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Related papers: Isolated vibrational wavepackets in D2+: Defining …

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A coherent superposition of rotational states in D$_2$ has been excited by nonresonant ultrafast (12 femtosecond) intense (2 $\times$ 10$^{14}$ Wcm$^{-2}$) 800 nm laser pulses leading to impulsive dynamic alignment. Field-free evolution of…

Understanding and controlling the electronic as well as ro-vibrational motion and, thus, the entire chemical dynamics in molecules is the ultimate goal of ultrafast laser and imaging science. In photochemistry, laser-induced dissociation…

A new simulation box setup is introduced for the precise description of the wavepacket evolution of two electronic systems in intense laser pulses. In this box, the regions of the hydrogen molecule H$_{2} $, and singly and doubly ionized…

Atomic Physics · Physics 2016-03-03 Mohsen Vafaee , Firoozeh Sami , Babak Shokri , Behnaz Buzari , Hassan Sabzyan

We investigate theoretically the dissociative ionization of a H2+ molecule using two ultrashort laser (pump-probe) pulses. The pump pulse prepares a dissociating nuclear wave packet on an ungerade surface of H2+. Next, an UV (or XUV) probe…

Quantum Physics · Physics 2013-05-29 Szczepan Chelkowski , André D. Bandrauk

Observing the motion of the nuclear wavepackets during a molecular reaction, in both space and time, is crucial for understanding and controlling the outcome of photoinduced chemical reactions. We have imaged the motion of a vibrational…

The coherent interaction with ultrashort light pulses is a powerful strategy for monitoring and controlling the dynamics of wave packets in all states of matter. As light presents an oscillation period of a few femtoseconds ($T=2.6$~fs in…

We show how to emulate a conventional pump-probe scheme using a single frequency-chirped ultrashort UV pulse to obtain a time-resolved image of molecular ultrafast dynamics. The chirp introduces a spectral phase in time that encodes the…

Chemical Physics · Physics 2017-05-03 Denis Jelovina , Johannes Feist , Fernando Martín , Alicia Palacios

We report on generation of a rotational wavepacket in the ground vibronic state (v = 0) of excited electronic B2{\Sigma}u+ state of N2+ in a femtosecond laser induced plasma spark. Decoding of the rotational wavepacket is achieved with the…

Some of us have recently reported in Science 321 232 (2008) vibrational cooling of translationally cold Cs_2 molecules into the lowest vibrational level v=0 of the singlet X 1Sigma_g ground electronic state. Starting from a sample of cold…

We propose a general technique to retrieve the information of dipole-forbidden resonances in the autoionizing region. In the simulation, a helium atom is pumped by an isolated attosecond pulse in the extreme ultraviolet (EUV) combined with…

Atomic Physics · Physics 2014-03-28 Wei-Chun Chu , Toru Morishita , C. D. Lin

We propose a simple way to determine the periodicities of wave packets in quantum systems directly from the energy differences of the states involved. The resulting classical periods and revival times are more accurate than those obtained…

Atomic Physics · Physics 2011-09-27 Paula Riviere , Shahid Iqbal , Jan M Rost

D$_2$ molecules, excited by linearly cross-polarized femtosecond extreme ultraviolet (XUV) and near-infrared (NIR) light pulses, reveal highly structured D$^+$ ion fragment momenta and angular distributions that originate from two different…

The dissociation spectrum of the hydrogen molecular ion by short intense pulses of infrared light is calculated. The time-dependent Schr\"odinger equation is discretized and integrated in position and momentum space. For few-cycle pulses…

Atomic Physics · Physics 2009-11-10 Liang-You Peng , I D Williams , J F McCann

We show the details of the pathway for dissociative ionization process of ground electronic state of aligned D$^{+}_{2}$ due to first ionization of D$_2$ in short ($\thicksim$100 fs) and intense ($4.0\times10^{14}$ W cm$^{-2}$) 480 nm laser…

Atomic Physics · Physics 2010-11-23 Mohsen Vafaee , Babak Shokri

We propose a method to investigate the vibrational dynamics of single polyatomic molecular ions confined in a Paul trap. Quantum logic techniques are employed to detect the recoil of single photon absorption events in the molecule via a…

Quantum Physics · Physics 2019-08-27 Philipp Schindler

Irradiation of isolated water molecules by few-cycle pulses of intense infrared laser light can give rise to ultrafast rearrangement resulting in formation of the H2+ ion. Such unimolecular reactions occur on the potential energy surface of…

Chemical Physics · Physics 2015-06-03 Manish Garg , Ashwani K. Tiwari , Deepak Mathur

In this work we report ab initio calculations for the $H_2^+$ molecule interacting with ultrashort intense laser pulses. We analyse several observables that can, in principle, be available experimentally, in order to get a deeper…

Atomic Physics · Physics 2017-05-25 R. E. F. Silva

We studied the recollision dynamics between the electrons and D$_2^+$ ions following the tunneling ionization of D$_2$ molecules in an intense short pulse laser field. The returning electron collisionally excites the D$_2^+$ ion to excited…

Atomic Physics · Physics 2009-11-10 X. M. Tong , Z. X. Zhao , C. D. Lin

We investigate the propagation of ultra-short laser pulses in atomic rubidium vapor. The pulses are intensive enough to ionize the atoms and are directly resonant with the 780 nm $D_2$ line. We derive a relatively simple theory for…

Optics · Physics 2019-07-03 Gabor Demeter

The ultrafast electronic and nuclear dynamics of H2 laser-induced double ionization is studied using a time-dependent wave packet approach that goes beyond the fixed nuclei approximation. The double ionization pathways are analyzed by…

Quantum Physics · Physics 2011-11-09 Sebastien Saugout , Christian Cornaggia , Annick Suzor-Weiner , Eric Charron
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