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The mid-infrared heating of interfacial water with different initial temperatures is studied using non-equilibrium molecular dynamics simulation. It is found that under the irradiation of a pulse at 3360-3380 $cm^{-1}$ the two-dimensional…

Soft Condensed Matter · Physics 2022-07-19 Liu-Ye Meng , Rong-Yao Yang , Wei-Zhou Jiang

We develop a new variant of the wave-packet analysis and solve the tunneling time problem for one particle. Our approach suggests an individual asymptotic description of the quantum subensembles of transmitted and reflected particles both…

Quantum Physics · Physics 2007-05-23 N. L. Chuprikov

We analyze the formation of Rb_2 molecules with short photoassociation pulses applied to a cold Rb-85 sample. A pump laser pulse couples a continuum level of the ground electronic state X ^1\Sigma_{g}^+ with bound levels in the 0_{u}^+…

Atomic Physics · Physics 2007-06-22 Jordi Mur-Petit , Eliane Luc-Koenig , Françoise Masnou-Seeuws

We investigate molecular dynamics of multiple ionization in N2 through multiple core-level photoabsorption and subsequent Auger decay processes induced by intense, short X-ray free electron laser pulses. The timing dynamics of the…

Resonant Raman excitation by ultrafast vacuum ultraviolet laser pulses is a powerful means to study electron dynamics in molecules, but experiments must contend with linear background ionization: frequencies high enough to reach resonant…

Chemical Physics · Physics 2015-06-23 S. Miyabe , P. Bucksbaum

In a previous publication, procedures were proposed for unambiguously extracting amplitudes for single and double ionization from a time-dependent wavepacket by effectively propagating for an infinite time following a radiation pulse. Here…

Atomic Physics · Physics 2009-11-13 A. Palacios , T. N. Rescigno , C. W. McCurdy

Coherently displaced harmonic oscillator number states of a harmonically bound ion can be coupled to two internal states of the ion by a laser-induced motional sideband interaction. The internal states can subsequently be read out in a…

Phase transitions driven by ultrashort laser pulses have attracted interest both for understanding the fundamental physics of phase transitions and for potential new data storage or device applications. In many cases these transitions…

Warm dense matter systems created in the laboratory are highly dynamical. In such cases electron dynamics is often needed to accurately simulate the evolution and properties of the system. Large systems force one to make simple…

Quantum Gases · Physics 2014-08-13 Paul E. Grabowski

Molecular vibrations underpin important phenomena such as spectral properties, energy transfer, and molecular bonding. However, obtaining a detailed understanding of the vibrational structure of even small molecules is computationally…

Quantum Physics · Physics 2020-01-24 Sam McArdle , Alex Mayorov , Xiao Shan , Simon Benjamin , Xiao Yuan

Localized quantum wave packets can be produced in a variety of physical systems and are the subject of much current research in atomic, molecular, chemical, and condensed-matter physics. They are particularly well suited for studying the…

Quantum Physics · Physics 2009-09-25 Robert Bluhm , Alan Kostelecky , James Porter

The thermalization of an isolated quantum system is described by quantum mechanics and thermodynamics, while these two subjects are still not fully consistent with each other. This leaves a less-explored region where both quantum and…

Quantum Gases · Physics 2024-11-22 Yuqing Wang , Libo Liang , Qinpei Zheng , Qi Huang , Wenlan Chen , Jing Zhang , Xuzong Chen , Jiazhong Hu

The vibrational wave-packet dynamics of diatomic rubidium molecules (Rb2) in triplet states formed on the surface of superfluid helium nanodroplets is investigated both experimentally and theoretically. Detailed comparison of experimental…

Atomic and Molecular Clusters · Physics 2017-09-13 Barbara Grüner , Martin Schlesinger , Philipp Heister , Walter T. Strunz , Frank Stienkemeier , Marcel Mudrich

In order to use a collection of trapped ions for experiments where a well defined preparation of vibrational states is necessary, all vibrational modes have to be cooled to ensure precise and repeatable manipulation of the ions' quantum…

Atomic Physics · Physics 2009-11-11 Christof Wunderlich , Giovanna Morigi , Dirk Reiss

We investigate the dynamics of a rotating Morse wave packet, appropriate for a ro-vibrating diatomic molecule. The coupling between vibrational and rotational degrees of freedom is explicated in real position space as well as in phase space…

Quantum Physics · Physics 2009-07-20 Utpal Roy , Suranjana Ghosh

The amplitude and probability of quantum transitions are represented as a path integrals in energy state space of the investigated multi-level quantum system. Using this approach we consider rotational dynamics of nitrogen molecules…

Quantum Physics · Physics 2014-07-16 Alexander Biryukov , Mark Shleenkov

We explore the laser-induced ionization dynamics of N2 and CO2 molecules subjected to a few-cycle, linearly polarized, 800\,nm laser pulse using effective two-dimensional single active electron time-dependent quantum simulations. We show…

Atomic Physics · Physics 2012-10-02 Michel Peters , Tung Nguyen-Dang , Eric Charron , Arne Keller , Osman Atabek

Vibrational-excitation cross sections of ground electronic state of carbon dioxide molecule by electron-impact through the CO2-(2\Pi) shape resonance is considered in the separation of the normal modes approximation. Resonance curves and…

Chemical Physics · Physics 2016-11-01 V. Laporta , J. Tennyson , R. Celiberto

A quantum-mechanical Gaussian wave-packet approach to the theoretical description of nuclear motions in a condensed-phase environment is developed. General expressions for the time-dependent reduced density matrix are given for a harmonic…

Chemical Physics · Physics 2009-10-31 L. Muhlbacher , A. Lucke , R. Egger

The relationship between a decaying strong turbulence and kinetic instabilities in a slowly expanding plasma is investigated using two-dimensional (2-D) hybrid expanding box simulations. We impose an initial ambient magnetic field…