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These lecture notes give a short review of methods such as the matrix ansatz, the additivity principle or the macroscopic fluctuation theory, developed recently in the theory of non-equilibrium phenomena. They show how these methods allow…

Statistical Mechanics · Physics 2009-11-13 B. Derrida

In this contribution we prove that the entropy of an N-body isolated system can not decrease and the entropy production should be non-negative provided the system possesses an equilibrium state. We define the entropy as a functional of the…

Statistical Mechanics · Physics 2007-05-23 A. Perez-Madrid

Entropy is a fundamental thermodynamic quantity that is a measure of the accessible microstates available to a system, with the stability of a system determined by the magnitude of the total entropy of the system. This is valid across truly…

Measuring entropy production of a system directly from the experimental data is highly desirable since it gives a quantifiable measure of the time-irreversibility for non-equilibrium systems and can be used as a cost function to optimize…

Statistical Mechanics · Physics 2024-07-16 Prashant Singh , Karel Proesmans

Entropy functionals are computed for non-stationary distributions of particles of Lorentz gas and hard disks. The distributions consisting of beams of particles are found to have the largest amount of entropy and entropy increase. The…

Statistical Mechanics · Physics 2007-05-23 Maurice Courbage , Seyed Majid Saberi Fathi

If the von Neumann equation is modified by time dependent statistical weights, the time rate of entropy, the entropy exchange and production of a Schottky system are derived whose Hamiltonian does not contain the interaction with the…

Quantum Physics · Physics 2019-01-30 Wolfgang Muschik

IIt is demonstrated that the entropy of statistical mechanics and of information theory, $S({\bf p}) = -\sum p_i \log p_i $ may be viewed as a measure of correlation. Given a probability distribution on two discrete variables, $p_{ij}$, we…

Mathematical Physics · Physics 2007-05-23 John H. Van Drie

The dissipation of general convex entropies for continuous time Markov processes can be described in terms of backward martingales with respect to the tail filtration. The relative entropy is the expected value of a backward submartingale.…

Probability · Mathematics 2015-01-27 Joaquin Fontbona , Benjamin Jourdain

Macroscopic nonextensive thermodynamics is studied without recourse to microscopic statistical mechanics. It is shown that if entropy is nonextensive, the concept of physical temperature introduced through the generalized zeroth law of…

Statistical Mechanics · Physics 2007-05-23 Sumiyoshi Abe

We obtain estimates on the exponential rate of decay of the relative entropy from equilibrium for Markov processes with a non-local infinitesimal generator. We adapt some of the ideas coming from the Bakry-Emery approach to this setting. In…

Probability · Mathematics 2014-02-14 Paolo Dai Pra , Gustavo Posta

In the study of non-equilibrium statistical mechanics, Ruelle derived explicit formulae for entropy production of smooth dynamical systems. The vanishing or strict positivity of entropy production is determined by the {\it entropy formula…

Dynamical Systems · Mathematics 2025-11-07 Gang Liao , Shirou Wang

The correspondence principle plays a fundamental role in quantum mechanics, which naturally leads us to inquire whether it is possible to find or determine close classical analogs of quantum states in phase space -- a common meeting point…

Quantum Physics · Physics 2022-01-28 A. S. Sanz

The rate of change of entropy $\dot S$ is measured for a system of particles floating on the surface of a fluid maintained in a turbulent steady state. The resulting coagulation of the floaters allows one to relate $\dot S$ to the velocity…

Chaotic Dynamics · Physics 2009-11-11 M. M. Bandi , W. I. Goldburg , J. R. Cressman

Our point of departure are the unitary dynamics of closed quantum systems as generated from the Schr\"odinger equation. We focus on a class of quantum models that typically exhibit roughly exponential relaxation of some observable within…

Quantum Physics · Physics 2011-12-23 Christian Bartsch , Jochen Gemmer

The entropy of a classical thermally isolated Hamiltonian system is given by the logarithm of the measure of phase space enclosed by the constant energy hyper-surface, also known as volume entropy. It has been shown that on average the…

Statistical Mechanics · Physics 2016-10-12 Michele Campisi

We investigate, via computer simulations, the time evolution of the (Boltzmann) entropy of a dense fluid not in local equilibrium. The macrovariables $M$ describing the system are the (empirical) particle density $f=\{f(\un{x},\un{v})\}$…

Statistical Mechanics · Physics 2009-11-10 P. L. Garrido , S. Goldstein , J. L. Lebowitz

We describe a framework in which is possible to develop and implement algorithms for the approximation of invariant measures of dynamical systems with a given bound on the error of the approximation. Our approach is based on a general…

Dynamical Systems · Mathematics 2017-10-05 Stefano Galatolo , Isaia Nisoli

For a Markov process the detailed balance condition is equivalent to the time-reversibility of the process. For stochastic differential equations (SDE's) time discretization numerical schemes usually destroy the property of…

Numerical Analysis · Mathematics 2019-02-20 Markos Katsoulakis , Yannis Pantazis , Luc Rey-Bellet

In our derivation of the second law of thermodynamics from the relation of adiabatic accessibility of equilibrium states we stressed the importance of being able to scale a system's size without changing its intrinsic properties. This…

Mathematical Physics · Physics 2015-06-19 Elliott H. Lieb , Jakob Yngvason

A formula for the transition density of a Markov process defined by an infinite-dimensional stochastic equation is given in terms of the Ornstein--Uhlenbeck bridge and a useful lower estimate on the density is provided. As a consequence,…

Probability · Mathematics 2007-05-23 B. Goldys , B. Maslowski