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Thermodynamic fluctuation theory originated with Einstein who inverted the relation $S=k_B\ln\Omega$ to express the number of states in terms of entropy: $\Omega= \exp(S/k_B)$. The theory's Gaussian approximation is discussed in most…

Statistical Mechanics · Physics 2015-05-19 George Ruppeiner

In 1928, Chapman generalised Einstein's theory of diffusion for non-uniform fluids to show the presence of a non-Fickian diffusion current, which he considered important in thermodiffusion (Ludwig-Soret effect). In 1941, Kiyosi It\^o…

Soft Condensed Matter · Physics 2026-03-25 Mayank Sharma , Angad Singh , A. Bhattacharyay

The meaning of thermodynamic descriptions is found in large-deviations scaling of the fluctuations probabilities. The primary large-deviations rate function is the entropy, which is the basis for both fluctuation theorems and for…

Statistical Mechanics · Physics 2015-05-27 Eric Smith

In this paper, we derive a generalized second fluctuation-dissipation theorem (FDT) for stochastic dynamical systems in the steady state. The established theory is built upon the Mori-type generalized Langevin equation for stochastic…

Statistical Mechanics · Physics 2021-06-15 Yuanran Zhu , Huan Lei , Changho Kim

The reformulation of nonequilibirum thermodynamics, to include the treatment of thermodynamic fluctuations, is applied to the hydrodynamic fluctuations of a simple fluid. It is shown that the nonequilibrium thermodynamic scheme leads to the…

Statistical Mechanics · Physics 2007-05-23 J. M. Rubi , P. Mazur

A new effective theory framework for fluctuating hydrodynamics in the relativistic regime is derived using standard thermodynamical principles and general properties of non-equilibrium stochastic dynamics. For the first time, we establish…

Nuclear Theory · Physics 2025-01-09 Nicki Mullins , Mauricio Hippert , Jorge Noronha

We consider fluctuations of the dissipated energy in nonlinear driven diffusive systems subject to bulk dissipation and boundary driving. With this aim, we extend the recently-introduced macroscopic fluctuation theory to nonlinear driven…

Statistical Mechanics · Physics 2013-10-29 P. I. Hurtado , A. Lasanta , A. Prados

Exact theoretical results for the violation of time dependent fluctuation-dissipation relations in driven dissipative systems are presented. The ratio of correlation to delayed response in the stochastic model introduced in [Phys. Rev.…

Statistical Mechanics · Physics 2007-05-23 Yair Shokef , Guy Bunin , Dov Levine

Fluctuation Theorems are statements about the entropy of systems far from thermal equilibrium. In this Letter relativistic Fluctuation Theorems for Brownian motion are presented and proven. Though there is a known discretization dilemma…

Statistical Mechanics · Physics 2007-05-23 Axel Fingerle

The Fluctuation Theorems are a group of exact relations that remain valid irrespective of how far the system has been driven away from equilibrium. Other than having practical applications, like determination of equilibrium free energy…

Statistical Mechanics · Physics 2016-11-04 Sourabh Lahiri , A. M. Jayannavar

Large entropy fluctuations in a nonequilibrium steady state of classical mechanics were studied in extensive numerical experiments on a simple 2-freedom model with the so-called Gauss time-reversible thermostat. The local fluctuations (on a…

Chaotic Dynamics · Physics 2009-10-31 Boris Chirikov

For equilibrium systems, the magnitude of thermal fluctuations is closely linked to the dissipative response to external perturbations. This fluctuation-dissipation relation has been described for material particles in a wide range of…

Quantum Gases · Physics 2023-01-24 Fahri Emre Öztürk , Frank Vewinger , Martin Weitz , Julian Schmitt

We illustrate recent results concerning the validity of the work fluctuation theorem in open quantum systems [M. Campisi, P. Talkner, and P. H\"{a}nggi, Phys. Rev. Lett. {\bf 102}, 210401 (2009)], by applying them to a solvable model of an…

Statistical Mechanics · Physics 2009-09-14 Michele Campisi , Peter Talkner , Peter Hänggi

The authors in a previous paper proved the hydrodynamic incompressible limit in $d\ge 3$ for a thermal lattice gas, namely a law of large numbers for the density, velocity field and energy. In this paper the equilibrium fluctuations for…

Mathematical Physics · Physics 2007-05-23 O. Benois , R. Esposito , R. Marra

Heat fluctuations over a time \tau in a non-equilibrium stationary state and in a transient state are studied for a simple system with deterministic and stochastic components: a Brownian particle dragged through a fluid by a harmonic…

Statistical Mechanics · Physics 2007-05-23 R. van Zon , E. G. D. Cohen

A stopping time $T$ is the first time when a trajectory of a stochastic process satisfies a specific criterion. In this paper, we use martingale theory to derive the integral fluctuation relation $\langle e^{-S_{\rm tot}(T)}\rangle=1$ for…

Statistical Mechanics · Physics 2019-10-22 Izaak Neri , Edgar Roldán , Simone Pigolotti , Frank Jülicher

We propose new ideal hydrodynamics in the function space which describes a fluid composed of the 1+1 dimensional real scalar field in the framework of the stochastic variational method (SVM). In the derivation, the thermal equilibrium is…

Nuclear Theory · Physics 2023-03-23 T. Koide , T. Kodama

Recently there has been considerable interest in the Fluctuation Theorem (FT). The FT shows how time reversible microscopic dynamics leads to irreversible macroscopic behavior as the system size or observation time increases. We show that…

Statistical Mechanics · Physics 2008-02-18 Denis J. Evans , Debra J. Searles

Active biological systems reside far from equilibrium, dissipating heat even in their steady state, thus requiring an extension of conventional equilibrium thermodynamics and statistical mechanics. In this Letter, we have extended the…

Soft Condensed Matter · Physics 2017-12-22 Dibyendu Mandal , Katherine Klymko , Michael R. DeWeese

The second law of thermodynamics posits that in closed macroscopic systems the rate of entropy production must be positive. However, small systems can exhibit negative entropy production over short timescales, seemingly in contradiction…

Quantum Gases · Physics 2023-08-08 Rama Sharma , Tapio P. Simula , Andrew J. Groszek