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Circular dichroism (CD) induced by spin angular momentum of light is vital to investigate the chirality of microscopic objects such as molecules, proteins and metamaterials. However, orbital angular momentum (OAM) of light failed to…

Spectroscopic techniques that are sensitive to molecular chirality are important analytical tools to quantitatively determine enantiomeric excess and purity of chiral molecular samples. Many chiroptical processes however produce weak…

Chemical Physics · Physics 2026-04-02 Sebastian Hartweg , Dusan k. Bozanic , Gustavo A. Garcia-Macias , Laurent Nahon

Molecular Circular dichroism (CD) spectroscopy faces significant limitations due to the inherent weakness of chiroptical light-matter interactions. In this view, resonant optical antennas constitute a promising solution to this problem…

Circular Dichroism (CD) can distinguish the handedness of chiral molecules. However, it is typically very weak due to vanishing absorption at low molecular concentrations. Here, we suggest Thermal Circular Dichroism (TCD) for chiral…

Optics · Physics 2024-07-19 Ershad Mohammadi , Giulia Tagliabue

Molecular chirality detection and enantiomer discrimination are very important issues for many areas of science and technology, prompting intensive investigations via optical methods. However, these methods are hindered by the intrinsically…

We derive here a new highly selective photoelectron-based chirality-sensing technique that utilizes 'locally-chiral' laser pulses. We show that this approach results in strong chiral discrimination, where the standard forwards/backwards…

Chemical Physics · Physics 2021-07-14 Ofer Neufeld , Hannes Hübener , Angel Rubio , Umberto De Giovannini

Polarization-dependent photon spectroscopy (dichroism) using signal-enhancing superchiral beams is shown to be sensitive to magnetic properties of the sample, whereas previous investigations explored charge-like electronic properties of…

Materials Science · Physics 2019-03-06 S. W. Lovesey , J. T. Collins , S. P. Collins

Circular dichroism (CD) spectroscopy is a useful technique for characterizing chiral molecules. It is more sensitive than total absorption to molecule conformation, and it is routinely used to identify enantiomers. We present here…

Chemical Physics · Physics 2023-11-21 Elena Molteni , Giuseppe Mattioli , Davide Sangalli

Circular dichroism (CD) caused by the response of a chiral object to circularly polarized light has been well established, and the strong CD of plasmonic meta-molecules has also become of interest in recent years; however, their response if…

Optics · Physics 2020-09-30 Yangzhe Guo , Guodong Zhu , Wanlu Bian , Bin Dong , Yurui Fang

We theoretically and numerically investigate the capability of disordered media to enhance the optical path length in dielectric slabs and augment their light absorption efficiency due to scattering. We first perform a series of Monte Carlo…

The difference in the transmission for left and right circularly polarised light though thin films on substrates in a magnetic field is used to obtain the magnetic circular dichroism of the film. However there are reflections at all the…

Materials Science · Physics 2015-05-14 Wala Dizayee , Minju Ying , A. Mark Fox , Gillian A. Gehring

Energy-loss magnetic chiral dichroism (EMCD) is a versatile method for studying magnetic properties on the nanoscale. However, the classical EMCD technique is notorious for its low signal to noise ratio (SNR). Here, we study the theoretical…

Instrumentation and Detectors · Physics 2019-03-12 Stefan Löffler , Walid Hetaba

We describe a new experimental setup for the detection of magnetic circular dichroism with fast electrons (EMCD). As compared to earlier findings the signal is an order of magnitude higher, while the probed area could be significantly…

Chiral crystals show promise for spintronic technologies on account of their high spin selectivity, which has led to significant recent interest in quantitative characterization and first-principles prediction of their spin-optoelectronics…

Materials Science · Physics 2023-12-05 Christian Multunas , Andrew Grieder , Junqing Xu , Yuan Ping , Ravishankar Sundararaman

A light beam can carry both spin angular momentum (SAM) and orbital angular momentum (OAM). SAM is commonly evidenced by circular dichroism (CD) experiments {\em i. e.} differential absorption of left and right-handed circularly polarized…

The concentration of a chiral solution is a key parameter in many scientific fields and industrial processes. This parameter can be estimated to high precision by exploiting circular birefringence or circular dichroism present in optically…

Quantum Physics · Physics 2022-11-08 Alexandre Belsley , Jonathan C. F. Matthews

Circular dichroism (CD) of photoemission from a surface state on Bi(111) is considered within an {\it ab initio} one-step theory of photoemission. The symmetry of the azimuthal distribution of CD for different spin directions is discussed…

Materials Science · Physics 2024-08-26 E. E. Krasovskii

We derive a set of design requirements that lead to structures suitable for molecular circular dichroism (CD) enhancement. Achirality of the structure and two suitably selected sequentially incident beams of opposite helicity ensures that…

Circular dichroism in the angular distribution (CDAD) is the effect that the angular intensity distribution of photoemitted electrons depends on the handedness of the incident circularly polarized light. A CDAD may arise from intrinsic…