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Inelastic x-ray scattering and Brillouin light scattering measurements of the dynamic structure factor of liquid hydrogen fluoride have been performed in the temperature range$ T=214\div 283 K$. The data, analysed using a viscoelastic model…

Disordered Systems and Neural Networks · Physics 2016-08-31 R. Angelini , P. Giura , D. Fioretto , G. Monaco , G. Ruocco , F. Sette

We present a mean-field theory of a coarse-grained model of a super-cooled liquid in which relaxation occurs via local plastic rearrangements. Local relaxation can be induced by thermal fluctuations or by the long-range elastic consequences…

Soft Condensed Matter · Physics 2023-12-07 Joseph W. Baron , Giulio Biroli

We investigate the relaxation behavior of thin films of a polyamide random copolymer, PA66/6I, with various film thicknesses using dielectric relaxation spectroscopy. Two dielectric signals are observed at high temperatures, the…

Soft Condensed Matter · Physics 2015-06-11 Natsumi Taniguchi , Koji Fukao , Paul Sotta , Didier R. Long

A detailed investigation of the charge-ordered charge-transfer salt \delta-(EDT-TTF-CONMe$_{2}$)$_{2}$Br by thermal-expansion measurements and dielectric spectroscopy reveals three dynamic processes of relaxational character. The slowest…

Strongly Correlated Electrons · Physics 2018-07-04 J. K. H. Fischer , P. Lunkenheimer , C. Leva , S. M. Winter , M. Lang , C. Mézière , P. Batail , A. Loidl , R. S. Manna

We derive an equation for the glass relaxation. In the derivation, the Zwanzig-Mori projection method is not applied explicitly, which makes our equation different from the mode coupling theory. Due to the nonlinearity, it is difficult to…

Disordered Systems and Neural Networks · Physics 2023-02-17 Li Wan

The $\alpha$-process (segmental motion) of thin polystyrene films supported on glass substrate has been investigated in a wider frequency range from 10$^{-3}$ Hz to 10$^4$ Hz using dielectric relaxation spectroscopy and thermal expansion…

Soft Condensed Matter · Physics 2009-10-31 Koji Fukao , Yoshihisa Miyamoto

The diverging relaxation time in approaching hypothetical ideal glass transition is a subject of hot debate. In the current paper we demonstrate, how diverging relaxation time and turning excess entropy to zero (which is an essence of…

Soft Condensed Matter · Physics 2024-10-25 M. V. Kondrin , Y. B. Lebed , A. A. Pronin , V. V. Brazhkin

Successful thermodynamic scaling of the structural alpha-relaxation time or transport coefficients of glass-forming liquids determined at various temperatures T and pressures P means the data conform to a single function of the product…

Soft Condensed Matter · Physics 2017-11-22 K. L. Ngai , M. Paluch

We consider the relaxation process and the out-of-equilibrium dynamics of natural generalizations to arbitrary dimensions of the well known one dimensional East process. These facilitated models are supposed to catch some of the main…

Statistical Mechanics · Physics 2015-06-22 Paul Chleboun , Alessandra Faggionato , Fabio Martinelli

Dielectric loss spectra of glass-forming propylene carbonate and glycerol at temperatures above and below T_g are presented. By performing aging experiments lasting up to five weeks, equilibrium spectra below T_g have been obtained. During…

Soft Condensed Matter · Physics 2009-10-31 U. Schneider , R. Brand , P. Lunkenheimer , A. Loidl

We report spin valve behavior in an organic nanowire consisting of three layers - cobalt, Alq3 and nickel - all nominally 50 nm in diameter. Based on the data, we conclude that the dominant spin relaxation mechanism in Alq3 is the…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 S. Pramanik , C-G. Stefanita , S. Bandyopadhyay , K. Garre , N. Harth , M. Cahay

We study the relaxation of force distributions in the q-model, assuming a uniform q-distribution. We show that "diffusion of correlations" makes this relaxation very slow. On a d-dimensional lattice, the asymptotic state is approached as a…

Statistical Mechanics · Physics 2015-06-24 Jacco H. Snoeijer , J. M. J. van Leeuwen

Glassy solids may undergo a fluidization (yielding) transition upon deformation whereby the material starts to flow plastically. It has been a matter of debate whether this process is controlled by a specific time scale, from among…

Soft Condensed Matter · Physics 2020-06-25 Alessio Zaccone , Eugene M. Terentjev

Among the challenges in discriminating between theoretical approaches to the glass transition is obtaining suitable data. In particular, particle--resolved data in liquids supercooled past the mode--coupling crossover has until recently…

Soft Condensed Matter · Physics 2021-03-16 Levke Ortlieb , Trond S. Ingebrigtsen , James E. Hallett , Francesco Turci , C. Patrick Royall

The dielectric response of liquids reflects both, reorientation of single molecular dipoles and collective modes, i.e., dipolar cross-correlations. A recent theory predicts the latter to produce an additional slow peak in the dielectric…

Soft Condensed Matter · Physics 2024-04-23 Till Böhmer , Florian Pabst , Jan P. Gabriel , Thomas Blochowicz

Using depolarized light scattering, we have recently shown that structural relaxation in a broad range of supercooled liquids follows, to good approximation, a generic line shape with high-frequency power law $\omega^{-1/2}$. We now…

Soft Condensed Matter · Physics 2022-05-11 Till Böhmer , Jan Philipp Gabriel , Rolf Zeißler , Timo Richter , Thomas Blochowicz

A major mystery of glass-forming liquids is the non-Arrhenius temperature-dependence of the average relaxation time. This paper briefly reviews the classical phenomenological models for this phenomenon - the free-volume model and the…

Condensed Matter · Physics 2015-06-25 Jeppe C. Dyre

Published dielectric and shear data of six molecular glass formers and one polymer are evaluated in terms of a spectrum of thermally activated processes, with the same barrier density for the retardation spectrum of shear and dielectrics.…

Disordered Systems and Neural Networks · Physics 2009-09-24 U. Buchenau

We perform a numerical simulation of energy relaxation in three-dimensional electron glasses in the strongly localized regime at finite temperatures. We consider systems with no interactions, with long-range Coulomb interactions and with…

Disordered Systems and Neural Networks · Physics 2009-10-31 A. Perez-Garrido , M. Ortuno , A. Diaz-Sanchez , E. Cuevas

The aging dynamics of a colloidal glass has been studied by multiangle Dynamic Light Scattering, Neutron Spin Echo, X-ray Photon Correlation Spectroscopy and Molecular Dynamics simulations. The two relaxation processes, microscopic (fast)…

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