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The ground state structural, electronic and magnetic properties of multiferroic TbMn$_2$O$_5$ are investigated via first-principles calculations. We show that the ferroelectricity in TbMn$_2$O$_5$ is driven by the non-centrosymmetric…

Materials Science · Physics 2009-11-13 Chenjie Wang , Guang-Can Guo , Lixin He

The commensurate and incommensurate magnetic structures of the magnetoelectric system YMn$_{2}$O$_{5}$, as determined from neutron diffraction, were found to be spin-density waves lacking a global center of symmetry. We propose a model,…

Materials Science · Physics 2009-11-11 L. C. Chapon , P. G. Radaelli , G. R. Blake , S. Park , S-W. Cheong

In multiferroic TbMn$_2$O$_5$, the behavior of the terbium ions forms a crucial part of the magneto-electric coupling. The result is a magnetically induced reversal of the electric polarization at 2 T. In this article we present the first…

Strongly Correlated Electrons · Physics 2011-06-27 R. D. Johnson , C. Mazzoli , S. R. Bland , C-H. Du , P. D. Hatton

Magnetic and ferroelectric properties of layered geometrically frustrated cluster compound FeTe$_2$O$_5$Br were investigated with single-crystal neutron diffraction and dielectric measurements. Incommensurate amplitude modulated magnetic…

Materials Science · Physics 2009-10-01 M. Pregelj , O. Zaharko , A. Zorko , Z. Kutnjak , P. Jeglic , P. J. Brown , M. Jagodic , Z. Jaglicic , H. Berger , D. Arcon

Three independent contributions to the magnetically induced spontaneous polarization of multiferroic TbMn2O5 are uniquely separated by optical second harmonic generation and an analysis in terms of Landau theory. Two of them are related to…

Strongly Correlated Electrons · Physics 2012-03-07 N. Leo , D. Meier , R. V. Pisarev , N. Lee , S. -W. Cheong , M. Fiebig

We have carried out a first-principles theoretical study of the magnetically induced polarization in orthorhombic TbMnO3, a prototypical material in which a cycloidal spin structure generates an electric polarization via the spin-orbit…

Materials Science · Physics 2009-12-16 Andrei Malashevich , David Vanderbilt

We report the observation of a magnetic polarization of the O\,$2p$-states in YMn$_2$O$_5$ through the use of soft X-ray resonant scattering at the oxygen $K$-edge. Remarkably, we find that the temperature dependence of the integrated…

Strongly Correlated Electrons · Physics 2015-03-19 S. Partzsch , S. B. Wilkins , J. P. Hill , E. Schierle , E. Weschke , D. Souptel , B. Büchner , J. Geck

We report a neutron diffraction study of the multiferroic mechanism in (ND4)2FeCl5D2O, a molecular compound that exhibits magnetically induced ferroelectricity. This material exhibits two successive magnetic transitions on cooling: a…

Using first principle calculations under the framework of density functional theory we have investigated the electronic structure, magnetism and ferroelectric polarization in the triangular lattice antiferromagnet AgFeO2, and its comparison…

Materials Science · Physics 2018-01-03 Jayita Chakraborty , Indra Dasgupta

There has been tremendous research activity in the field of magneto-electric (ME) multiferroics after Kimura et al. [1] showed that antiferromagnetic and ferroelectric order coexist in orthorhom- bically distorted perovskite TbMnO3 and are…

By combining neutron four-circle diffraction and polarized neutron diffraction techniques we have determined the complex spin structures of a multiferroic, YMn2O5, that exhibits two ferroelectric phases at low temperatures. The obtained…

Type-II multiferroics, in which the magnetic order breaks inversion symmetry, are appealing for both fundamental and applied research due their intrinsic coupling between magnetic and electrical orders. Using first-principles calculations…

Materials Science · Physics 2023-11-20 Urmimala Dey , Mark S. Senn , Nicholas C. Bristowe

The ground-state structural and electronic properties of ferroelectric BiFeO$_3$ are calculated using density functional theory within the local spin-density approximation and the LSDA+U method. The crystal structure is computed to be…

Materials Science · Physics 2007-05-23 J. B. Neaton , C. Ederer , U. V. Waghmare , N. A. Spaldin , K. M. Rabe

Comparative studies of magnetoelectric susceptibility ($\alpha$), magnetization ($M$), and magnetostriction ($u$) in TbMn$_{2}$O$_{5}$ reveal that the increment of $M$ owing to the field-induced Tb$^{3+}$ spin alignment coins a…

Strongly Correlated Electrons · Physics 2015-03-17 Yoon Seok Oh , Byung-Gu Jeon , S. Y. Haam , S. Park , V. F. Correa , A. H. Lacerda , S. -W. Cheong , Gun Sang Jeon , Kee Hoon Kim

We present a theoretical study of the structure-property correlation in gallium ferrite, based on the first principles calculations followed by a subsequent comparison with the experiments. Local spin density approximation (LSDA+U) of the…

Materials Science · Physics 2011-07-27 Amritendu Roy , Somdutta Mukherjee , Rajeev Gupta , Rajendra Prasad , Sushil Auluck , Ashish Garg

We uncover a new pathway towards multiferroicity, showing how magnetism can drive ferroelectricity without relying on inversion symmetry breaking of the magnetic ordering. Our free-energy analysis demonstrates that any commensurate…

Materials Science · Physics 2009-11-11 Joseph J. Betouras , Gianluca Giovannetti , Jeroen van den Brink

The electric polarization and its magnetic origins in multiferroic RMn2O5, where R is rare-earth ion, are still issues under debate. In this work, the temperature-dependent electric polarization of DyMn2O5, the most attractive member of…

Materials Science · Physics 2014-02-06 Z. Y. Zhao , M. F. Liu , X. Li , L. Lin , Z. B. Yan , S. Dong , J. -M. Liu

We report the discovery of linear magnetoelectric effect in the well-known green phase compound, Sm2BaCuO5, which crystallizes in the centrosymmetric orthorhombic (Pnma) structure. Magnetization and specific heat measurements reveal the…

Strongly Correlated Electrons · Physics 2019-10-02 Premakumar Yanda , N. V. Ter-Oganessian , A. Sundaresan

First-principles electronic structure calculations have been performed for the double perovskite Bi$_2$CoMnO$_6$ in its non-centrosymmetric polar state using generalized gradient approximation plus Hubbard U approach. We find that while Co…

Materials Science · Physics 2010-10-25 Satadeep Bhattacharjee , Olle Eriksson , Biplab Sanyal

In this paper, we investigate the physical properties of the type II multiferroic GdMn$_2$O$_5$ material by means of neutrons scattering, electric polarization and magnetization measurements. A complex $(T,H)$ phase diagram shows up, with…

Strongly Correlated Electrons · Physics 2023-07-13 Balédent V , Vaunat A. , Petit S. , L. Nataf , Chattopadhyay S. , Raymond S. , Foury-Leylekian P
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