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Related papers: Robust non-adiabatic molecular dynamics for metals…

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We explain the concept of superadiabatic approximations and show how in the context of the Born- Oppenheimer approximation they lead to an explicit formula that can be used to predict transitions at avoided crossings. Based on this formula,…

Chemical Physics · Physics 2016-06-29 Volker Betz , Benjamin D. Goddard , Uwe Manthe

The importance of multi-electron dynamics during the tunnel ionization of a correlated quantum system is investigated. By comparison of the solution of the time-dependent Schr\"odinger equation (TDSE) with the time-dependent configuration…

Atomic Physics · Physics 2016-05-23 Maximilian Hollstein , Daniela Pfannkuche

Efficient simulation of strongly correlated electrons has become a routine tool in molecular electronic structure theory due to recent advances in approximate configuration interaction (CI) techniques. Nonetheless, the quantitative and…

Quantum Physics · Physics 2026-04-06 Daniel Gibney , Anthony W Schlimgen , Jan-Niklas Boyn

Increasing the luminosity of relativistic hadron beams is critical for the advancement of nuclear physics. Coherent electron cooling (CEC) promises to cool such beams significantly faster than alternative methods. We present simulations of…

With the rapid development of ultra-fast experimental techniques used for carrier dynamics in solid-state systems, a microscopic understanding of the related phenomena, particularly a first-principle calculation is highly desirable.…

Materials Science · Physics 2022-09-23 Fan Zheng , Lin-wang Wang

We examine time-resolved X-ray diffraction from molecules in the gas phase which undergo nonadiabatic avoided-crossing dynamics involving strongly coupled electrons and nuclei. Several contributions to the signal are identified,…

Chemical Physics · Physics 2017-05-30 Markus Kowalewski , Kochise Bennett , Shaul Mukamel

Microscopic thermal machines promise to play an important role in future quantum technologies. Making such devices widely applicable will require effective strategies to channel their output into easily accessible storage systems like…

Statistical Mechanics · Physics 2024-10-02 Joshua Eglinton , Federico Carollo , Igor Lesanovsky , Kay Brandner

Two-dimensional electronic spectroscopy (2DES) provides a detailed picture of electronically nonadiabatic dynamics that can be interpreted with the aid of simulations. Here, we develop and contrast trajectory-based nonadiabatic dynamics…

Quantum electrodynamics in 1 + 1D (QED2) shares intriguing properties with QCD, including confinement, string breaking, and interesting phase diagram when the non-trivial topological $\theta$-term is considered. Its lattice regularization…

High Energy Physics - Lattice · Physics 2024-11-05 Matteo D'Anna , Marina Krstic Marinkovic , Joao C. Pinto Barros

We design a quantum molecular dynamics method for strongly correlated electron metals. The strong electronic correlation effects are treated within a real-space version of the Gutzwiller variational approximation (GA), which is suitable for…

Strongly Correlated Electrons · Physics 2017-07-12 Jean-Pierre Julien , Joel D. Kress , Jian-Xin Zhu

We extend the Mixed Quantum-Classical Initial Value Representation (MQC-IVR), a semiclassical method for computing real-time correlation functions, to electronically nonadiabatic systems using the Meyer-Miller-Stock-Thoss (MMST) Hamiltonian…

Chemical Physics · Physics 2018-01-17 Matthew S. Church , Timothy J. H. Hele , Gregory S. Ezra , Nandini Ananth

This work reports on the development of a new approach to the multiscale computational modelling of the focused electron beam-induced deposition (FEBID), realised using the advanced software packages: MBN Explorer and MBN Studio. Our…

Computational Physics · Physics 2025-06-24 Ilia A. Solov'yov , Alexey Prosvetov , Gennady Sushko , Andrey V. Solov'yov

We build on the concept of eigenvector continuation to develop an efficient multi-state method for the rigorous and smooth interpolation of a small training set of many-body wavefunctions through chemical space at mean-field cost. The…

Chemical Physics · Physics 2024-05-02 Kemal Atalar , Yannic Rath , Rachel Crespo-Otero , George H. Booth

Quantum systems are typically subject to various environmental noise sources. Treating these environmental disturbances with a system-bath approach beyond weak coupling one must refer to numerical methods as, for example, the numerically…

Quantum Physics · Physics 2021-12-08 Timo Palm , Peter Nalbach

The dynamics of an electronic two-level system coupled to an electromagnetic field are simulated explicitly for one and three dimensional systems through semiclassical propagation of the Maxwell-Liouville equations. We consider three…

Dynamics of neutral atoms in nonuniform magnetic fields, typical of quadrupole magnetic traps, is considered by applying an accurate method for solving nonlinear systems of differential equations. This method is more general than the…

Atomic Physics · Physics 2009-10-30 V. I. Yukalov

In this Letter, we study the real-ime dynamics of single-electron pumpings. We modulate the left tunneling barrier along with the dot level but slightly changing the right barrier to operate the single-electron pumping device at zero bias.…

Mesoscale and Nanoscale Physics · Physics 2012-07-03 Chuan-Yu Lin , Wei-Min Zhang

Adiabatic evolution is a central paradigm in quantum physics. Digital simulations of adiabatic processes are generally viewed as costly, since algorithmic errors typically accumulate over the long evolution time, requiring exceptionally…

Quantum Physics · Physics 2025-10-15 Yangyu Lu , Yifei Huang , Dong An , Qi Zhao , Dingshun Lv , Xiao Yuan

We show that the time dependent single electron, nuclear density matrix of an interacting electronic system coupled to nuclear degrees of freedom can be exactly reproduced by that of an electronic system with arbitrarily specified…

Materials Science · Physics 2009-02-07 Vinod Krishna

Numerical studies of ionic motion through solid electrolytes commonly involve static nudged-elastic band (NEB) methods or costly \emph{ab initio} molecular dynamics (AIMD). Building on a time-local model of current carrier-electrolyte…

Materials Science · Physics 2025-04-10 Aleksandr Rodin , Ben Andrew Olsen , Andrey Ustyuzhanin , Artem Maevskiy