Related papers: Thermal desorption of CH4 retained in CO2 ice
There is evidence to suggest that clathrate hydrates have a significant effect on the surface geology of icy bodies in the Solar System. However the aqueous environments believed to be present on these bodies are likely to be saline rather…
The efficiency of cavity sideband cooling of trapped molecules is theoretically investigated for the case where the IR transition between two rovibrational states is used as a cycling transition. The molecules are assumed to be trapped…
Context. Interstellar surface chemistry is a complex process that occurs in icy layers accumulated onto grains of different sizes. Efficiency of surface processes often depends on the immediate environment of adsorbed molecules. Aims. We…
Organosulfur species are potential major carriers of sulfur in the interstellar medium, as well as interesting ingredients in prebiotic chemistry. The most fundamental question regarding these species is under which conditions they reside…
Context. Interstellar ice is the main form of metal species in dark molecular clouds. Experiments and observations have shown that the ice is significantly processed after the freeze-out of molecules onto grains. The processing is caused by…
The H II region W40 harbors a small group of young, hot stars behind roughly 9 magnitudes of visual extinction. We have detected gaseous carbon monoxide (CO) and diatomic carbon (C_2) in absorption toward the star W40 IRS 1a. The 2-0 R0,…
Chemical equilibrium considerations suggest that, assuming solar elemental abundances, carbon on HD 209458b is sequestered primarily as carbon monoxide (CO) and methane (CH4). The relative mole fractions of CO(g) and CH4(g) in chemical…
Aims. Formamide (HCONH2) is the simplest molecule containing the peptide bond first detected in the gas phase in Orion-KL and SgrB2. In recent years, it has been observed in high temperature regions such as hot corinos, where thermal…
Experimentally determining thermophysical properties for various compositions commonly found in CO2 transportation systems is extremely challenging. To overcome this challenge, we performed Monte Carlo (MC) and molecular dynamics (MD)…
Clouds have a strong impact on the climate of planetary atmospheres. The potential scattering greenhouse effect of CO2 ice clouds in the atmospheres of terrestrial extrasolar planets is of particular interest because it might influence the…
Gas-phase hydroxylamine (NH$_2$OH) has recently been detected within dense clouds in the interstellar medium. However, it is also likely present within interstellar ices, as well as on the icy surfaces of outer Solar System bodies, where it…
It is widely believed that the carbonate-silicate cycle is the main agent to trigger deglaciations by CO$_2$ greenhouse warming on Earth and on Earth-like planets when they get in frozen state. Here we use a 3D Global Climate Model to…
Physical conditions in dense and cold regions of interstellar clouds favour the formation of ice mantles on the surfaces of interstellar grains. It is predicted that most of the gaseous species heavier than H2 or He will adsorb onto the…
UV absorption cross sections are an essential ingredient of photochemical atmosphere models. Exoplanet searches have unveiled a large population of short-period objects with hot atmospheres, very different from what we find in our solar…
We report the successful buffer-gas cooling and magnetic trapping of chromium atoms with densities exceeding $10^{12}$ atoms per cm$^{3}$ at a temperature of 350 mK for the trapped sample. The possibilities to extend the method to…
Chemisorption of CO on the stepped Cu(211) surface is studied within ab-initio density functional theory (DFT) and scanning tunneling microscopy (STM) imaging as well as manipulation experiments. Theoretically we focus on the experimentally…
Observations of star forming environments revealed that the abundances of some deuterated interstellar molecules are markedly larger than the cosmic D/H ratio of 10-5. Possible reasons for this pointed to grain surface chemistry. How- ever,…
Water ice is abundant both astrophysically, for example in molecular clouds, and in planetary systems. The Kuiper belt objects, many satellites of the outer solar system, the nuclei of comets and some planetary rings are all known to be…
Cosmic-ray-induced sputtering is one of the important desorption mechanisms at work in astrophysical environments. The chemical evolution observed in high-density regions, from dense clouds to protoplanetary disks, and the release of…
We study the influence of thermal Casimir-Polder forces on the near-surface trapping of cold polar molecules, with emphasis on LiH and YbF near an Au surface at room temperature. We show that for a molecule initially prepared in its…