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Related papers: Proving the Perdew-Burke-Ernzerhof density functio…

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We assess the validity of various exchange-correlation functionals for computing the structural, vibrational, dielectric, and thermodynamical properties of materials in the framework of density-functional perturbation theory (DFPT). We…

By adding a non-linear core correction to the well established Dual Space Gaussian type pseudopotentials for the chemical elements up to the third period, we construct improved pseudopotentials for the Perdew Burke Ernzerhof (PBE)…

Fe$_{2}$VAl and Fe$_{2}$TiSn are full Heusler compounds with non-magnetic ground state. The two compouds are good thermoelectric materials. PBE and LDA(PW92) are the two most commonly used density functionals to study the Heusler compounds.…

Strongly Correlated Electrons · Physics 2017-08-04 Shivprasad S. Shastri , Sudhir K. Pandey

Theoretically, NaAuS is predicted as topological insulator, while no detail electronic structure study has been done for this compound. Here, we report the structural and electronic properties of NaAuS by using LDA, PBEsol, PBE and revPBE…

Strongly Correlated Electrons · Physics 2017-07-27 Antik Sihi , Sohan Lal , Sudhir K. Pandey

In our previous study [Phys. Rev. B 86, 201104 (2012)] we introduced the so called quasi-non-uniform gradient-level exchange-correlation approximation (QNA) and demonstrated it's strength in producing highly accurate equilibrium volumes for…

Materials Science · Physics 2015-06-18 H. Levämäki , L. Vitos , M. P. J. Punkkinen , K. Kokko

We present density functional theory calculations of the geometry, adsorption energy and electronic structure of thiophene adsorbed on Cu(111), Cu(110) and Cu(100) surfaces. Our calculations employ dispersion corrections and self-consistent…

Materials Science · Physics 2014-05-14 Zhi-Xin Hu , Haiping Lan , Wei Ji

The cohesive energy, equilibrium lattice constant, and bulk modulus of noble metals are computed by different van der Waals-corrected Density Functional Theory methods, including vdW-DF, vdW-DF2, vdW-DF-cx, rVV10 and PBE-D. Two…

Chemical Physics · Physics 2016-07-27 Alberto Ambrosetti , Pier Luigi Silvestrelli

The development of novel materials for vacuum electron sources in particle accelerators is an active field of research that can greatly benefit from the results of \textit{ab initio} calculations for the characterization of the electronic…

Materials Science · Physics 2021-06-01 Holger-Dietrich Saßnick , Caterina Cocchi

The electronic band structures of two-dimensional materials are significantly different from those of their bulk counterparts, due to quantum confinement and strong modifications of electronic screening. An accurate determination of…

Mesoscale and Nanoscale Physics · Physics 2020-07-08 Tomáš Rauch , Miguel A. L. Marques , Silvana Botti

Semilocal density functionals for the exchange-correlation energy are needed for large electronic systems. The Tao-Perdew-Staroverov-Scuseria (TPSS) meta-generalized gradient approximation (meta-GGA) is semilocal and usefully accurate, but…

Materials Science · Physics 2009-06-30 John P. Perdew , Adrienn Ruzsinszky , Gabor I. Csonka , Lucian A. Constantin , Jianwei Sun

It has been well established that nitrogen coordinated transition metal, TM-N$_{4}$-C (TM$=$Fe and Co) moieties, are responsible for the higher catalytic activity for the electrochemical oxygen reduction reaction. However, the results…

Materials Science · Physics 2022-09-20 Azim Fitri Zainul Abidin , Ikutaro Hamada

A study of the adsorption of CO on late 4d and $5d$ transition metal (111) surfaces (Ru, Rh, Pd, Ag, Os, Ir, and Pt) considering atop and hollow site adsorption is presented. The applied functionals include the gradient corrected PBE and…

Materials Science · Physics 2011-12-30 A. Stroppa , G. Kresse

Ab initio studies of structural, elastic and electronic properties of the tetragonal perovskite-type PbZr0.5Ti0.5O3 are presented using the pseudo-potential plane wave method within the density functional theory in generalized gradient…

Materials Science · Physics 2013-06-25 Renata Bujakiewicz-Koronska

We derive a generalized gradient approximation to the exchange energy to be used in density functional theory calculations of two-dimensional systems. This class of approximations has a long and successful history, but it has not yet been…

Strongly Correlated Electrons · Physics 2009-01-07 S. Pittalis , E. Rasanen , J. G. Vilhena , M. A. L. Marques

Exchange-correlation functionals with corrections for van der Waals interactions (PBE-D2, PBE-D3, PBE-D3(BJ), PBE-TS, optPBE-vdW and vdW-DF2) are tested for graphene and hexagonal boron nitride, both in the form of bulk and bilayer. The…

Mesoscale and Nanoscale Physics · Physics 2018-08-22 Irina V. Lebedeva , Alexander V. Lebedev , Andrey M. Popov , Andrey A. Knizhnik

We implement a Becke fuzzy cells type space partitioning scheme for the purposes of exchange-correlation within the GPAW projector augmented-wave method based density functional theory code. Space partitioning is needed in the situation…

Materials Science · Physics 2019-02-20 H. Levämäki , M. Kuisma , K. Kokko

Electronic structure descriptors are computationally efficient quantities used to construct qualitative correlations for a variety of properties. In particular, the oxygen p-band center has been used to guide material discovery and…

Materials Science · Physics 2019-02-18 Ryan Jacobs , Jonathan Hwang , Yang Shao-Horn , Dane Morgan

In order to assess the accuracy of commonly used approximate exchange-correlation density functionals, we present a comparison of accurate exchange and correlation potentials, exchange energy densities and energy components with the…

Condensed Matter · Physics 2007-05-23 Claudia Filippi , Xavier Gonze , C. J. Umrigar

The weighted density approximation, its implementation and its application to ferroelectric materials is discussed. Calculations are presented for several perovskite oxides and related materials. In general the weighted density…

Materials Science · Physics 2009-10-31 I. I. Mazin , D. J. Singh

The newly developed "strongly constrained and appropriately normed" (SCAN) meta-generalized-gradient approximation (meta-GGA) can generally improve over the non-empirical Perdew-Burke-Ernzerhof (PBE) GGA not only for strong chemical…

Materials Science · Physics 2016-10-19 Haowei Peng , Zeng-Hui Yang , Jianwei Sun , John P. Perdew