Related papers: The c2d Spitzer spectroscopic survey of ices aroun…
We report the first fully sampled maps of the distribution of interstellar CO2 ices, H2O ices and total hydrogen nuclei, as inferred from the 9.7 micron silicate feature, toward the star-forming region Cepheus A East with the IRS instrument…
Currently ~36 different absorption bands have been detected in the infrared spectra of cold, dense interstellar and circumstellar environments. These are attributed to the vibrational transitions of ~17 different molecules frozen on dust…
The properties of the ices that form in dense molecular clouds represent an important set of initial conditions in the evolution of interstellar and preplanetary matter in regions of active star formation. Of the various spectral features…
The evolution of interstellar ices can be studied with thermal tracers such as the vibrational modes of CO$_2$ ice that show great diversity depending on their local chemical and thermal environment. In this work we present JWST…
H2O is the most abundant component of astrophysical ices. In most lines of sight it is not possible to fit both the H2O 3 um stretching, the 6 um bending and the 13 um libration band intensities with a single pure H2O spectrum. Recent…
We present Temperature Programmed Desorption (TPD) experiments of CO and N2 ices in pure, layered and mixed morphologies at various ice "thicknesses" and abundance ratios as well as simultaneously taken Reflection Absorption Infrared…
CO$_2$ is an important, stable, and abundant molecule in the Universe, but it is very difficult to detect because it has no observable pure rotational transitions. The unique sensitivity and resolution of the James Webb Space Telescope…
CO2 is the third most abundant ice component found on dust grains in star-forming regions and a common ingredient of exoplanet atmospheres. Characterization of its adsorption properties on ices through the binding energy (BE) is essential…
With the goal to study the physical and chemical evolution of ices in solar-mass systems, a spectral survey is conducted of a sample of 41 low luminosity YSOs using 3-38 um Spitzer and ground-based spectra. The long-known 6.0 and 6.85 um…
JWST has shown that CO2 and CO are common on the surfaces of objects in the Kuiper belt and have apparent surface coverages even higher than that of water ice, though water ice is expected to be significantly more abundant in the bulk…
CO2 ice is one of the most abundant components in ice-coated interstellar ices besides H2O and CO, but the most favorable path to CO2 ice is still unclear. Molecular dynamics calculations on the ultraviolet photodissociation of different…
The carbon isotope ratio is a powerful tool for studying the evolution of stellar systems. Recent detections of CO isotopologues in disks and exoplanet atmospheres pointed towards significant fractionation in these systems. In order to…
CO$_2$ ice is an important reservoir of carbon and oxygen in star and planet forming regions. Together with water and CO, CO$_2$ sets the physical and chemical characteristics of interstellar icy grain mantles, including desorption and…
Diffusion of species in icy dust grain mantles is a fundamental process that shapes the chemistry of interstellar regions; yet measurements of diffusion in interstellar ice analogs are scarce. Here we present measurements of CO diffusion…
JWST is discovering a plethora of species in planet-forming disks around very low-mass stars such as C2H2, C6H6, C4H2, CH3 etc. The column densities of these species retrieved from 0D slab models are very large, e.g. of the order of…
In regions where stars form, variations in density and temperature can cause gas to freeze-out onto dust grains forming ice mantles, which influences the chemical composition of a cloud. The aim of this paper is to understand in detail the…
The H II region W40 harbors a small group of young, hot stars behind roughly 9 magnitudes of visual extinction. We have detected gaseous carbon monoxide (CO) and diatomic carbon (C_2) in absorption toward the star W40 IRS 1a. The 2-0 R0,…
The relative abundances of atomic and molecular species in planet-forming disks around young stars provide important constraints on photochemical disk models and provide a baseline for calculating disk masses from measurements of trace…
Carbon monoxide (CO) is the second most abundant molecule in the gas-phase of the interstellar medium. In dense molecular clouds, it is also present in the solid-phase as a constituent of the mixed water-dominated ices covering dust grains.…
Infrared-dark high-mass clumps are among the most promising objects to study the initial conditions of the formation process of high-mass stars and rich stellar clusters. In this work, we have observed the (3-2) rotational transition of…