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Monte Carlo methods are used to study the phase transition in ammonium chloride from the orientationally ordered $\delta$ phase to the orientationally disordered $\gamma$ phase. An effective pair potential is used to model the interaction…

chem-ph · Physics 2008-02-03 Robert Q. Topper , David L. Freeman

We use an auxiliary-field Monte Carlo (AFMC) method to calculate thermodynamic properties (spin susceptibility and heat capacity) of ultra-small metallic grains in the presence of pairing correlations. This method allows us to study the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Y. Alhassid , L. Fang , S. Schmidt

We study model protein solutions and colloidal suspensions in the temperature range whereupon the nature of the system changes from a homogeneous fluid to a "cluster fluid". It is commonly assumed - as deduced by the behavior of the…

Statistical Mechanics · Physics 2011-09-02 Jean-Marc Bomont , Jean-Louis Bretonnet , Dino Costa

A generalization of the microcanonical ensemble suggests a simple strategy for the simulation of first order phase transitions. At variance with flat-histogram methods, there is no iterative parameters optimization, nor long waits for…

Statistical Mechanics · Physics 2008-11-26 V. Martin-Mayor

A phase diagram is a graph in parameter space showing the phase boundaries of a many-particle system. Commonly, the control parameters are chosen to be those of the (generalized) canonical ensemble, such as temperature and magnetic field.…

Statistical Mechanics · Physics 2009-06-22 Michael Kastner , Michel Pleimling

The present study regards the zeroth order mean field approximation of a dipole-type interaction model, which is analytically solved in the canonical and microcanonical ensembles. After writing the canonical partition function, the free and…

Statistical Mechanics · Physics 2018-03-16 Atenas Boris , Curilef Sergio

We combine spin polarised density functional theory and thermodynamic mean field theory to describe the phase transitions of antiperovskite manganese nitrides. We find that the inclusion of the localized spin contribution to the entropy,…

Materials Science · Physics 2016-10-25 Marco Piazzi , Jan Zemen , Vittorio Basso

We have performed parallel tempering Monte Carlo simulations using a simple continuum heteropolymer model for proteins. All ten heteropolymer sequences which we have studied have shown first-order transitions at low temperature to ordered…

Soft Condensed Matter · Physics 2010-01-05 J. E. Magee , J. Warwicker , L. Lue

We present a Monte Carlo study of the finite temperature properties of an extended Hubbard-Peierls model describing one dimensional $\pi$-conjugated polymers. The model incorporates electron-phonon and hyperfine interaction and it is solved…

Mesoscale and Nanoscale Physics · Physics 2010-12-17 S. Bhattacharya , M. S. Ferreira , S. Sanvito

The problem of the existence of a Strong Stochasticity Threshold in the FPU-beta model is reconsidered, using suitable microcanonical observables of thermodynamic nature, like the temperature and the specific heat. Explicit expressions for…

chao-dyn · Physics 2008-02-03 C. Giardina' , R. Livi

New experiments for water at the surface of proteins at very low temperature display intriguing dynamic behaviors. The extreme conditions of these experiments make it difficult to explore the wide range of thermodynamic state points needed…

Discontinuous percolation transitions and the associated tricritical points are manifest in a wide range of both equilibrium and non-equilibrium cooperative phenomena. To demonstrate this, we present and relate the continuous and first…

Disordered Systems and Neural Networks · Physics 2013-05-30 Golnoosh Bizhani , Maya Paczuski , Peter Grassberger

The results of a detailed histogram Monte-Carlo study of critical-fluctuation effects on the magnetic-field temperature phase diagram associated with the hexagonal Heisenberg antiferromagnet with weak axial anisotropy are reported. The…

Condensed Matter · Physics 2009-10-22 A. Mailhot , M. L. Plumer , A. Caillé

A statistical method is derived for the calculation of thermodynamic properties of many-body systems at low temperatures. This method is based on the self-healing diffusion Monte Carlo method for complex functions [F. A. Reboredo J. Chem.…

Other Condensed Matter · Physics 2014-03-05 Fernando A. Reboredo , Jeongnim Kim

We present a geometric and dynamical approach to the micro-canonical ensemble of classical Hamiltonian systems. We generalize the arguments in \cite{Rugh} and show that the energy-derivative of a micro-canonical average is itself…

chao-dyn · Physics 2009-10-30 Hans Henrik Rugh

We study the thermodynamics of the Hamiltonian Mean Field (HMF) model with an external potential playing the role of a "magnetic field". If we consider only fully stable states, this system does not present any phase transition. However, if…

Statistical Mechanics · Physics 2015-05-20 Pierre-Henri Chavanis

We present a new method for investigating first-order phase transitions using Monte Carlo simulations. It relies on the multiple-histogram method and uses solely histograms of individual phases. In addition, we extend the method to include…

adap-org · Physics 2009-10-28 Martin Ebeling , Walter Nadler

The notion of negative absolute temperature emerges naturally from Boltzmann's definition of "surface" microcanonical entropy in isolated systems with a bounded energy density. Recently, the well-posedness of such construct has been…

Statistical Mechanics · Physics 2017-05-31 Pierfrancesco Buonsante , Roberto Franzosi , Augusto Smerzi

We show that systems with negative specific heat can violate the zeroth law of thermodynamics. By both numerical simulations and by using exact expressions for free energy and microcanonical entropy it is shown that if two systems with the…

Statistical Mechanics · Physics 2009-11-13 A. Ramirez-Hernandez , H. Larralde , F. Leyvraz

Fermionic cold atoms in optical traps provide viable quantum simulators of correlation effects in electronic systems. For dressed Rydberg atoms in two-dimensional traps with out-of-plane dipole moments, a realistic model of the pairwise…

Quantum Gases · Physics 2026-01-13 Clio Johnson , Neil D. Drummond , James P. Hague , Calum MacCormick