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We show how one can measure the signal from slow jumps of a single molecule between metastable positions using a setup where the molecule is fixed to one lead, and one of the coupling strengths is controlled externally. Such a measurement…

Mesoscale and Nanoscale Physics · Physics 2013-04-04 Tero T. Heikkila , Wolfgang Belzig

We report on inelastic electron tunneling spectroscopy measurements carried out on single molecules incorporated into a mechanically controllable break-junction of Au and Pt electrodes at low temperature. Here we establish a correlation…

Mesoscale and Nanoscale Physics · Physics 2010-11-16 Youngsang Kim , Hyunwook Song , Florian Strigl , Hans-Fridtjof Pernau , Takhee Lee , Elke Scheer

A theoretical model of a single molecule coupled to many vibronic modes is presented. At low energies, transport is dominated by electron-vibron processes where transfer of an electron through the dot is accompanied by the…

Mesoscale and Nanoscale Physics · Physics 2011-08-19 Abdullah Yar , Andrea Donarini , Sonja Koller , Milena Grifoni

A theoretical model of a single molecule coupled to many vibronic modes is presented. At low energies, transport is dominated by electron-vibron processes where transfer of an electron through the dot is accompanied by the…

Mesoscale and Nanoscale Physics · Physics 2015-03-17 Abdullah Yar , Andrea Donarini , Sonja Koller , Milena Grifoni

In single-molecule transistors, we observe inelastic cotunneling features that correspond energetically to vibrational excitations of the molecule, as determined by Raman and infrared spectroscopy. This is a form of inelastic electron…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 L. H. Yu , Z. K. Keane , J. W. Ciszek , L. Cheng , M. P. Stewart , J. M. Tour , D. Natelson

The effect of electron-phonon coupling on the current noise in a molecular junction is investigated within a simple model. The model comprises a 1-level bridge representing a molecular level that connects between two free electron…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Michael Galperin , Abraham Nitzan , Mark A. Ratner

A pair of coherent femtosecond pulse excitations applied to a molecule with strong electron-phonon coupling creates a coherent superposition of a low momentum and a high momentum wavepacket in the vibrational states of both the excited…

Quantum Physics · Physics 2009-11-06 Holger F. Hofmann , Takao Fuji , Takayoshi Kobayashi

Interaction of nonrelativistic electrons with a standing electromagnetic wave is considered. The modulation amplitude of an electron current in the field of a standing or traveling electromagnetic wave is calculated in the quantum approach.

Quantum Physics · Physics 2017-09-22 M. A. Kutlan

We investigate the role of electronic-vibrational coupling in resonant electron transport through single-molecule junctions, taking into account that the corresponding coupling strengths may depend on the charge and excitation state of the…

Mesoscale and Nanoscale Physics · Physics 2016-03-23 Andre Erpenbeck , Rainer Härtle , Michel Bockstedte , Michael Thoss

The realization of molecular-based electronic devices depends to a large extent on the ability to mechanically stabilize the involved molecular bonds, while making use of efficient resonant charge transport through the device. Resonant…

Mesoscale and Nanoscale Physics · Physics 2018-09-11 David Gelbwaser-Klimovsky , Alán Aspuru-Guzik , Michael Thoss , Uri Peskin

We study spin-dependent transport in a suspended carbon nanotube quantum dot in contact with two ferromagnetic leads and with the dot's spin coupled to the flexural mechanical modes. The spin-vibration interaction induces spin-flip…

Mesoscale and Nanoscale Physics · Physics 2015-03-03 Pascal Stadler , Wolfgang Belzig , Gianluca Rastelli

Devices for nano- and molecular size electronics are currently a focus of research aimed at an efficient current rectification and switching. A few generic molecular scale devices are reviewed here on the basis of first-principles and model…

Soft Condensed Matter · Physics 2015-06-25 A. M. Bratkovsky

We analyze theoretically the interplay between the torsional and the rotational motion of an aligned biphenyl-like molecule. To do so, we consider a transition between two electronic states with different internal torsional potentials,…

Chemical Physics · Physics 2017-02-08 Juan J. Omiste , Lars Bojer Madsen

A polaron model proposed as a possible mechanism for nonlinear conductance [Galperin M, Ratner M A, and Nitzan A 2005 Nano Lett. 5 125-30] is revisited with focus on the differences between the weak and strong molecule-lead coupling cases.…

Mesoscale and Nanoscale Physics · Physics 2008-08-26 Michael Galperin , Abraham Nitzan , Mark A. Ratner

A theoretical investigation of the dissociative excitation by electron impact on the NO molecule is presented, aiming to make up for the lack of data for this process in the literature. A full set of vibrationally-resolved cross sections…

Atomic Physics · Physics 2020-05-22 V. Laporta , J. Tennyson , I. F. Schneider

The current-induced vibrational dynamics is a key factor determining the stability of molecular nanojunctions. Beyond conventional Joule heating, a different mechanism caused by nonconservative current-induced forces has been predicted for…

Mesoscale and Nanoscale Physics · Physics 2026-02-20 Martin Mäck , Michael Thoss , Samuel L. Rudge

It has been experimentally observed that weakly conducting suspended films of smectic liquid crystals undergo electroconvection when subjected to a large enough potential difference. The resulting counter-rotating vortices form a very…

patt-sol · Physics 2009-10-30 V. B. Deyirmenjian , Zahir A. Daya , Stephen W. Morris

In this article we present a novel semi-analytical approach to calculate first-order electron-vibration coupling constants within the framework of density functional theory. It combines analytical expressions for the first-order derivative…

Mesoscale and Nanoscale Physics · Physics 2013-11-12 Marius Bürkle , Janne K. Viljas , Thomas J. Hellmuth , Elke Scheer , Florian Weigend , Gerd Schön , Fabian Pauly

Planar rotors can be realized by confining molecular ions or charged nanoparticles together with atomic ions in a Paul trap. We study the case of molecular ions or charged nanoparticles that have an electric dipole moment which couples to…

Quantum Physics · Physics 2025-04-02 Monika Leibscher , Ferdinand Schmidt-Kaler , Christiane P. Koch

We use a novel technique to experimentally explore transport properties through a single metallic nanoparticle with variable coupling to electric leads. For strong dot-lead coupling the conductance is an oscillatory function of the gate…

Mesoscale and Nanoscale Physics · Physics 2017-09-05 O. Bitton , A. Frydman , R. Berkovits , D. B. Gutman
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