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We determine the second, third, and fourth virial coefficients appearing in the density expansion of the osmotic pressure of a monodisperse polymer solution in good-solvent conditions. Using the expected large-concentration behavior, we…

Statistical Mechanics · Physics 2007-05-23 Sergio Caracciolo , Bortolo Matteo Mognetti , Andrea Pelissetto

A simulation technique is described for quantifying the contribution of three-body interactions to the thermodynamical properties of coarse-grained representations of complex fluids. The method is based on comparing the third virial…

Soft Condensed Matter · Physics 2015-06-19 Douglas J. Ashton , Nigel B. Wilding

We calculate the second and third virial coefficients of the effective sphere-sphere interaction due to polymer depletion. By utilizing the anisotropy of a typical polymer conformation, we can consider polymers that are roughly the same…

Soft Condensed Matter · Physics 2009-10-31 Mario Triantafillou , Randall D. Kamien

The fourth virial coefficient is calculated exactly for a fluid of hard spheres in even dimensions. For this purpose the complete star cluster integral is expressed as the sum of two three-folded integrals only involving spherical angular…

Statistical Mechanics · Physics 2022-05-11 Ignacio Urrutia

The fourth virial coefficient is calculated exactly for a fluid of hard spheres in odd dimensions up to 11.

Statistical Mechanics · Physics 2009-11-10 I. Lyberg

We compute the fourth virial coefficient of a binary nonadditive hard-sphere mixture over a wide range of deviations from diameter additivity and size ratios. Hinging on this knowledge, we build up a $y$ expansion [B. Barboy and W. N.…

Soft Condensed Matter · Physics 2011-10-25 G. Pellicane , F. Saija , C. Caccamo , P. V. Giaquinta

The virial expansion method is applied within a harmonic approximation to an interacting N-body system of identical fermions. We compute the canonical partition functions for two and three particles to get the two lowest orders in the…

Statistical Mechanics · Physics 2012-12-27 J. R. Armstrong , N. T. Zinner , D. V. Fedorov , A. S. Jensen

We derive path-integral expressions for the second and third virial coefficients of monatomic quantum gases. Unlike previous work that considered only Boltzmann statistics, we include exchange effects (Bose-Einstein or Fermi-Dirac…

Statistical Mechanics · Physics 2020-05-25 Giovanni Garberoglio , Allan H. Harvey

We derive an exact, analytic expression for the fourth virial coefficient of a system of polydisperse spheres under the constraint that the smallest sphere has a radius smaller than a given function of the radii of the three remaining…

Soft Condensed Matter · Physics 2009-10-31 Ronald Blaak

We present first-principles theoretical determination of the three-body polarizability and the third dielectric virial coefficient of helium. Coupled-cluster theory and the full configuration interaction procedure were used to perform…

Chemical Physics · Physics 2023-03-29 Jakub Lang , Michal Lesiuk , Michal Przybytek , Bogumil Jeziorski

For three anyons confined in a harmonic oscillator, only the class of states that interpolate nonlinearly with the statistical parameter contributes to the third virial coefficient of a free anyon gas. Rather than evaluating the full…

High Energy Physics - Theory · Physics 2009-10-22 J. Law , Avinash Khare , R. K. Bhaduri , Akira Suzuki

Exact results are given for the fourth virial coefficient of hard spheres in even dimensions up through 12. The fifth and sixth virial coefficients are numerically computed for dimensions 2 through 50 and it is found that the sixth virial…

Statistical Mechanics · Physics 2007-05-23 N. Clisby , B. M. McCoy

We present the first framework for fully quantum calculation of the third dielectric virial coefficient $C_\varepsilon(T)$ of noble gases, including exchange effects. The quantum effects are taken into account with the path-integral Monte…

Statistical Mechanics · Physics 2021-12-16 Giovanni Garberoglio , Allan H. Harvey , Bogumił Jeziorski

We consider a mixture of two single-spin-state fermions with an interaction of negligible range and infinite $s$-wave scattering length. By varying the mass ratio $\alpha$ across $\alpha_c\simeq 13.6069$ one can switch on-and-off the Efimov…

Quantum Gases · Physics 2024-07-19 Chao Gao , Shimpei Endo , Yvan Castin

Star polymer undergoes a transformation from a group of loosely coupled chains at low number of arms to a dense hairy colloid at their high number. This change affects solubility, aggregation and rheological behavior and is of much…

Soft Condensed Matter · Physics 2019-06-20 Ostap Kalyuzhnyi , Khristine Haidukivska , Viktoria Blavatska , Jaroslav Ilnytskyi

We analyze the effective triplet interactions between the centers of star polymers in a good solvent. Using an analytical short distance expansion inspired by scaling theory, we deduce that the triplet part of the three-star force is…

Soft Condensed Matter · Physics 2015-06-24 Christian von Ferber , Arben Jusufi , Christos N. Likos , Hartmut Lowen , Martin Watzlawek

Third-order weak lensing statistics are a promising tool for cosmological analyses since they extract cosmological information in the non-Gaussianity of the cosmic large-scale structure. However, such analyses require precise and accurate…

Cosmology and Nongalactic Astrophysics · Physics 2023-04-26 Laila Linke , Sven Heydenreich , Pierre A. Burger , Peter Schneider

For various polymers with different topological structures we numerically evaluate the mean-square radius of gyration and the hydrodynamic radius systematically through simulation. We call polymers with nontrivial topology topological…

Soft Condensed Matter · Physics 2016-11-23 Erica Uehara , Tetsuo Deguchi

We analyze diffusion of small particles in a solid polymeric medium taking into account a short range particle-polymer interaction. The system is modeled by a particle diffusion on a ternary lattice where the sites occupied by polymer…

Statistical Mechanics · Physics 2015-06-11 Federico Camboni , Andreas Koher , Igor M. Sokolov

We use the method of solving the three-anyon problem developed in our earlier publication to evaluate numerically the third virial coefficient of free anyons. In order to improve precision, we explicitly correct for truncation effects. The…

High Energy Physics - Theory · Physics 2009-10-30 Stefan Mashkevich , Jan Myrheim , Kåre Olaussen
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