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Interstellar complex organic molecules (iCOMs) can be loosely defined as chemical compounds with at least six atoms in which at least one is carbon. The observations of iCOMs in star-forming regions have shown that they contain an important…

Solar and Stellar Astrophysics · Physics 2019-09-30 Joan Enrique-Romero , Albert Rimola , Cecilia Ceccarelli , Piero Ugliengo , Nadia Balucani , Dimitrios Skouteris

The question, what is the role of freeze-out of chemical species in determining the molecular abundances in the interstellar gas is a matter of debate. We investigate a theoretical case of a dense interstellar molecular cloud core by…

Astrophysics of Galaxies · Physics 2018-03-14 Juris Kalvans , Ivar Shmeld

Interstellar dust grains play a crucial role in the evolution of the galactic interstellar medium (ISM). Despite its importance, however, dust remains poorly understood in terms of its origin, composition, and abundance throughout the…

Astrophysics of Galaxies · Physics 2010-05-11 Brian J. Williams

In chemical reaction network theory, ordinary differential equations are used to model the temporal change of chemical species concentration. As the functional form of these ordinary differential equations systems is derived from an…

Molecular Networks · Quantitative Biology 2025-02-27 Anna C. M. Thöni , William E. Robinson , Yoram Bachrach , Wilhelm T. S. Huck , Tal Kachman

Interstellar dust grains exhibit complex dynamics which is essential for understanding many key interstellar processes that involve dust, including grain alignment, grain growth, grain shattering etc. Grain rotational and translational…

Astrophysics · Physics 2007-05-23 A. Lazarian , Huirong Yan

The low density interstellar medium (ISM) close to the Sun and inside of the heliosphere provides a unique laboratory for studying interstellar dust grains. Grain characteristics in the nearby ISM are obtained from observations of…

Astrophysics of Galaxies · Physics 2015-06-05 Priscilla C. Frisch , Jonathan D. Slavin

The construction of a reaction network containing all relevant intermediates and elementary reactions is necessary for the accurate description of chemical processes. In the case of a complex chemical reaction (involving, for instance, many…

Chemical Physics · Physics 2017-12-19 Gregor N. Simm , Markus Reiher

Advanced telescopes, such as ALMA and JWST, are likely to show that the chemical universe may be even more complex than currently observed, requiring astrochemical modelers to improve their models to account for the impact of new data.…

Astrophysics of Galaxies · Physics 2017-08-07 E M Penteado , C Walsh , H M Cuppen

Context: Molecular hydrogen ($\rm{H_2}$) is crucial in galaxy formation and evolution, serving as the main fuel for star formation (SF). In metal-enriched environments, $\rm{H_2}$ primarily forms on interstellar dust grain surfaces.…

The recent discovery of methyl formate and dimethyl ether in the gas phase of cold cores with temperatures as cold as 10 K challenges our previous astrochemical models concerning the formation of complex organic molecules. The strong…

Solar and Stellar Astrophysics · Physics 2016-03-23 Qiang Chang , Eric Herbst

A magnetohydrodynamic model of a steady, transverse C-type shock in a dense molecular cloud is presented. A complete gas-grain chemical network is taken into account: the gas-phase chemistry, the adsorption of gas species on dust grains,…

Astrophysics of Galaxies · Physics 2018-06-12 A. V. Nesterenok

Continuous-time, random-walk Monte Carlo simulations of H2 formation on grains have been performed for surfaces that are stochastically heated by photons. We have assumed diffuse cloud conditions and used a variety of grains of varying…

Astrophysics · Physics 2009-11-11 H. M. Cuppen , O. Morata , Eric Herbst

Context. Interstellar surface chemistry is a complex process that occurs in icy layers accumulated onto grains of different sizes. Efficiency of surface processes often depends on the immediate environment of adsorbed molecules. Aims. We…

Astrophysics of Galaxies · Physics 2024-07-31 Juris Kalvāns , Aija Kalniņa , Kristaps Veitners

In the interstellar medium (ISM), the formation of complex organic molecules (COMs) is largely facilitated by surface reactions. However, in cold dark clouds, thermal desorption of COMs is inefficient because of the lack of thermal energy…

Astrophysics of Galaxies · Physics 2022-09-07 Alec Paulive , Joshua T. Carder , Eric Herbst

There exist several methods for simulating biological and physical systems as represented by chemical reaction networks. Systems with low numbers of particles are frequently modelled as discrete-state Markov jump processes and are typically…

Quantitative Methods · Quantitative Biology 2022-10-24 Joshua C. Kynaston , Christian A Yates , Anna Hekkink , Chris Guiver

The aim of the present work is to perform a comprehensive analysis of the interstellar chemistry of nitrogen, focussing on the gas-phase formation of the smallest polyatomic species and in particular nitrogen hydrides. We present a new…

Solar and Stellar Astrophysics · Physics 2015-06-18 Romane Le Gal , Pierre Hily-Blant , Alexandre Faure , Guillaume Pineau des Forêts , Claire Rist , Sébastien Maret

We study molecular hydrogen formation in and on solids. We construct a model with surface sites and bulk sites capable of describing (1) the motion and exchange of H and H_2 between surface and bulk, (2) the recombination of H and…

Astrophysics · Physics 2007-05-23 Amir Levinson , David F. Chernoff , Edwin E. Salpeter

$H_2$ is the most abundant interstellar species. Its deuterated forms ($HD$ and $D_2$) are also significantly abundant. Huge abundances of these molecules could be explained by considering the chemistry occurring on the interstellar dust.…

Astrophysics of Galaxies · Physics 2015-04-27 DIpen Sahu , Ankan Das , Liton Majumdar , Sandip K. Chakrabarti

Observations of gaseous complex organic molecules (COMs) in cold starless and prestellar cloud cores require efficient desorption of the COMs and their parent species from icy mantles on interstellar grains. With a simple astrochemical…

Astrophysics of Galaxies · Physics 2022-07-04 Juris Kalvāns , Kedron Silsbee

Context: Complex molecules such as ethanol and dimethyl ether have been observed in a number of hot molecular cores and hot corinos. Attempts to model the molecular formation process using gas phase only models have so far been…

Astrophysics of Galaxies · Physics 2015-05-18 P. Hall , T. J. Millar
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