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We extensively investigated the critical behavior of mixtures of colloids and polymers via the two-component Asakura-Oosawa model and its reduction to a one-component colloidal fluid using accurate theoretical and simulation techniques. In…

Soft Condensed Matter · Physics 2009-11-11 F. Lo Verso , R. L. C. Vink , D. Pini , L. Reatto

As a generic model for liquid-vapour type transitions in random porous media, the Asakura-Oosawa model for colloid-polymer mixtures is studied in a matrix of quenched spheres using extensive Monte Carlo (MC) simulations. Since such systems…

Soft Condensed Matter · Physics 2009-11-13 R. L. C. Vink , K. Binder , H. Loewen

We study numerically the critical behavior of a modified, active Asakura-Oosawa model for colloid-polymer mixtures. The colloids are modeled as self-propelled particles with Vicsek-like interactions. This system undergoes phase separation…

Soft Condensed Matter · Physics 2017-03-08 Benjamin Trefz , Jonathan Tammo Siebert , Thomas Speck , Kurt Binder , Peter Virnau

We consider the equilibrium behavior of fluids imbibed in disordered mesoporous media, including their gas-liquid critical point when present. Our starting points are on the one hand a description of the fluid/solid-matrix system as a…

Statistical Mechanics · Physics 2015-05-28 Gilles Tarjus , Martin-Luc Rosinberg , Edouard Kierlik , Matthieu Tissier

We study how the formalism of the Hierarchical Reference Theory (HRT) can be extended to inhomogeneous systems. HRT is a liquid state theory which implements the basic ideas of Wilson momentum shell renormalization group (RG) to microscopic…

Statistical Mechanics · Physics 2009-11-10 Alberto Orlandi , Alberto Parola , Luciano Reatto

An extension of the Asakura-Oosawa-Vrij model of hard sphere colloids and non-adsorbing polymers, that takes polymer non-ideality into account through a repulsive stepfunction pair potential between polymers, is studied with grand canonical…

Soft Condensed Matter · Physics 2007-05-23 R. L. C. Vink , M. Schmidt

We propose a new coarse-grained model for the description of liquid-vapor phase separation of colloid-polymer mixtures. The hard-sphere repulsion between colloids and between colloids and polymers, which is used in the well-known…

Soft Condensed Matter · Physics 2009-11-13 Jochen Zausch , Peter Virnau , Kurt Binder , Juergen Horbach , Richard L. Vink

We consider infinite-dimensional random diffusion dynamics for the Asakura--Oosawa model of interacting hard spheres of two different sizes. We construct a solution to the corresponding SDE with collision local times, analyse its reversible…

Probability · Mathematics 2025-11-24 Myriam Fradon , Alexander Zass

A colloidal particle placed in an inhomogeneous solution of smaller non-adsorbing polymers will move towards regions of lower polymer concentration, in order to reduce the free energy of the interface between the surface of the particle and…

Soft Condensed Matter · Physics 2017-12-13 Richard P. Sear , Patrick B. Warren

A smooth cut-off formulation of the Hierarchical Reference Theory (HRT) is developed and applied to a Yukawa fluid. The HRT equations are derived and numerically solved leading to: the expected renormalization group structure in the…

Statistical Mechanics · Physics 2009-11-13 Alberto Parola , Davide Pini , Luciano Reatto

Critical phenomena in real fluids demonstrate a combination of universal features caused by the divergence of long-range fluctuations of density and nonuniversal (system-dependent) features associated with specific intermolecular…

Statistical Mechanics · Physics 2013-07-09 M. A. Anisimov

The colloidal gel and glass transitions are investigated using the idealized mode coupling theory (MCT) for model systems characterized by short-range attractive interactions. Results are presented for the adhesive hard sphere and hard core…

Soft Condensed Matter · Physics 2009-10-31 J. Bergenholtz , M. Fuchs

We study a self-organized critical system under influence of turbulent motion of the environment. The system is described by the anisotropic continuous stochastic equation proposed by Hwa and Kardar [{\it Phys. Rev. Lett.} {\bf 62}: 1813…

Statistical Mechanics · Physics 2020-09-22 N. V. Antonov , N. M. Gulitskiy , P. I. Kakin , G. E. Kochnev

The idealized mode coupling theory (MCT) is applied to colloidal systems interacting via short-range attractive interactions of Yukawa form. At low temperatures MCT predicts a slowing down of the local dynamics and ergodicity breaking…

Soft Condensed Matter · Physics 2009-10-31 J. Bergenholtz , M. Fuchs

Using Gibbs ensemble Monte Carlo simulations and density functional theory we investigate the fluid-fluid demixing transition in inhomogeneous colloid-polymer mixtures confined between two parallel plates with separation distances between…

Soft Condensed Matter · Physics 2009-11-11 Andrea Fortini , Matthias Schmidt , Marjolein Dijkstra

The possibility to induce demixing in a colloidal mixture by adding small polymers, or other equivalent depletant agents, is theoretically investigated. By use of Mean Field Theory, suitably generalized to deal with short range effective…

Soft Condensed Matter · Physics 2015-10-28 Alberto Parola , Luciano Reatto

The influence of confinement, due to flat parallel structureless walls, on phase separation in colloid-polymer mixtures, is investigated by means of grand-canonical Monte Carlo simulations. Ultra-thin films, with thicknesses between…

Soft Condensed Matter · Physics 2009-11-11 Richard L. C. Vink , Andres De Virgiliis , Juergen Horbach , Kurt Binder

We investigate the influence of confinement on phase separation in colloid-polymer mixtures. To describe the particle interactions, the colloid-polymer model of Asakura and Oosawa [J. Chem. Phys. 22, 1255 (1954)] is used. Grand canonical…

Soft Condensed Matter · Physics 2007-05-23 R. L. C. Vink , K. Binder , J. Horbach

As first explained by the classic Asakura-Oosawa (AO) model, effective attractive forces between colloidal particles induced by depletion of nonadsorbing polymers can drive demixing of colloid-polymer mixtures into colloid-rich and…

Soft Condensed Matter · Physics 2021-08-27 Alan R. Denton , Wyatt J. Davis

Using a simple mean-field density functional theory theory (DFT), we investigate the structure and phase behaviour of a model colloidal fluid composed of particles interacting via a pair potential which has a hard core of diameter $\sigma$,…

Soft Condensed Matter · Physics 2007-05-23 A. J. Archer , D. Pini , R. Evans , L. Reatto
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