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Ensemble density functional theory (EDFT) is a promising alternative to time-dependent density functional theory for computing electronic excitation energies. Using coordinate scaling, we prove several fundamental exact conditions in EDFT…

Strongly Correlated Electrons · Physics 2023-07-04 Thais R. Scott , John Kozlowski , Steven Crisostomo , Aurora Pribram-Jones , Kieron Burke

We use first principles methods to study static and dynamical mechanical properties of the ferroelectric polymer Poly(vinylidene fluoride) (PVDF) and its copolymer with trifluoro ethylene (TrFE). We use density functional theory [within the…

Soft Condensed Matter · Physics 2009-11-10 H. B. Su , Alejandro Strachan , William A. Goddard

The systematics of one-quasiparticle configurations in neutron-rich Sr, Zr, and Mo odd isotopes is studied within the Hartree-Fock-Bogoliubov plus Equal Filling Approximation method preserving both axial and time reversal symmetries.…

Nuclear Theory · Physics 2011-01-25 R. Rodriguez-Guzman , P. Sarriguren , L. M. Robledo

Interactions between negatively charged aluminosilicate species and positively charged metal cations are critical to many important engineering processes and applications, including sustainable cements and aluminosilicate glasses. In an…

Materials Science · Physics 2023-01-18 Kai Gong , Kengran Yang , Claire E. White

The self consistent version of the density functional theory (DFT) is presented, which allows to calculate the ground state and dynamic properties of finite multi-electron systems such as atoms, molecules and clusters. The exact functional…

Condensed Matter · Physics 2007-05-23 M. Ya. Amusia , V. R. Shaginyan

We show an $\textit{ab initio}$ construction of the energy density functional (EDF) for electron systems using the functional renormalization group. The correlation energies of the homogeneous electron gas given in our framework reproduce…

Strongly Correlated Electrons · Physics 2021-08-03 Takeru Yokota , Tomoya Naito

We derive an exact representation of the exchange-correlation energy within density functional theory (DFT) which spawns a class of approximations leading to correct long-range asymptotic behavior. In what amounts to be the simplest…

Materials Science · Physics 2009-11-10 Roi Baer , Daniel Neuhauser

First principles studies of multiferroic materials, such as bismuth ferrite (BFO), require methods that extend beyond standard density functional theory (DFT). The DFT+U method is one such extension that is widely used in the study of BFO.…

Materials Science · Physics 2018-04-10 J. Kane Shenton , Wei Li Cheah , David R. Bowler

The interplay between the collective dynamics of the quadrupole and octupole deformation degree of freedom is discussed in a series of Sm and Gd isotopes both at the mean field level and beyond, including parity symmetry restoration and…

Nuclear Theory · Physics 2015-06-11 R. Rodriguez-Guzman , L. M. Robledo , P. Sarriguren

Density functional theory (DFT) embedding provides a formally exact framework for interfacing correlated wave-function theory (WFT) methods with lower-level descriptions of electronic structure. Here, we report techniques to improve the…

Chemical Physics · Physics 2015-06-12 Jason D. Goodpaster , Taylor A. Barnes , Frederick R. Manby , Thomas F. Miller

A covariant hyper-nuclear energy density functional (EDF) is derived from in medium nucleon meson vertex functionals, assuring the proper description of nuclear mean-field dynamics. The fundamental SU(3) coupling constants for the…

Nuclear Theory · Physics 2022-11-30 Horst Lenske , Madhumita Dhar

We report a comprehensive density functional theory (DFT) + $U$ study of the energetics of charged and neutral oxygen defects in both PuO$_{2}$ and $\alpha$-Pu$_{2}$O$_{3}$, and present a quantitative determination of the equilibrium…

Materials Science · Physics 2012-08-21 Bo Sun , Haifeng Liu , Haifeng Song , Guang-Cai Zhang , Hui Zheng , Xian-Geng Zhao , Ping Zhang

An extension of the Barcelona Catania Paris Madrid (BCPM) energy density functional is proposed to deal with odd-mass systems as well as multiquasiparticle excitations. The extension is based on the assumption that the equal filling…

Nuclear Theory · Physics 2024-04-25 S. A. Giuliani , L. M. Robledo

By breaking both the axial and the spatial reflection symmetries, we develop multidimensionally constrained relativistic mean field (MDC-RMF) models. The nuclear shape is assumed to be invariant under the reversion of $x$ and $y$ axes,…

Nuclear Theory · Physics 2014-02-05 Bing-Nan Lu , Jie Zhao , En-Guang Zhao , Shan-Gui Zhou

We report a combined experimental and theoretical study of boron carbide under stress/deformation. A special rotating anvil press, the rotating tomography Paris Edinburgh cell (RotoPEC), has been used to apply torsional deformation to boron…

The energy density is the prime parameter to define the deconfinement of quarks and gluons occurring in collisions of heavy ions. Recently, there is mounting evidence that many observables in proton-proton collisions behave in a manner very…

High Energy Physics - Phenomenology · Physics 2016-08-09 E. Cuautle , G. Paić

The structural and electronic properties of Rutherfordium, the newest group IV B element, have been evaluated by first principles density functional theory in scalar relativistic formalism with and without spin-orbit coupling and compared…

Materials Science · Physics 2011-06-17 Jyoti Gyanchandani , S. K. Sikka

A novel method for calculating spectroscopic properties of medium-mass and heavy atomic nuclei with an odd number of nucleons is introduced, based on the framework of nuclear energy density functional theory and the particle-core coupling…

Nuclear Theory · Physics 2016-05-04 K. Nomura , T. Nikšić , D. Vretenar

The Multi-Reference Energy Density Functional (MR-EDF) approach (also called configuration mixing or Generator Coordinate Method), that is commonly used to treat pairing in finite nuclei and project onto particle number, is re-analyzed. It…

Nuclear Theory · Physics 2015-05-28 Guillaume Hupin , Denis Lacroix , Michael Bender

A strong enhancement at low $\gamma$-ray energies has recently been discovered in the $\gamma$-ray strength function of $^{56,57}$Fe. In this work, we have for the first time obtained theoretical $\gamma$ decay spectra for states up to…

Nuclear Theory · Physics 2014-12-24 B. Alex Brown , A. C. Larsen
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