Related papers: The solid state phase transformation of potassium …
The thermal conductivity of solid parahydrogen crystal with methane admixtures has been measured in the temperature range 1.5 to 8 K. Solid samples were grown from the gas mixture at 13 K. Concentration of CH4 admixture molecules in the gas…
The oxidation of CO on single Pd atoms anchored to MgO(100) surface oxygen vacancies is studied with temperature-programmed-reaction mass-spectrometry and infrared spectroscopy. In one-heating-cycle experiments CO$_2$, formed from O$_2$ and…
While propagating in transparent media, near-infrared multi-terawatt (TW) laser beams break up in a multitude of filaments of typically 100-200 um diameter with peak intensities as high as 10 to 100~TW/cm$^{2}$. We observe a phase…
Pressure-induced superconductivity and structural phase transitions in phosphorous (P) are studied by resistivity measurements under pressures up to 170 GPa and fully $ab-initio$ crystal structure and superconductivity calculations up to…
We have measured the specific heat of crystals of (Ca1-xSrx)3Ru2O7 using ac- and relaxation-time calorimetry. Special emphasis was placed on the characterization of the Neel (TN=56 K) and structural (Tc = 48 K) phase transitions in the…
Using molecular dynamics simulations driven by a machine-learned interatomic potential, we investigate at low to intermediate pressures the $\lambda$-transition of sulfur, a temperature-induced polymerization. At ambient pressure, we…
A study of high pressure solid Te was carried out at room temperature using Raman spectroscopy and Density Functional Theory (DFT) calculations. The analysis of the P-dependence of the experi- mental phonon spectrum reveals the occurrence…
Quantitative knowledge of sulfur speciation in the fluid phase is key to understanding sulfur degassing from magmas and its transfer along with metals by fluids across the lithosphere. Farsang and Zajacz (1) recently reported new sulfur…
Single crystals of the three-dimensional frustrated magnet and spin liquid candidate compound PbCuTe$_2$O$_6$ were grown using both the Travelling Solvent Floating Zone (TSFZ) and the Top-Seeded Solution Growth (TSSG) techniques. The growth…
The double superconducting transition in PrOs$_4$Sb$_{12}$, first observed in specific heat $C(T)$ measurements of single crystal samples, is the subject of an in-depth study. The double superconducting transitions of a batch of single…
Lithium doped sodium niobate is an ecofriendly piezoelectric material that exhibits a variety of structural phase transitions with composition and temperature. We have investigated the phase stabilities of an important composition…
We have investigated $4s\;^2S_{1/2} \rightarrow 5p\;^2P_{1/2}$ transition ($D_1$ line) of the potassium isotopes $^{39}$K, $^{40}$K, and $^{41}$K using Doppler-free laser saturation spectroscopy. Our measurements reveal the hyperfine…
To investigate excess-hydrolysis of titanium alkoxides, TiO2 powders were fabricated from titanium-tetra-isopropoxide using 6:1 and 100:1 H2O:Ti (r) ratios. Powders were dried and fired at a range of temperatures ( up to 800 C).…
We present a 5-phase equation of state (EOS) for elemental carbon. The phases considered are: diamond, BC8, simple-cubic, simple-hexagonal, and the liquid/plasma state. The solid phase free energies are constrained by density functional…
We calculate superconducting transition temperatures ($T_{\rm c}$) in sulfur hydrides H$_{2}$S and H$_{3}$S from first principles using the density functional theory for superconductors. At pressures of $\lesssim$150 GPa, the high values of…
X-ray diffraction (XRD) experiments have been carried out on quartz-like GaPO4 at high pressure and room temperature. A transition to a high pressure disordered crystalline form occurs at 13.5 GPa. Slight heating using a YAG infrared laser…
Heat capacity, magnetic susceptibility, NMR, and resistivity of SrNi2P2 single crystals are presented, illustrating a purely structural transition at 325 K with no magnetism. Bulk superconductivity is found at 1.4 K. The magnitude of the…
A recent paper by Zaghoo et al. presents optical data at high-pressure and high-temperature and interprets the data as evidence for a first-order phase transition to metallic hydrogen during heating. Here we argue that the presented data…
We have studied structural phase transitions in high quality underdoped La$_{2-x}$Ba$_x$CuO$_4$ single crystals using high resolution x-ray scattering techniques. Critical properties associated with the continuous High Temperature…
Single crystals of MgB2 have been grown with a high-pressure cubic anvil technique. They grow via the peritectic decomposition of the MgNB9 ternary nitride. The crystals are of a size up to 2x1x0.1mm3 with a weight up to 230 micrograms.…