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The dynamics of flexible polymers in dilute solutions is studied taking into account the hydrodynamic memory, as a consequence of fluid inertia. As distinct from the Rouse-Zimm (RZ) theory, the Boussinesq friction force acts on the monomers…

Soft Condensed Matter · Physics 2009-11-10 V. Lisy , J. Tothova , A. V. Zatovsky

The presence of a viscoelastic mechanism distinctly different from the segmental a-relaxation and the Rouse modes within the glass-rubber transition zone of polymers had been justified by theoretical considerations, and subsequently…

Soft Condensed Matter · Physics 2014-10-20 K. L. Ngai , S. Capaccioli , Daniele Prevosto , Luigi Grassia

Both linear and nonlinear Langevin equations are derived directly from the Liouville equation for an exactly solvable model consisting of a Brownian particle of mass $M$ interacting with ideal gas molecules of mass $m$ via a quadratic…

Statistical Mechanics · Physics 2009-11-10 Alexander V. Plyukhin , Jeremy Schofield

Intrachain contact formation rates, fundamental to the dynamics of biopolymer self-organization such as protein folding, can be monitored in the laboratory through fluorescence quenching measurements. The common approximations for the…

Condensed Matter · Physics 2009-11-07 John J. Portman

Recent theoretical modeling offers a unified picture for the description of stochastic processes characterized by a crossover from anomalous to normal behavior. This is particularly welcome, as a growing number of experiments suggest the…

Statistical Mechanics · Physics 2019-07-16 Fulvio Baldovin , Enzo Orlandini , Flavio Seno

Presenting theoretical arguments and numerical results we demonstrate long-range intrachain correlations in concentrated solutions and melts of long flexible polymers which cause a systematic swelling of short chain segments. They can be…

Soft Condensed Matter · Physics 2009-11-13 J. P. Wittmer , P. Beckrich , H. Meyer , A. Cavallo , A. Johner , J. Baschnagel

We investigate conformations and dynamics of a polymer considering its monomers to be active Brownian particles. This active polymer shows very intriguing physical behavior which is absent in an active Rouse chain. The chain initially…

Soft Condensed Matter · Physics 2020-04-13 Shalabh K. Anand , Sunil P. Singh

Using extensive computer simulations, the behavior of the structural modes --- more precisely, the eigenmodes of a phantom Rouse polymer --- are characterized for a polymer in the three-dimensional repton model, and are used to study the…

Soft Condensed Matter · Physics 2015-03-18 Gerard T. Barkema , Debabrata Panja , J. M. J. van Leeuwen

In this paper we establish a new efficient method for simulating polymer-solvent systems which combines a lattice Boltzmann approach for the fluid with a continuum molecular dynamics (MD) model for the polymer chain. The two parts are…

Soft Condensed Matter · Physics 2009-10-31 Patrick Ahlrichs , Burkhard Duenweg

We present a model for semiflexible polymers in Hamiltonian formulation which interpolates between a Rouse chain and worm-like chain. Both models are realized as limits for the parameters. The model parameters can also be chosen to match…

Soft Condensed Matter · Physics 2015-06-12 Gerard T. Barkema , J. M. J. van Leeuwen

We present the reduced dynamics of a bead in a Rouse chain which is submerged in a bath containing a driving agent that renders it out-of-equilibrium. We first review the generalized Langevin equation of the middle bead in an equilibrated…

Statistical Mechanics · Physics 2017-03-08 Hans Vandebroek , Carlo Vanderzande

The purpose of this paper is to investigate several analytical methods of solving first passage (FP) problem for the Rouse model, a simplest model of a polymer chain. We show that this problem has to be treated as a multi-dimensional…

Soft Condensed Matter · Physics 2015-12-09 Jing Cao , Jian Zhu , Zuowei Wang , Alexei E. Likhtman

Many researchers have been encouraged to describe the dynamics of chromosomal loci in chromatin using the classical Rouse model of polymer dynamics by the agreement between the measured mean square displacement (MSD) versus time of…

Recent experiments using fluorescence spectroscopy have been able to probe the dynamics of conformational fluctuations in proteins. The fluctuations are Gaussian but do not decay exponentially, and are therefore, non-Markovian. We present a…

Statistical Mechanics · Physics 2008-10-14 Arti Dua , R. Adhikari

We present a semi-analytical approach to the determination of the dynamic properties of randomly branched polymers under the Rouse approximation. The principle procedure is based on examining a spectrum of eigenvalues which represents the…

Statistical Mechanics · Physics 2009-10-31 Josh P. Kemp , Zheng Yu Chen

We present data of Monte Carlo simulations for monodisperse linear polymer chains in dense melts with degrees of polymerization between N=16 and N=512. The aim of this study is to investigate the crossover from Rouse-like dynamics for short…

Soft Condensed Matter · Physics 2009-10-31 T. Kreer , J. Baschnagel , M. Mueller , K. Binder

Brownian motion occurs in a variety of fluids, from rare gases to liquids. The Langevin equation, describing friction and agitation forces in statistical balance, is one of the most successful ways to treat the phenomenon. In rare gases, it…

Statistical Mechanics · Physics 2020-06-15 Frank Munley

We investigated the static and dynamic properties of a Rouse ring polymer modified by introducing an effective, spherically symmetric, attractive potential of entropic nature and a memory function describing the effect of dynamic…

Soft Condensed Matter · Physics 2026-05-27 Nail Fatkullin , Carlos Mattea , Kevin Lindt , Siegfried Stapf , Margarita Kruteva

We study analytically the tracer particle mobility in single-file systems with distributed friction constants. Our system serves as a prototype for non-equilibrium, heterogeneous, strongly interacting Brownian systems. The long time…

Statistical Mechanics · Physics 2015-06-18 Michael A. Lomholt , Tobias Ambjornsson

In molecular dynamics simulations and single molecule experiments, observables are usually measured along dynamic trajectories and then averaged over an ensemble ("bundle") of trajectories. Under stationary conditions, the time-evolution of…

Statistical Mechanics · Physics 2018-01-17 Hugues Meyer , Thomas Voigtmann , Tanja Schilling