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Methods for estimating the correlation energy of molecules and other electronic systems are discussed based on the assumption that the correlation energy can be partitioned between atomic regions. In one method, the electron density is…

Chemical Physics · Physics 2022-05-16 Jerry L. Whitten

Recent advances in the field of strongly correlated electron systems allow to access the entanglement properties of interacting fermionic models, by means of Monte Carlo simulations. We briefly review the techniques used in this context to…

Statistical Mechanics · Physics 2019-04-12 Francesco Parisen Toldin , Fakher F. Assaad

We present a proposal for the realization of entanglement Hamiltonians in one-dimensional critical spin systems with strongly interacting cold atoms. Our approach is based on the notion that the entanglement spectrum of such systems can be…

Quantum Gases · Physics 2021-02-10 R. E. Barfknecht , T. Mendes-Santos , L. Fallani

Shannon entropy in position ($S_{\rvec}$) and momentum ($S_{\pvec}$) spaces, along with their sum ($S_t$) are presented for unit-normalized densities of He, Li$^+$ and Be$^{2+}$ ions, spatially confined at the center of an impenetrable…

Quantum Physics · Physics 2021-03-01 Sangita Majumdar , Amlan K. Roy

Entropic measures provide analytic tools to help us understand correlation in quantum systems. In our previous work, we calculated linear entropy and von Neumann entropy as entanglement measures for the ground state and lower lying excited…

Quantum Physics · Physics 2015-07-21 Chien-Hao Lin , Yew Kam Ho

We study the entanglement entropy between the two outgoing particles in an elastic scattering process. It is formulated within an S-matrix formalism using the partial wave expansion of two-body states, which plays a significant role in our…

High Energy Physics - Theory · Physics 2016-07-08 Robi Peschanski , Shigenori Seki

The time dependent quantum Monte Carlo method for fermions is introduced and applied for calculation of entanglement of electrons in one-dimensional quantum dots with several spin-polarized and spin-compensated electron configurations. The…

Quantum Physics · Physics 2021-07-09 Ivan P. Christov

A structural model of hydrogenated amorphous silicon containing an isolated dangling bond is used to investigate the effects of electron interactions on the electronic level splittings, localization of charge and spin, and fluctuations in…

Materials Science · Physics 2009-11-07 R. G. Hennig , P. A. Fedders , A. E. Carlsson

Electron correlation effects are essential for an accurate ab initio description of molecules. A quantitative a priori knowledge of the single- or multi-reference nature of electronic structures as well as of the dominant contributions to…

Quantum Physics · Physics 2012-12-18 Katharina Boguslawski , Paweł Tecmer , Örs Legeza , Markus Reiher

In quantum chemistry calculations, the correlation energy is defined as the difference between the Hartree-Fock limit energy and the exact solution of the nonrelativistic Schrodinger equation. With this definition, the electron correlation…

Quantum Physics · Physics 2009-11-11 Zhen Huang , Sabre Kais

In this work, we present an investigation on the spatial entanglement entropies in the helium atom by using highly correlated Hylleraas functions to represent the S-wave states. Singlet-spin 1sns 1Se states (with n = 1 to 6) and…

Quantum Physics · Physics 2014-11-06 Chien-Hao Lin , Yew Kam Ho

An inversion method is formulated for extracting entanglement-related information on two-particle interactions in a one-dimensional system from measurable one-particle position- and momentum-distribution functions. The method is based on a…

Quantum Physics · Physics 2017-01-31 I. Nagy , M. L. Glasser

We investigate the entanglement in Hubbard models of hardcore bosons in $1D$, with an additional hardcore interaction on nearest neighbouring sites. We derive analytical formulas for the bipartite entanglement entropy for any number of…

Strongly Correlated Electrons · Physics 2019-08-07 Ioannis Kleftogiannis , Ilias Amanatidis , Vladislav Popkov

Recent numerical advances in the field of strongly correlated electron systems allow the calculation of the entanglement spectrum and entropies for interacting fermionic systems. An explicit determination of the entanglement (modular)…

Strongly Correlated Electrons · Physics 2018-11-16 Francesco Parisen Toldin , Fakher F. Assaad

The accurate calculation of the (differential) correlation energy is central to the quantum chemical description of bond-formation and bond-dissociation processes. In order to estimate the quality of single- and multi-reference approaches…

Chemical Physics · Physics 2013-07-16 Katharina Boguslawski , Pawel Tecmer , Gergely Barcza , Ors Legeza , Markus Reiher

The compressibility of a two-dimensional electron system with spin in a spatially correlated random potential and a quantizing magnetic field is investigated. Electron-electron interaction is treated with the Hartree-Fock method. Numerical…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Alexander Struck , Bernhard Kramer

The quantum entanglement for the two electrons in three-body atomic systems such as the helium atom, the hydrogen negative ion and the positronium negative ion are investigated by employing highly correlated Hylleraas functions to represent…

Quantum Physics · Physics 2015-06-15 Chien-Hao Lin , Yen-Chang Lin , Yew Kam Ho

We investigate the extended Hubbard model as an approximation to the local and spatial entanglement of a one-dimensional chain of nanostructures where the particles interact via a long range interaction represented by a `soft' Coulomb…

Strongly Correlated Electrons · Physics 2011-02-03 J. P. Coe , V. V. França , I. D'Amico

Entanglement is the fundamental difference between classical and quantum systems and has become one of the guiding principles in the exploration of high- and low-energy physics. The calculation of entanglement entropies in interacting…

Quantum Physics · Physics 2022-08-17 Patrick Emonts , Ivan Kukuljan

The complex nature of electron-electron correlations is made manifest in the very simple but non-trivial problem of two electrons confined within a sphere. The description of highly non-local correlation and self-interaction effects by…

Other Condensed Matter · Physics 2016-08-16 J. Jung , P. García-González , J. E. Alvarellos , R. W. Godby