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Typical properties of glassy materials are shown to be captured by a mean-field free-volume theory. Relaxation processes are supposed to be free-volume activated, and different entropy barriers are associated with density relaxation and…
Contrasts between beta relaxation in equilibrium viscous liquids and glasses are rationalized in terms of a double-well potential model with structure-dependent asymmetry, assuming structure is described by a single order parameter. The…
Solids subjected to repeated cycles of stress or deformation can fail after several cycles, a phenomenon termed fatigue failure. Although intensely investigated for a wide range of materials owing to its obvious practical importance, a…
The molecular mobility of glass and supercooled liquid states of nilutamide has been studied with broadband dielectric spectroscopy for a wide range of temperature and frequency. Besides primary $\alpha$-relaxation an excess wing like…
A detailed numerical study is made of relaxation at equilibrium in the Sherrington-Kirkpatrick Ising spin glass model, at and above the critical temperature Tg. The data show a long time stretched exponential relaxation q(t) ~…
The origin of stretched exponential relaxation in supercooled glass-forming liquids is one of the central questions regarding the anomalous dynamics of these fluids. The dominant explanation for this phenomenon has long been the proposition…
The dynamics of dislocations is reported to exhibit glassy properties. We study numerically various versions of 2d edge dislocation systems in the absence of externally applied stress. Two types of glassy behavior are identified: (i)…
The Gilroy-Phillips model of relaxational jumps in asymmetric double-well potentials, developed for the Arrhenius-type secondary relaxations of the glass phase, is extended to a formal description of the breakdown of the shear modulus at…
The primary relaxation in glass forming supercooled liquids (SCLs) above the glass transformation temperature T_g is discussed in terms of the first-order (steepness) and the second-order (curvature) temperature derivatives of the observed…
The phenomenology of the beta relaxation process in the shear-mechanical response of glass-forming liquids is summarized and compared to that of the dielectric beta process. Furthermore, we discuss how to model the observations by means of…
Understanding the effect of glassy dynamics on the stability of bio-macromolecules and investigating the underlying relaxation processes governing degradation processes of these macromolecules are of immense importance in the context of…
Mechanical relaxation behaviour of various natural volcanic glasses have been investigated in the temperature range RT-1200K using special low frequency flexure (f~0.63Hz) pendulum experiments. The rheological properties complex Young's…
Granular materials such as sand, powders, and grains are omnipresent in daily life, industrial applications, and earth-science [1]. When unperturbed, they form stable structures that resemble the ones of other amorphous solids like metallic…
Classification of glass-forming liquids based on the dramatic change in their properties upon approach to the glassy state is appealing, since this is the most conspicuous and often-studied aspect of the glass transition. Herein, we show…
Understanding the relaxation of a system towards equilibrium is a longstanding problem in statistical mechanics. Here we address the role of long-range interactions in this process by considering a class of two-dimensional or geophysical…
In the mode coupling theory of the liquid to glass transition the long time structural relaxation follows from equations solely determined by equilibrium structural parameters. The present extension of these structural relaxation equations…
We combine the swap Monte Carlo algorithm to long multi-CPU molecular dynamics simulations to analyse the equilibrium relaxation dynamics of model supercooled liquids over a time window covering ten orders of magnitude for temperatures down…
We investigate the dielectric response in the glass-electret state of two dipolar glass-forming materials. This unusual polar glassy state of matter is produced when a dipolar liquid is supercooled under the influence of a high electric dc…
Electron irradiation enables quantitative control over the plastic flow dynamics of silicate glasses, even far below the glass transition temperature. Through stress-relaxation experiments spanning ambient to near-glass-transition…
Dielectric beta-relaxation in a pyridine-toluene solution is studied close to the glass transition. In the equilibrium liquid state the beta loss peak frequency is not Arrhenius (as in the glass) but virtually temperature-independent, while…