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We report a Raman scattering investigation of multiferroic bismuth ferrite BiFeO3 epitaxial (c-axis oriented) thin films from -192 to 1000C. Phonon anomalies have been observed in three temperature regions: in the gamma-phase from 930C to…

Materials Science · Physics 2015-05-14 R. Palai , J. F. Scott , R. S. Katiyar

We determine the nature of coupled phonons and magnetic excitations in AlFeO3 using inelastic light scattering from 5 K to 315 K covering a spectral range from 100-2200 cm-1 and complementary first-principles density functional theory-based…

Strongly Correlated Electrons · Physics 2012-05-01 Pradeep Kumar , A. Bera , D. V. S. Muthu , S. N. Shirodkar , R. Saha , A. Shireen , A. Sundaresan , U. V. Waghmare , A. K. Sood , C. N. R. Rao

We present evidence for a concomitant structural and ferroelectric transformation around $T_S\sim 360$ K in multiferroic BiFeO$_3$/LaAlO$_3$ thin films close to the tetragonal phase. Phonon excitations are investigated by using Raman…

Strongly Correlated Electrons · Physics 2015-05-30 K. -Y. Choi , S. H. Do , P. Lemmens , D. Wulferding , C. S. Woo , J. H. Lee , K. Chu , C. -H. Yang

We report on bifurcations effect mediated by the electron-phonon coupling in a concentrated rare-earth-containing antiferromagnet, observed in the spectra of coupled $4f$-electron-phonon modes under the influence of an external magnetic…

Temperature-dependent Raman spectra of TbMnO$_3$ from 5 K to 300 K in the spectral range of 200 to 1525 cm$^{-1}$ show five first-order Raman allowed modes and two high frequency modes. The intensity ratio of the high frequency Raman band…

Strongly Correlated Electrons · Physics 2010-04-12 Pradeep Kumar , Surajit Saha , D. V. S. Muthu , J. R. Sahu , A. K. Sood , C. N. R. Rao

Raman scattering measurements on BiFeO3 single crystals show an important coupling between the magnetic order and lattice vibrations. The temperature evolution of phonons shows that the lowest energy E and A1 phonon modes are coupled to the…

Strongly Correlated Electrons · Physics 2010-10-12 P. Rovillain , M. Cazayous , Y. Gallais , A. Sacuto , R. P. S. M. Lobo , D. Lebeugle , D. Colson

We report inelastic neutron scattering measurements of the phonon spectra in a pure powder sample of the multiferroic material BiFeO3. A high-temperature range was covered to unravel the changes in the phonon dynamics across the Neel (T_N ~…

Materials Science · Physics 2015-03-19 M. Zbiri , H. Schober , N. Choudhury , R. Mittal , S. L. Chaplot , S. J. Patwe , S. N. Achary , A. K. Tyagi

We present a fully analytical model of hybridization between magnon, and phonons observed experimentally in magneto-Raman scattering in van der Waals (vdW) antiferromagnets (AFM). Here, the representative material, FePS3, has been shown to…

Mesoscale and Nanoscale Physics · Physics 2025-01-03 Somsubhra Ghosh , Mainak Palit , Sujan Maity , Subhadeep Datta

Spin-phonon coupling, the interaction of spins with surrounding lattice is a key parameter to understand the underlying physics of multiferroics and engineer their magnetization dynamics. Elementary excitations in multiferroic materials are…

Materials Science · Physics 2020-11-05 Bommareddy Poojitha , Anjali Rathore , Ankit Kumar , Surajit Saha

A new effect originating from the crystal-field-excitation - phonon coupling was observed (in the far infrared spectra of a multiferroic PrFe3(BO3)4). The reststrahlen band corresponding to the A2 symmetry nondegenerate phonon mode near 50…

Materials Science · Physics 2014-11-05 K. N. Boldyrev , T. N. Stanislavchuk , A. A. Sirenko , L. N. Bezmaternykh , M. N. Popova

We present neutron inelastic scattering measurements of the low-energy phonons in single crystal BiFeO3. The dispersions of the three acoustic phonon modes (LA along [100], TA1 along [010] and TA2 along [110]) and two low energy optic…

Our measured dielectric constant and mechanical response of multiferroic BiFeO3 indicate four phase transitions below room temperature. Features correlate with those reported at 50K (from a peak in the zero-field-cooled magnetic…

Materials Science · Physics 2008-06-23 S. A. T. Redfern , C. Wang , J. W. Hong , G. Catalan , J. F. Scott

Infrared reflectivity spectra of cubic SrMnO$_{3}$ ceramics reveal 18 % stiffening of the lowest-frequency phonon below the antiferromagnetic phase transition occurring at T$_{N}$ = 233 K. Such a large temperature change of the polar phonon…

Materials having strong coupling between different degrees of freedom such as spin, lattice, orbital, and charge are of immense interest due to their potential device applications. Here, we have stabilized the 9R phase of BaMnO3, by Sr (Ti)…

Materials Science · Physics 2021-10-27 Bommareddy Poojitha , Anjali Rathore , Surajit Saha

Spin-charge-lattice coupling mediated by multi-magnon processes is demonstrated in multiferroic BiFeO3. Experimental evidence of two and three magnons excitations as well as multimagnon coupling at electronic energy scales and high…

We report remarkable multiferroic effects in polycrystalline Bi2Fe4O9. High-resolution X-ray diffraction shows that this compound has orthorhombic structure. Magnetic measurements confirm an antiferromagnetic transition around 260 K. A…

Materials Science · Physics 2009-11-13 A. K. Singh , S. D. Kaushik , Brijesh Kumar , A. Venimadhav , P. K. Mishra , V. Siriguri , S. Patnaik

We have performed Raman scattering investigations on the high energy magnetic excitations in a BiFeO$_3$ single crystal as a function of both temperature and laser excitation energy. A strong feature observed at 1250 cm$^{-1}$ in the Raman…

Strongly Correlated Electrons · Physics 2018-11-13 M. Cazayous , A. Sacuto , D. Lebeugle , D. Colson

Terahertz and far-infrared electric and magnetic responses of hexagonal piezomagnetic YMnO3 single crystals are investigated. Antiferromagnetic resonance is observed in the spectra of magnetic permeability mu_a [H(omega) oriented within the…

Materials Science · Physics 2012-02-13 C. Kadlec , V. Goian , K. Z. Rushchanskii , P. Kuzel , M. Lezaic , K. Kohn , R. V. Pisarev , S. Kamba

The magnetic susceptibility between 1.5 and 800 K, the infrared reflectivity at room temperature and the temperature dependence of the dielectric constant at mm-wavelengths are reported for single crystalline BiFeO3. A well developed…

Strongly Correlated Electrons · Physics 2010-07-22 Jun Lu , M Schmidt , P Lunkenheimer , A Pimenov , A A Mukhin , V D Travkin , A Loidl

We have identified three of the four magnetoelectric modes of multiferroic BiFeO$_3$ measured using THz spectroscopy. Excellent agreement with the observed peaks is obtained by including the effects of easy-axis anisotropy along the…

Strongly Correlated Electrons · Physics 2015-06-11 Randy S. Fishman , Nobuo Furukawa , Jason T. Haraldsen , Masaaki Matsuda , Shin Miyahara
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