Related papers: Crossover of aging dynamics in polymer glass: from…
The glass transition temperature $T_g$ and the temperature $T_{\alpha}$ corresponding to the peak in the dielectric loss due to the $\alpha$-process have been simultaneously determined as functions of film thickness $d$ through dielectric…
Following a recent work by Yoshino, we study the aging dynamics of a directed polymer in random media, in 1+1 dimensions. Through temperature quench, and temperature cycling numerical experiments similar to the experiments on real spin…
The aging effects of a 'diffusing glass', a single elastic string diffusing in a two-dimensional disordered media assisted by thermal noise are studied by Monte Carlo (MC) simulations. We find for the first time convincing numerical…
The relaxation dynamics of many disordered systems, such as structural glasses, proteins, granular materials or spin glasses, is not completely frozen even at very low temperatures. This residual motion leads to a change of the properties…
Aging to the equilibrium liquid state of organic glasses is studied. The glasses were prepared by cooling the liquid to temperatures just below the glass transition. Aging following a temperature jump was studied by measuring the dielectric…
By means of Monte Carlo simulations on the three-dimensional Ising spin-glass model, we have studied aging phenomena with various temperature($T$)-change protocols. Particularly, a $T$-shift protocol, in which a system is first quenched to…
We present new experimental results on the dielectric constant in orientational glasses K$_{1-x}$Li$_x$TaO$_3$ (KLT) with x < 0.05, together with the detailed (analytic and numerical) study of a model which attributes the observed aging to…
The effect of tensile stress applied during cooling of binary glasses on the potential energy states and mechanical properties is investigated using molecular dynamics simulations. We study the three-dimensional binary mixture that was…
Cu$_{0.5}$Co$_{0.5}$Cl$_{2}$-FeCl$_{3}$ graphite intercalation compound is a three-dimensional short-range Ising spin glass with a spin freezing temperature $T_{c}$ ($= 3.92 \pm 0.11$ K). The stability of the spin glass phase in the…
Recent experiments have demonstrated that the glass transition temperature of thin polymer films can be shifted as compared to the same polymer in the bulk, the amplitude and the sign of this effect depending on the interaction between the…
Describing the dynamics and thermodynamics of amorphous materials near the glass transition is a major challenge in soft-matter physics and polymer engineering. Here, we show that the dependence of the dielectric alpha-relaxation time on…
Glasses are out-of-equilibrium systems aging under the crystallization threat. During ordinary glass formation, the atomic diffusion slows down rendering its experimental investigation impractically long, to the extent that a timescale…
A microscopic theory for equilibrium and non equilibrium relaxations in structural glasses is formulated. For all temperatures below the glass transition the dynamics can be asymptotically separated in a $\beta $ - relaxation regime, which…
An analysis of the glass transition of four materials with similar chemical structures is performed: PET, PEN and two PET/PEN blends (90/10 and 70/30 w/w). During the melt processing of the blends transesterification reactions yield block…
Several papers have recently presented results of measurements of physical aging by studying the behavior of glassy materials quenched from temperatures above their glass transition temperature $T_g$. The evolution of the aging process is…
Non-reversing relaxation enthalpies (DHnr) at glass transitions Tg(x) in the PxGexSe1-2x ternary display wide, sharp and deep global minima (~ 0) in the 0.09 < x < 0.145 range, within which Tgs become thermally reversing. In this…
A universal dynamical crossover temperature, Tcr, in glassy liquids, associated with the {\alpha}-\b{eta} bifurcation temperature, TB, has been observed in dielectric spectroscopy and other experiments. Tcr lies significantly above the…
The glass transition, extensively studied in dense fluids, polymers, or colloids, corresponds to a dramatic evolution of equilibrium transport coefficients upon a modest change of control parameter, like temperature or pressure. A similar…
We perform molecular dynamics simulations of an idealized polymer melt surrounding a nanoscopic filler particle to probe the effects of a filler on the local melt structure and dynamics. We show that the glass transition temperature $T_g$…
Aging effects in the relaxations of conductivity of a two-dimensional electron system in Si have been studied as a function of carrier density. They reveal an abrupt change in the nature of the glassy phase at the metal-insulator transition…