2016-02-17 Elsa M. de la Calleja-Mora , Leandro B. Krott , Marcia C. Barbosa

Effect of an internal chemical pressure on structural, optical, magnetic and electrical properties in Bi0.9RE0.1FeO3 Ceramics (RE =Gd3+,Tb3+,Dy3+)has been studied extensively. Some of the highlights are as follows; 1. Coexistence of…

Materials Science · Physics 2012-06-26 T. Karthik , T. Durga Rao , A. Srinivas , Saket Asthana

A detailed account of the local atomic structure and disorder at 5~K across the phase diagram of the high temperature superconductor K$_x$Fe$_{2-y}$Se$_{2-z}$S$_z$ $(0 \leq z \leq 2)$ is obtained from neutron total scattering and associated…

Superconductivity · Physics 2019-09-25 P. Mangelis , R. J. Koch , H. Lei , R. B. Neder , M. T. McDonnell , M. Feygenson , C. Petrovic , A. Lappas , E. S. Bozin

Oxide heterostructures exhibit a vast variety of unique physical properties. Examples are unconventional superconductivity in layered nickelates and topological polar order in (PbTiO$_3$)$_n$/(SrTiO$_3$)$_n$ superlattices. Although it is…

XY pyrochlore antiferromagnets are well-known to exhibit order-by-disorder through both quantum and thermal selection. In this paper we consider the effect of substituting non-magnetic ions onto the magnetic sites in a pyrochlore XY model…

Disordered Systems and Neural Networks · Physics 2015-06-22 A. Andreanov , P. A. McClarty

We report the temperature-dependent synchrotron based X-ray diffraction analysis of NASICON type Na$_3$FeCr(PO$_4$)$_3$ sample, which undergoes a symmetry-lowering structural transition from a monoclinic ($C2/c$) phase with long-range…

Materials Science · Physics 2026-04-15 Madhav Sharma , Archna Sagdeo , Rajendra S. Dhaka