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Competing interactions and geometric frustration provide favourable conditions for exotic states of matter. Such competition often causes multiple phase transitions as a function of temperature and can lead to magnetic structures that break…

We report a systematic study of the structure, electric and magnetic properties of Ca$_3$Co$_{2-x}$Mn$_x$O$_6$ single crystals with $x =$ 0.72 and 0.26. The DC and AC magnetic susceptibilities display anomalies with characteristic of the…

Materials Science · Physics 2017-09-08 J. Shi , J. D. Song , J. C. Wu , X. Rao , H. L. Che , Z. Y. Zhao , H. D. Zhou , J. Ma , R. R. Zhang , L. Zhang , X. G. Liu , X. Zhao , X. F. Sun

Ferroelectric and ferromagnetic materials possess spontaneous electric and magnetic order, respectively, which can be switched by the corresponding applied electric and magnetic fields. Multiferroics combine these properties in a single…

Strongly Correlated Electrons · Physics 2012-11-27 J. Lee , S. A. Trugman , C. D. Batista , C. L. Zhang , D. Talbayev , X. S. Xu , S. --W. Cheong , D. A. Yarotski , A. J. Taylor , R. P. Prasankumar

The spinel FeV2O4 is known to exhibit peculiar physical properties, which is generally ascribed to the unusual presence of two cations showing a pronounced interplay between spin, orbital and lattice degrees of freedom (Fe2+ and V3+ on the…

Materials Science · Physics 2012-02-16 Q. Zhang , K. Singh , F. Guillou , C. Simon , Y. Breard , V. Caignaert , V. Hardy

Ferrimagnetic spinel materials of formula AB2X4, where A and B are transition metals and X is oxygen or sulphur, hold promise for the realization of multiferroic characteristics. In this work, we report synthesis of spinel CoMn2O4 and…

Materials Science · Physics 2026-04-07 P. Kumar , P. Das , B. K. Kuanr , S. Patnaik

By studying the dielectric properties of the geometrically frustrated spinel CdV2O4, we observe ferroelectricity developing at the transition into the collinear antiferromagnetic ground state. In this multiferroic spinel, ferroelectricity…

The thermodynamic, magnetic, dielectric, and magnetoelectric properties of HoFe$_3$(BO$_3$)$_4$ and Ho$_{0.5}$Nd$_{0.5}$Fe$_3$(BO$_3$)$_4$ are investigated. Both compounds show a second order Ne\'{e}l transition above 30 K and a first order…

Strongly Correlated Electrons · Physics 2009-09-24 R. P. Chaudhury , F. Yen , B. Lorenz , Y. Y. Sun , L. N. Bezmaternykh , V. L. Temerov , C. W. Chu

Neutron diffraction is used to probe the (H,T) phase diagram of magneto-electric (ME) LiNiPO4 for magnetic fields along the c-axis. At zero field the Ni spins order in two antiferromagnetic phases. One has commensurate (C) structures and…

We propose a way to use electric-field to control the magnetic ordering of the tetragonal BiFeO3. Based on systematic first-principles studies of the epitaxial strain effect on the ferroelectric and magnetic properties of the tetragonal…

Materials Science · Physics 2015-05-28 Hang-Chen Ding , Chun-Gang Duan

Dielectric spectroscopy is used to check for the onset of polar order in the quasi one-dimensional quantum spin system Sul-Cu2Cl4 when passing from the spin-liquid state into the ordered spiral phase in an external magnetic field. We find…

Strongly Correlated Electrons · Physics 2015-03-20 F. Schrettle , S. Krohns , P. Lunkenheimer , A. Loidl , E. Wulf , T. Yankova , A. Zheludev

By combining neutron four-circle diffraction and polarized neutron diffraction techniques we have determined the complex spin structures of a multiferroic, YMn2O5, that exhibits two ferroelectric phases at low temperatures. The obtained…

We report the magnetic, dielectric and ferroelectric properties of polycrystalline iron vanadate(FeVO4), which has been recently found to exhibit multiferroicity in low temperature with noncollinear magnetic orderings. The influence of…

Materials Science · Physics 2011-02-21 L. Zhao , M. P. Y. Wu , K. W. Yeh , M. K. Wu

We clarify that the antiferromagnetic order in the distorted tetrahedral quasi-one dimensional spin system induces electric polarizations. In this system, the effects of the low dimensionality and the magnetic frustration are expected to…

Measurements of polarized neutron scattering were performed on a $S=1/2$ chain multiferroic LiCu$_2$O$_2$. In the ferroelectric ground state with the spontaneous polarization along the c-axis, the existence of transverse spiral spin…

Strongly Correlated Electrons · Physics 2009-11-13 S. Seki , Y. Yamasaki , M. Soda , M. Matsuura , K. Hirota , Y. Tokura

Recent progress in the field of multiferroics led to the discovery of many new materials in which ferroelectricity is induced by cycloidal spiral orders. The direction of the electric polarization is typically constrained by spin…

Magnetoelectric properties were investigated for an S=1/2 chain antiferromagnet CuCl2, which turns out to be the first example of non-chalcogen based spiral-spin induced multiferroics. Upon the onset of helimagnetic order propagating along…

Strongly Correlated Electrons · Physics 2010-09-01 S. Seki , T. Kurumaji , S. Ishiwata , H. Matsui , H. Murakawa , Y. Tokunaga , Y. Kaneko , T. Hasegawa , Y. Tokura

GdFe3(BO3)4 exhibits a structural phase transition at 156 K, antiferromagnetic order of the Fe3+ moments at 36 K followed by a spin reorientation phase transition at 9 K. The reorientation phase transition is studied through dielectric,…

Strongly Correlated Electrons · Physics 2009-11-11 F. Yen , B. Lorenz , Y. Y. Sun , C. W. Chu , L. N. Bezmaternykh , A. N. Vasiliev

The antiferromagnetic - ferromagnetic phase transition in YBaCo2O5.50 and YBaCo2O5.44 cobaltites with different types of oxygen-ion ordering in the [YO0.5/0.44] layers has been studied by neutron powder diffraction. Using the magnetic…

Materials Science · Physics 2007-05-23 D. D. Khalyavin , D. N. Argyriou , U. Amann , A. A. Yaremchenko , V. V. Kharton

Mixed spin chain compounds, ACuFe2(VO4)3 (A= Li,Na), reach magnetically ordered state at TN ~ 11 K (Li) or ~ 9 K (Na) and experience further transformation of magnetic order at T* ~ 7 K (Li) or ~ 5 K (Na), evidenced in magnetic…

BiFeO3 is a model multiferroic in which the ferroelectric polarization is coupled to ferroelastic lattice distortions, yet deterministic control of its domain structure remains limited by high switching fields and competing polarization…