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The surface conductivity is measured by a four-probe technique for pentacene and rubrene single-crystals laminated on polarized and nearly unpolarized molecular monolayers with application of perpendicular electric fields. The polarization…

Materials Science · Physics 2009-11-10 J. Takeya , T. Nishikawa , T. Takenobu , S. Kobayashi , C. Goldmann , C. Krellner , T. Shimoda , T. Mitani , Y Iwasa , B. Batlogg

We report a detailed comparison on the role of a self-assembled monolayer (SAM) of dipolar molecules on the threshold voltage and charge carrier mobility of organic field-effect transistor (OFET) made of both amorphous and polycrystalline…

Materials Science · Physics 2014-02-05 C. Celle , C. Suspene , M. Ternisien , S. Lenfant , D. Guerin , K. Smaali , K. Lmimouni , J. P. Simonato , D. Vuillaume

Few examples of the exploitation of molecular magnetic properties in molecular electronics are known to date. Here we propose the realization of Self assembled monolayers (SAM) of a particular stable organic radical. This radical is meant…

Chemical Physics · Physics 2016-11-18 Paolo Messina

The self-assembly of a single layer of organic molecules on a substrate is a powerful strategy to modify surfaces and interfacial properties. The detailed interplay of molecule-to-substrate and molecule-molecule interactions are crucial for…

Molecular-scale diodes made from self-assembled monolayers (SAMs) could complement silicon-based technologies with smaller, cheaper, and more versatile devices. However, advancement of this emerging technology is limited by insufficient…

Silanization bases on the adsorption, selfassembly and covalent binding of silane molecules onto surfaces, resulting in a densely packed self-assembled monolayer (SAM). Following standard recipes, however, the quality of the monolayer is…

We have investigated the conductance properties of C60-containing self-assembled monolayers (SAMs), which are used in organic field-effect transistors, employing a combination of molecular-dynamics simulations, semiempirical electronic…

Mesoscale and Nanoscale Physics · Physics 2015-06-19 Susanne Leitherer , Christof Jäger , Marcus Halik , Timothy Clark , Michael Thoss

Self-assembled monolayers (SAMs) of organic molecules are widely employed in surface chemistry and biology, and serve as ultra-fine lithographic resists. Due to their small thickness of only a few nanometers, the analysis of patterned…

Materials Science · Physics 2014-10-28 Hadas Alon , Idan Bakish , Josh Nehrer , Assaf Y. Anderson , Chaim N. Sukenik , Avi Zadok , Doron Naveh

Molecular self-assembly is a well-known technique to create highly functional nanostructures on surfaces. Self-assembly on two-dimensional materials is a developing field and has already resulted in the discovery of several rich and…

Mesoscale and Nanoscale Physics · Physics 2017-09-04 Avijit Kumar , Kaustuv Banerjee , Peter Liljeroth

The tunable properties of molecular materials place them among the favorites for a variety of future generation devices. In addition, to maintain the current trend of miniaturization of those devices, a departure from the present top-down…

Graphene-based materials have been suggested for applications ranging from nanoelectronics to nanobiotechnology. However, the realization of graphene-based technologies will require large quantities of free-standing two-dimensional (2D)…

The way of reduction of metal oxyde semiconductor (MOS) structures is going to reach limitations and new devices have to be explored as an alternative to MOS technology. Molecular electronic and more particularly self-assembly-molecular…

Materials Science · Physics 2007-08-15 C. Trapes , L. Rouai , L. Patrone

The alignment of permanent dipole moments and the resulting spontaneous orientation polarization (SOP) is commonly observed in evaporated neat films of polar organic molecules and leads to a so-called giant surface potential. In case of…

Materials Science · Physics 2025-05-01 Alexander Hofmann , Albin Cakaj , Lea Kolb , Yutaka Noguchi , Wolfgang Brütting

The Self-Assembly of Nano-Objects (SANO) code we implemented demonstrates the ability to predict the molecular self-assembly of different structural motifs by tuning the molecular building blocks as well as the metallic substrate. It…

Computational Physics · Physics 2012-11-26 Thomas Roussel , Lourdes F. Vega

Tantalum is a promising platform for superconducting quantum circuits, yet coherence times remain limited by dielectric losses from interfacial two-level systems (TLS), exacerbated by native oxide regrowth. Here, we implement molecular…

Self-limiting assembly of particles represents the state-of-the-art controllability in nanomanufacturing processes where the assembly stops at a designated stage1,2, providing a desirable platform for applications requiring delicate…

Atomic and Molecular Clusters · Physics 2021-11-02 Liang Zhao , Bchara Sidnawi , Jichao Fan , Ruiyang Chen , Thomas Scully , Scott Dietrich , Weilu Gao , Qianhong Wu , Bo Li

Spontaneous orientation polarization (SOP) of polar molecules is formed in vacuum-deposited films by tilting their permanent dipole moment against the substrate surface direction. In this study, we developed SOP molecules with high…

Materials Science · Physics 2026-02-18 Masaki Tanaka , Rena Sugimoto , Nobuhumi Nakamura

In weakly interacting organic semiconductors, static and dynamic disorder often have an important impact on transport properties. Describing charge transport in these systems requires an approach that correctly takes structural and…

Materials Science · Physics 2017-11-15 Susanne Leitherer , Christof M. Jäger , Andreas Krause , Marcus Halik , Tim Clark , Michael Thoss

We compute the electronic structure of two-dimensional (2D) materials decorated with self-assembled organic monolayers using density functional theory. We find that 2D materials are strongly impacted by near-field electrostatic effects…

Materials Science · Physics 2021-09-22 Qunfei Zhou , Bukuru Anaclet , Trevor Steiner , Michele Kotiuga , Pierre Darancet

The effect of structural constriction on molecular mobility is investigated by broadband dielectric spectroscopy (BDS) within three types of molecular arrangements: monomers, oligomers and self-assembled monolayers (SAMs). While disordered…

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