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Shortened abstract: Microcanonical equilibrium macrostates are characterized as the solutions of a constrained minimization problem, while canonical equilibrium macrostates are characterized as the solutions of a related, unconstrained…

Statistical Mechanics · Physics 2007-05-23 M. Costeniuc , R. S. Ellis , H. Touchette , B. Turkington

Boltzmann's principle S(E,N,V...)=ln W(E,N,V...) allows the interpretation of Statistical Mechanics of a closed system as Pseudo-Riemannian geometry in the space of the conserved parameters E,N,V... (the conserved mechanical parameters in…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

We extend the recently developed non-gaussian thermodynamic formalism \cite{tre98} of a (presumably strongly turbulent) non-Markovian medium to its most general form that allows for the formulation of a consistent thermodynamic theory. All…

Space Physics · Physics 2009-10-31 R. A. Treumann

The postulational basis of classical thermodynamics has been expanded to incorporate equilibrium fluctuations. The main additional elements of the proposed thermodynamic theory are the concept of quasi-equilibrium states, a definition of…

Statistical Mechanics · Physics 2019-06-11 Y. Mishin

The local physical properties of an isolated quantum statistical system in the stationary state reached long after a quench are generically described by the Gibbs ensemble, which involves only its Hamiltonian and the temperature as a…

Statistical Mechanics · Physics 2017-06-13 Laura Foini , Andrea Gambassi , Robert Konik , Leticia F. Cugliandolo

Systems with a long-term stationary state that possess as a spatio-temporally fluctuation quantity $\beta$ can be described by a superposition of several statistics, a "super statistics". We consider first, the Gamma, log-normal and…

Statistical Mechanics · Physics 2015-06-05 O. Obregón , A. Gil-Villegas

Finite heat reservoir capacity and temperature fluctuations lead to modification of the well known canonical exponential weight factor. Requiring that the corrections least depend on the one-particle energy, we derive a deformed entropy,…

Statistical Mechanics · Physics 2016-05-20 T. S. Biro , G. G. Barnafoldi , P. Van

We describe in detail a mathematical framework in which statistical ensembles of hybrid classical-quantum systems can be properly described. We show how a maximum entropy principle can be applied to derive the microcanonical ensemble of…

Statistical Mechanics · Physics 2026-03-12 J. L. Alonso , C. Bouthelier-Madre , A. Castro , J. Clemente-Gallardo , J. A. Jover-Galtier

It has recurrently been proposed that the Boltzmann textbook definition of entropy $S(E)=k\ln \Omega (E)$ in terms of the number of microstates $\Omega (E)$ with energy $E$ should be replaced by the expression $S_G(E)=k\ln \sum_{E^\prime…

Statistical Mechanics · Physics 2014-06-12 Jose M. G. Vilar , J. Miguel Rubi

The Eigenstate Thermalization Hypothesis implies that for a thermodynamically large system in one of its eigenstates, the reduced density matrix describing any finite subsystem is determined solely by a set of {\it relevant} conserved…

Statistical Mechanics · Physics 2017-01-04 Sourav Nandy , Arnab Sen , Arnab Das , Abhishek Dhar

Employing different statistical ensembles may lead to qualitatively different results concerning averages of physical observables on the mesoscopic scale. Here we discuss differences between the canonical and the grandcanonical ensembles…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 Alex Kamenev , Yuval Gefen

We propose a Gaussian ensemble as a description of the long-time dynamics of isolated quantum integrable systems. Our approach extends the Generalized Gibbs Ensemble (GGE) by incorporating fluctuations of integrals of motion. It is…

Statistical Mechanics · Physics 2017-05-24 Hyungwon Kim , Anatoli Polkovnikov , Emil A. Yuzbashyan

Descriptions of molecular systems usually refer to two distinct theoretical frameworks. On the one hand the quantum pure state, i.e. the wavefunction, of an isolated system which is determined to calculate molecular properties and to…

Statistical Mechanics · Physics 2011-03-17 Barbara Fresch , Giorgio J. Moro

Randomness is ubiquitous in many applications across data science and machine learning. Remarkably, systems composed of random components often display emergent global behaviors that appear deterministic, manifesting a transition from…

Machine Learning · Computer Science 2025-05-16 Luca Muscarnera , Luigi Loreti , Giovanni Todeschini , Alessio Fumagalli , Francesco Regazzoni

The classical Gaussian ensembles of random matrices can be constructed by maximizing Boltzmann-Gibbs-Shannon's entropy, S_{BGS} = - \int d{\bf H} [P({\bf H})] \ln [P({\bf H})], with suitable constraints. Here we construct and analyze…

Statistical Mechanics · Physics 2009-11-10 Fabricio Toscano , Raul O. Vallejos , Constantino Tsallis

In ordinary Boltzmann-Gibbs thermostatistics, the relative entropy expression plays the role of generalized free energy, providing the difference between the off-equilibrium and equilibrium free energy terms associated with Boltzmann-Gibbs…

Statistical Mechanics · Physics 2007-12-13 G. B. Bagci

In high-energy collisions the number of the created particles is far less than the thermodynamic limit, especially in small colliding systems (e.g. proton-proton). Therefore final-state effects and fluctuations in the one-particle energy…

High Energy Physics - Phenomenology · Physics 2017-06-28 Gábor Bíró , Gergely Gábor Barnaföldi , Tamás Sándor Biró , Károly Ürmössy

We examine the {combinatorial} or {probabilistic} definition ("Boltzmann's principle") of the entropy or cross-entropy function $H \propto \ln \mathbb{W}$ or $D \propto - \ln \mathbb{P}$, where $\mathbb{W}$ is the statistical weight and…

Statistical Mechanics · Physics 2015-05-13 Robert K. Niven

The general fluctuation theory is reviewed with special attention to the role played by different ensembles, and is extended to incorporate stationary metastable states obtained in the long time limit. The fluctuation in a quantity depends…

Statistical Mechanics · Physics 2007-05-23 P. D. Gujrati

We show that the stochastic interpretation of Tsallis' thermostatistics given recently by Beck [Phys. Rev. Lett {\bf 87}, 180601 (2001)] leads naturally to a multi-parameter generalization. The resulting class of distributions is able to…

Classical Physics · Physics 2009-11-07 Fabio Sattin , Luca Salasnich