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We report first principles analysis of electron-phonon coupling in molecular devices under external bias voltage and during current flow. Our theory and computational framework are based carrying out density functional theory within the…

Materials Science · Physics 2009-11-11 N. Sergueev , D. Roubtsov , Hong Guo

We consider the non-equilibrium dynamics of a molecular level interacting with local phonon modes in the case of a strong polaronic shift which prevents a perturbative treatment of the problem. Instead, we find that in an adiabatic regime…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 D. Mozyrsky , M. B. Hastings , I. Martin

The non-equilibrium dynamics of matter excited by light may produce electronic phases that do not exist in equilibrium, such as laser-induced high-transition-temperature superconductivity. Here we simulate the dynamics of a metal driven at…

Strongly Correlated Electrons · Physics 2022-12-05 John Sous , Benedikt Kloss , Dante M. Kennes , David R. Reichman , Andrew J. Millis

The interaction between electronic and vibrational degrees of freedom is an important mechanism in nonequilibrium charge transport through molecular nanojunctions. While adiabatic polaron-type coupling has been studied in great detail, new…

Mesoscale and Nanoscale Physics · Physics 2022-06-10 Christoph Kaspar , André Erpenbeck , Jakob Bätge , Christian Schinabeck , Michael Thoss

We study thermoelectric transport through a coherent molecular conductor connected to two electron and two phonon baths using the nonequilibrium Green's function method. We focus on the mutual drag between electron and phonon transport as a…

Mesoscale and Nanoscale Physics · Physics 2016-05-11 Jing-Tao Lü , Jian-Sheng Wang , Per Hedegård , Mads Brandbyge

Employing the nonequilibrium Green's function method, we develop a fully quantum mechanical model to study the coupled electron-phonon transport in one-dimensional atomic junctions in the presence of a weak electron-phonon interaction. This…

Mesoscale and Nanoscale Physics · Physics 2008-03-04 J. T. Lü , Jian-Sheng Wang

We present a fully nonequilibrium calculation of the low-temperature transport properties of a single molecular quantum dot coupled to local phonon mode when an ac field is applied to the gate. The resonant behavior is shown in the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Rong Lu

Here we present a theoretical analysis of inelastic effects on thermoelectric properties of molecular-scale junction in both linear and nonlinear response regimes. Considered device is composed of molecular quantum dot (with discrete energy…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 Kamil Walczak

We study the influence of a linear energy bias on a non-equilibrium excitation on a chain of molecules coupled to local phonons (a tilted Holstein model) using both a random-walk rate kernel theory and a nonperturbative, massively…

Quantum Physics · Physics 2022-07-29 R. Kevin Kessing , Pei-Yun Yang , Salvatore R. Manmana , Jianshu Cao

We consider a polaron model where molecular \emph{rotations} are important. Here, the usual hopping between neighboring sites is affected directly by the electron-phonon interaction via a {\em twist-dependent} hopping amplitude. This model…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Wei Zhang , Alexander O. Govorov , Sergio E. Ulloa

We developed a theory of charge transport in a system of non-interacting polarons. The theory was conducted to a compact relation through a nonperturbative method based on electron-phonon Hamiltonian. The derived final result represents…

Other Condensed Matter · Physics 2012-03-15 F. Marsusi , J. Sabbaghzadeh

We theoretically study the electrical transport properties of a single level quantum dot connected to two normal conducting leads, which is coupled to the lattice vibrations. We determine the current through the quantum dot in two different…

Mesoscale and Nanoscale Physics · Physics 2020-09-01 Levente Máthé , Ioan Grosu

Finite-bias electron transport through single molecules generally induces nonequilibrium molecular vibrations (phonons). By a mapping to a Fokker-Planck equation, we obtain analytical scaling forms for the nonequilibrium phonon distribution…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Jens Koch , Matthias Semmelhack , Felix von Oppen , Abraham Nitzan

We present a simple model of electrical transport through a metal-molecule-metal nanojunction that includes charging effects as well as aspects of the electronic structure of the molecule. The interplay of a large charging energy and an…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Matthias H. Hettler , Herbert Schoeller , Wolfgang Wenzel

We investigate full quantum mechanical evolution of two electrons nonlinearly coupled to quantum phonons and simulate the dynamical response of the system subject to a short spatially uniform optical pulse that couples to dipole-active…

Statistical Mechanics · Physics 2025-03-06 K. Kovač , D. Golež , M. Mierzejewski , J. Bonča

A theoretical approach for the non-equilibrium transport properties of nanoscale systems coupled to metallic electrodes with strong electron-phonon interactions is presented. It consists in a resummation of the dominant Feynman diagrams…

Mesoscale and Nanoscale Physics · Physics 2014-02-20 R. Seoane Souto , A. Levy Yeyati , A. Martín-Rodero , R. C. Monreal

We present a combined theoretical approach to study the nonequilibrium transport properties of nanoscale systems coupled to metallic electrodes and exhibiting strong electron-phonon interactions. We use the Keldysh Green function formalism…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 R. C. Monreal , F. Flores , A. Martin-Rodero

Physical foundations of adiabatic and nonadiabatic electronics of materials are considered in this article. It is shown the limitation of adiabatic approach to electronics of materials. It is shown that nonadiabatic physical properties of…

Materials Science · Physics 2007-05-23 V. A. Vdovenkov

We investigate the steady-state electronic transport through a suspended dimer molecule coupled to leads. When strongly coupled to a vibrational mode, the electron transport is enhanced at the phonon resonant frequency and higher-order…

Mesoscale and Nanoscale Physics · Physics 2013-02-18 D. H. Santamore , Neill Lambert , Franco Nori

The electron transport properties of a four-terminal molecular device are computed within the framework of density functional theory and non-equilibrium Keldysh theory. The additional two terminals lead to new properties, including a…

Mesoscale and Nanoscale Physics · Physics 2009-09-01 Kamal K. Saha , Wenchang Lu , J. Bernholc , Vincent Meunier