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In single particle imaging experiments, beams of individual nanoparticles are exposed to intense pulses of x-rays from free-electron lasers to record diffraction patterns of single, isolated molecules. The reconstruction for structure…

The dc response of an electrochemical thin film, such as the separator in a micro-battery, is analyzed by solving the Poisson-Nernst-Planck equations, subject to boundary conditions appropriate for an electrolytic/galvanic cell. The model…

Chemical Physics · Physics 2009-09-29 Martin Z. Bazant , Kevin T. Chu , B. J. Bayly

Long-ranged electrostatic interactions in electrolytes modify their contact angles on charged substrates in a scale and geometry dependent manner. For angles measured at scales smaller than the typical Debye screening length, the wetting…

Soft Condensed Matter · Physics 2009-11-07 Tom Chou

In this letter we analyze the effects of an externally applied electric field on thermal fluctuations for a fluid containing charged species. We show in particular that the fluctuating Poisson-Nernst-Planck equations for charged…

Motivated by contact resistance on the front side of a crystalline silicon solar cell, we formulate and analyse a two-dimensional mathematical model for electron flow across a poorly conducting (glass) layer situated between silver…

Analysis of PDEs · Mathematics 2014-12-08 J. P. Black , C. J. W. Breward , P. D. Howell

Theoretically and experimentally, we study electroviscous phenomena resulting from charge-flow coupling in a nanoscale capillary. Our theoretical approach relies on Poisson-Boltzmann mean-field theory and on coupled linear relations for…

We report on direct numerical simulations of the effect of electrostatic charges on particle-laden duct flows. The corresponding electrostatic forces are known to affect particle dynamics at small scales and the associated turbophoretic…

Fluid Dynamics · Physics 2020-12-30 Holger Grosshans , Claus Bissinger , Mathieu Calero , Miltiadis V. Papalexandris

An electrostatic hexapole lens is used to manipulate the transverse properties of a beam of barium fluoride molecules from a cryogenic buffer gas source. The spatial distribution of the beam is measured by recording state-selective…

We study the effects of electrostatic gating on the lateral distribution of charge carriers in two dimensional devices, in a non-linear dielectric environment. We compute the charge distribution using the Thomas-Fermi approximation to model…

Mesoscale and Nanoscale Physics · Physics 2020-03-05 Eylon Persky , Hyeok Yoon , Yanwu Xie , Harold Y. Hwang , Jonathan Ruhman , Beena Kalisky

We study a model electrochemical thin film at dc currents exceeding the classical diffusion-limited value. The mathematical problem involves the steady Poisson-Nernst-Planck equations for a binary electrolyte with nonlinear boundary…

Chemical Physics · Physics 2007-05-23 Kevin T. Chu , Martin Z. Bazant

The problem of the one dimensional electro-diffusion of ions in a strong binary electrolyte is considered. In such a system the solute dissociates completely into two species of ions with unlike charges. The mathematical description…

Chemical Physics · Physics 2012-03-28 Sandip Ghosal , Zhen Chen

Two overall neutral surfaces with positive and negative charged domains ("patches") have been shown in recent experiments to exhibit long-range attraction when immersed in an ionic solution. Motivated by the experiments, we calculate…

Soft Condensed Matter · Physics 2016-08-31 Ram M. Adar , David Andelman , Haim Diamant

Nonlinear electrokinetic phenomena, where electrically driven fluid flows depend nonlinearly on the applied voltage, are commonly encountered in aqueous suspensions of colloidal particles. A prime example is the induced-charge…

Soft Condensed Matter · Physics 2024-11-27 Zhanwen Wang , Michael J. Miksis , Petia M. Vlahovska

The interaction of charges in dielectric materials is screened by the dielectric constant of the bulk dielectric. In dielectric theories, screening is assigned to the surface charge appearing from preferential orientations of dipoles along…

Soft Condensed Matter · Physics 2019-09-04 Salman Seyedi , Daniel R. Martin , Dmitry V. Matyushov

Ion flow in charged nanopores is strongly influenced by the ratio of the Debye length to the pore radius. We investigate the asymptotic behaviour of solutions to the Poisson-Nernst-Planck (PNP) system in narrow pore like geometries and…

Analysis of PDEs · Mathematics 2019-04-10 B. Matejczyk , J. -F. Pietschmann , G. Richardson , M. -T. Wolfram

Hydrodynamic flow of charge carriers in graphene is an energy flow unlike the usual mass flow in conventional fluids. In neutral graphene, the energy flow is decoupled from the electric current, making it difficult to observe the…

Mesoscale and Nanoscale Physics · Physics 2021-08-26 B. N. Narozhny , I. V. Gornyi , M. Titov

Electroosmotic pumping of fluid through a nanopore that traverses an insulating membrane is considered. The density of surface charge on the membrane is assumed uniform, and sufficiently low for the Poisson-Boltzmann equation to be…

Fluid Dynamics · Physics 2014-05-15 M. Mao , J. D. Sherwood , S. Ghosal

On the basis of a hydrodynamical model analogous to that in critical fluids, we investigate the influences of shear flow upon the electrostatic contribution to the viscosity of binary electrolyte solutions in the Debye-H\"{u}ckel…

Statistical Mechanics · Physics 2007-05-23 Hirofumi Wada

In low-permeability rock, fluid and mineral transport occur in pores and fracture apertures at the scale of micrometers and below. At this scale, the presence of surface charge, and a resultant electrical double layer, may considerably…

Fluid Dynamics · Physics 2018-05-02 Asger Bolet , Gaute Linga , Joachim Mathiesen

Classical theory of the electric double layer is based on the fundamental assumption of a dilute solution of point ions. There are a number of situations such as high applied voltages, high concentration of electrolytes, systems with…

Fluid Dynamics · Physics 2015-06-11 Brian D. Storey , Martin Z. Bazant