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We present general and rigorous results showing that the microcanonical and canonical ensembles are equivalent at all three levels of description considered in statistical mechanics - namely, thermodynamics, equilibrium macrostates, and…

Statistical Mechanics · Physics 2015-05-15 Hugo Touchette

The unitary dynamics of isolated quantum systems does not allow a pure state to thermalize. Because of that, if an isolated quantum system equilibrates, it will do so to the predictions of the so-called "diagonal ensemble" $\rho_{DE}$.…

Quantum Physics · Physics 2018-11-14 Fabio Anza

A sudden change of the Hamiltonian parameter drives a quantum system out of equilibrium. For a finite-size system, expectations of observables start fluctuating in time without converging to a precise limit. A new equilibrium state emerges…

Quantum Physics · Physics 2013-03-21 Lorenzo Campos Venuti , Paolo Zanardi

For classical system under constant composition, macroscopic structure in thermodynamically equilibrium state can be determined through the so-called canonical average, including sum over possible microscopic states on phase space. Although…

Statistical Mechanics · Physics 2018-08-10 Koretaka Yuge , Shouno Ohta

The basic characteristics of the classical many-particle (''macroscopic'') systems are notoriously hard to reproduce in quantum theory. In this paper we show that this is not the case for certain many-particle systems within the recently…

Quantum Physics · Physics 2025-03-03 J. Jeknic-Dugic , M. Arsenijevic , M. Dugic

Given physical systems, counting rule for their statistical mechanical descriptions need not be unique, in general. It is shown that this nonuniqueness leads to the existence of various canonical ensemble theories which equally arise from…

Quantum Physics · Physics 2009-10-31 Sumiyoshi Abe , A. K. Rajagopal

We present a geometric and dynamical approach to the micro-canonical ensemble of classical Hamiltonian systems. We generalize the arguments in \cite{Rugh} and show that the energy-derivative of a micro-canonical average is itself…

chao-dyn · Physics 2009-10-30 Hans Henrik Rugh

Macroscopic thermodynamics of equilibrium is constructed for systems obeying power-law canonical distributions. With this, the connection between macroscopic thermodynamics and microscopic statistical thermodynamics is generalized. This is…

Statistical Mechanics · Physics 2009-10-31 Sumiyoshi Abe , A. K. Rajagopal

The dynamical status of isolated quantum systems, partly due to the linearity of the Schrodinger equation is unclear: Conventional measures fail to detect chaos in such systems. However, when quantum systems are subjected to observation --…

Quantum Physics · Physics 2009-11-10 Salman Habib , Kurt Jacobs , Kosuke Shizume

Ensemble inequivalence has been observed in several systems. In particular it has been recently shown that negative specific heat can arise in the microcanonical ensemble in the thermodynamic limit for systems with long-range interactions.…

Statistical Mechanics · Physics 2015-06-24 F. Leyvraz , S. Ruffo

We propose a tensor network algorithm for the efficient sampling of quantum pure states belonging to a generalized microcanonical ensemble. The algorithm consists in an adaptation of the power method to a recently introduced ensemble of…

Quantum Physics · Physics 2013-09-05 Silvano Garnerone , Thiago R. de Oliveira

Focusing on isolated macroscopic systems, described either in terms of a quantum mechanical or a classical model, our two key questions are: In how far does an initial ensemble (usually far from equilibrium and largely unknown in detail)…

Statistical Mechanics · Physics 2013-11-13 Peter Reimann , Mykhaylo Evstigneev

In this didactical note I review in depth the rationale for using generalised canonical distributions in quantum statistics. Particular attention is paid to the proper definitions of quantum entropy and quantum relative entropy, as well as…

Quantum Physics · Physics 2008-06-03 Jochen Rau

Ensemble inequivalence occurs when a systems thermodynamic properties vary depending on the statistical ensemble used to describe it. This phenomenon is known to happen in systems with long-range interactions and has been observed in many…

Statistical Mechanics · Physics 2026-04-09 Daniel Arrufat-Vicente , David Mukamel , Stefano Ruffo , Nicolo Defenu

In this paper, we draw attention to the problem of phase transitions in systems with locally affine microcanonical entropy, in which partial equivalence of (microcanonical and canonical) ensembles is observed. We focus on a very simple spin…

Statistical Mechanics · Physics 2020-02-19 Agata Fronczak , Piotr Fronczak , Grzegorz Siudem

The most efficient MC weights for the calculation of physical, canonical expectation values are not necessarily those of the canonical ensemble. The use of suitably generalized ensembles can lead to a much faster convergence of the…

Statistical Mechanics · Physics 2011-01-24 Bernd A. Berg

The basic quantity for the description of the statistical properties of physical systems is the density of states or equivalently the microcanonical entropy. Macroscopic quantities of a system in equilibrium can be computed directly from…

Statistical Mechanics · Physics 2007-05-23 Michel Pleimling , Hans Behringer

Starting from the quantum mechanics for $N$ particles, we show that we can directly derive the microcanonical ensemble average of the physical quantity $A$ by using only the long time average and the equal probability assumption for the…

Statistical Mechanics · Physics 2013-07-03 Tetsuro Saso

What is the best description that we can construct of a thermodynamic system that is not in equilibrium, given only one, or a few, extra parameters over and above those needed for a description of the same system at equilibrium? Here, we…

Statistical Mechanics · Physics 2007-07-05 Gavin E. Crooks

In this paper we introduce a simple procedure for computing the macroscopic quantum behaviour of periodic quantum systems in the high energy regime. The macroscopic quantum coherence is ascribed to a one-particle state, not to a condensate…

Quantum Physics · Physics 2015-06-17 A. Martín-Ruiz , J. Bernal , Adrián Carbajal-Domínguez
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