Related papers: From Boltzmann-Gibbs ensemble to generalized ensem…
The standard formulation of thermostatistics, being based on the Boltzmann-Gibbs distribution and logarithmic Shannon entropy, describes idealized uncorrelated systems with extensive energies and short-range interactions. In this letter, we…
The statistical mechanics of a cloud of particles interacting via their gravitational potentials is an old problem which encounters some issues when the traditional Boltzmann-Gibbs statistics is applied. In this article, we consider the…
We develop a method using a coarse graining of the energy fluctuations of an equilibrium quantum system which produces simple parameterizations for the behaviour of the system. As an application, we use these methods to gain more…
We show, in two different ways, that the Tsallis' partition function and its derivatives are related to thermodynamic quantities such as entropy, internal energy, etc., in the same way as in Boltzmann-Gibbs' formalism, with the Lagrange…
Within the Tsallis thermodynamics' framework, and using scaling properties of the entropy, we derive a generalization of the Gibbs-Duhem equation. The analysis suggests a transformation of variables that allows standard thermodynamics to be…
Conventional Boltzmann--Gibbs statistical mechanics successfully describes systems with weak to moderate correlations, where the number of accessible configurations $W(N)$ grows exponentially with the number of degrees of freedom~$N$.…
The microcanonical ensemble has long been a starting point for the development of thermodynamics from statistical mechanics. However, this approach presents two problems. First, it predicts that the entropy is only defined on a discrete set…
In the present paper the conditions for the validity of the Tsallis' Statistics are analyzed. The same has been done following the analogy with the traditional case: starting from the microcanonical description of the systems and taking…
We show that there exists a natural way to define a condition of generalized thermal equilibrium between systems governed by Tsallis thermostatistics, under the hypotheses that i) the coupling between the systems is weak, ii) the structure…
This work explores fundamental statistical and thermodynamic properties of short-and long-range-interacting systems. The purpose of this study is twofold. Firstly, we rigorously prove that the probability distribution of arbitrary few-body…
Comparison of the thermodynamic entropy with Boltzmann's principle shows that under conditions of constant volume the total number of arrangements in simple thermodynamic systems with temperature-independent heat capacities is TC/k. A…
Maximum-entropy ensembles are key primitives in statistical mechanics from which thermodynamic properties can be derived. Over the decades, several approaches have been put forward in order to justify from minimal assumptions the use of…
In bulk systems the calculation of the main thermodynamic quantities leads to the same expectation values in the thermodynamic limit, regardless of the choice of the statistical ensemble. Single linear molecules can be still regarded as…
The Boltzmann--Gibbs entropy is a functional on the space of probability measures. When a state space is countable, one characterization of the Boltzmann--Gibbs entropy is given by the Shannon--Khinchin axioms, which consist of continuity,…
This is an analysis of the additivity of the entropy of thermodynamical systems with finite heat baths. It is presented an expression for the physical entropy of weakly interacting ergodic systems, and it is shown that it is valid for both…
The maximum entropy formalism developed by Jaynes determines the relevant ensemble in nonequilibrium statistical mechanics by maximising the entropy functional subject to the constraints imposed by the available information. We present an…
The foundations of the Boltzmann-Gibbs (BG) distributions for describing equilibrium statistical mechanics of systems are examined. Broadly, they fall into: (i) probabilistic paaroaches based on the principle of equal a priori probability…
The Gibbs entropy of a macroscopic classical system is a function of a probability distribution over phase space, i.e., of an ensemble. In contrast, the Boltzmann entropy is a function on phase space, and is thus defined for an individual…
After reviewing some fundamental results derived from the introduction of the generalized Gibbs canonical ensemble, such as the called thermodynamic uncertainty relation, it is described a physical scenario where such a generalized ensemble…
Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble. Classically this is the manifold of all points in the $N-$body phase space with the given total energy. Due to Boltzmann's principle,…